Corrosion fatigue short crack growth behaviour in a high strength steel

The influence of an aggressive environment (0.6 M, aerated NaCl solution) on short fatigue crack initiation and growth behaviour has been studied. The study involved three major test series, namely: air fatigue, corrosion fatigue, and intermittent air fatigue/corrosion fatigue. The above tests carried out under fully reversed torsional loading conditions at a frequency of 5 Hz, showed that it was the non-metallic inclusions which took part in crack initiation resulting from debonding at metal matrix/inclusion interface and pitting of inclusions in both air and corrosove environments, respectively. Short fatigue crack growth results in these two environments obtained by using plastic replication technique, indicated a large effect of microstructure i.e. prior austenite grain boundaries. The stage/stages at which the environmental contribution was dominant has been discussed by considering the results achieved from intermittent tests. However, the mechanisms involved in corrosion fatigue short crack growth have also been described in the light of results obtained from futher investigations carried out by conducting corrosion fatigue tests under applied cathodic potential conditions and tests on hydrogen pre-charged specimens under air fatigue and uniaxial tension conditions.     

苯并口恶嗪-环氧化合物-胺类催化剂体系开环聚合反应的研究

采用TLC，GPC，1H－NMR及IR等分析方法，对苯并恶嗪－环氧化合物－胺类催化剂体系的聚合反应进行了研究，表征了产物结构，并探讨了聚合反应机理，结果表明，苯并恶唪－环氧化合物体系在胺类催化剂如苄胺，咪唑的作用下，能发生开环聚合反应，生成低分子量的聚合物。     

Failure analysis of a wire rope

Wire ropes, pulleys, counterweights, and connecting systems are used for auto tensioning of contact wires of electric railways. A wire rope in one such auto tensioning system suffered premature failure. Failure investigation revealed fatigue cracks initiating at nonmetallic inclusions near the surface of individual wire strands in the rope. The inclusions were identified as Al-Ca-Ti silicates in a large number of stringers, and some oxide and nitride inclusions were also found. The wire used in the rope did not conform to the composition specified for AISI 316 grade steel, nor did it satisfy the minimum tensile strength requirements. Failure of the wire rope was found to be due to fatigue; however, the ultimate fracture of the rope was the result of overload that occurred after fatigue failure had reduced the number of wire strands supporting the load.     

Sensitizing Mechanism and Adsorption Properties of Dye—Sensitized TiO2 Thin Films

The dye-sensitized TiO2 complex films were prepared by the dye coat onto TiO2 surfaces,and the sensitizing mechanism and adsorption properties of the dye-sensitized TiO2 complex films were inverstigated.The influence of the application conditions of dye adsorbed on TiO2 films on the amount of dye adsorption was discussed.Experimental results show that the concentration,the temperature of dye solutions and the dipping time of TiO2 films in the dye solutions have a significant influence on the amount of dye adsorption.Cell test indicates that the conversion efficiency of light to electricity increases with the amount of dye adsorption.     

碳纤维缠绕复合材料在潜水外压容器上的应用

在铝合金圆筒体外以浸渍树脂碳纤维进行缠绕复合增强，增强后的筒体耐静水外压能力大幅度提高；整体缠绕的全复合材料筒体，在耐静水外压能力及减轻自身重量方面也获得了明显的效果。此外，在铝合金细长圆管的外壁复合缠绕碳纤维，能有效地提高圆管对轴向压载荷的抗失稳与抗屈曲破坏能力。     

Growth of Fe on Si (100) at room temperature and formation of iron silicide

Low-energy electron diffraction (LEED), Auger electron spectroscopy and X-ray photoelectron spectroscopy (XPS) investigations of both the growth of an iron film on silicon (100) at room temperature and the subsequent formation of iron silicide are the subjects of this paper. An in-situ cleaned silicon (100) wafer without carbon or oxygen contamination exhibiting the known 2 × 1 reconstruction in the LEED pattern served as the substrate. Iron was deposited on this reconstructed surface at 300 K. The comparison of theoretical calculations based on three growth mechanisms with XPS data obtained with take-off angles of 0° and 50° clearly demonstrates a layer-by-layer growth of the iron film on silicon (100). At 300 K no formation of iron silicide was observed, although an interaction between iron and silicon could be detected at the interface. The formation of iron silicide was observed at annealing temperatures of 630–730 K. Quantitative XPS analysis yields the presence of FeSi₂, when the thickness is large enough. Neither the iron film on silicon nor the silicide shows any LEED pattern.     

精密角位移传感器及其可靠性研究

从理论上探讨了磁阻率效应，叙述了精密角位移传感器的工作原理及结构设计。传感器的分辨率已达０．０１°，通过可靠性寿命试验，传感器的失效率λ（ｔ）＜１×１０－７／ｈ。     

苎麻阳离子改性的研究（三）：改性苎麻的染色机理

采用上染速率，等温吸附模型，Ｚｅｔａ电位、染料与纤维的结合力等方法从理论上研究了改性苎麻的染色机理，苎麻改性后，纤维表面的Ｚｅｔａ电位由原来的－４２ｍＶ提高到－１８ｍＶ，正电性显著增加，提高了阴离子染料对改性苎麻的亲和力，上染率高，节约染料。     

结构陶瓷的高温疲劳强度衰减理论

提出了陶瓷材料疲劳强度衰减理论并由此导出了各种疲劳关系式。建立了疲劳基本方程ｄσ＿ｒ／ｄ＿ｉ＝一Ａσ（ｔ）￣ｎｔ￣（－ｍ），得出了疲劳寿命公式Ｔ＝Ｍ（σ＿０－σ）／Ａσ￣ｎ（静疲劳时Ｍ＝１，连续增载疲劳时Ｍ＝ｎ＋１，循环疲劳时Ｍ＝（ｎ＋１）／（１＋Ｒ＋Ｒ￣２＋……＋Ｒ￣ｎ），逐级加载时，并导出不同疲劳方式下疲劳寿命间的关系。同时，用多种Ｓｉ＿３Ｎ＿４材料在高温中作了论证试验，结果与理论一致。     

压裂泵往复密封性能及机理研究

根据流体动压润滑理论，对压裂泵柱塞密封摩擦副的润滑机理进行了理论分析。在排出和吸入行程，柱塞密封摩擦副均能满足流体动压润滑的条件，即在柱塞与密封界面上能形成并保持一定厚度的油膜润滑密封，从而达到减小摩擦提高寿命的目的；建立了摩擦界面油膜厚度和泄漏量的计算公式。利用有限元法理论，对密封圈的压力沿轴向的分布规律、泄漏量与压力变化关系进行了模拟计算。对往复密封圈沿轴向压力分布、泄漏量随压力变化进行了测试；试验结果表明，建立的计算模型具有较高的计算精度，揭示了压裂泵的密封机理。