Effects of a Nd—Fe—B magnetic filler on the crystallization of poly(phenylene sulfide)

The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002     

20%乙·苄可湿性粉剂的高效液相色谱分析

本文采用高效液相色谱法,以乙腈+水(60+40)作为流动相,使用C18柱,在同一条件下,同时成功地测定出20%乙·苄可湿性粉剂中的二元有效成份含量。该方法快速准确,乙草胺测定方法的相关系数为0.99986,平均回收率99.2%,苄黄隆测定方法的相关系数为0.99996,平均回收率为99.5%。     

Preparation of ultra-fine copper powder and its lead-free conductive thick film

In this paper, non-agglomerated monodispersed ultra-fine copper metallic powders have been synthesized with chemical reduction method. Fine lead-free glass powders were also prepared by solid synthesis process. Thick film paste prepared by above-mentioned copper metallic powders and lead-free glass powders was applied as conductive paste of MLCC. Mixture of glass and zinc oxide give the thick film a high adhesion strength which is attributed to the rough interface from interfacial reaction between glass and chip, and a good densification. Diffusion of metal between copper thick film and nickel thick film is clear. Ni-Cu solid solution appears under high temperature firing.     

水热合成纳米氧化锡粉体工艺因素研究

以SnCl4·5H2O和氨水为原料,通过正交实验并借助于XRD、TEM等手段,研究了前驱物浓度、反应温度、保温时间和氨水滴加速率等工艺因素对水热合成纳米SnO2粉体的影响。     

Structure of rapidly solidified aluminum alloys

This paper is a summary of an extensive research program carried out by the authors on the structure of rapidly solidified aluminum alloys; and a comparison with the work of others also involved in this field. The paper discusses the changes in the dendritic and non-dendritic structure of the matrix at cooling rates from 10^–3 to 10¹⁰ K/s and discusses the hetergeneity of the structure caused by interdendritic-segretion during solidification.     

真空熔炼高压气体雾化制粉技术及设备

介绍了气体雾化粉的品种、用途及工业化生产。还介绍了真空熔炼-高压气体雾化制粉所需的设备。     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

微波热液法制备光催化TiO2功能材料

采用微波加热法，研究了钛配离子热分解水解反应的规律。结果表明，水解产物在大气气氛和300℃下煅烧2h，所得产物为锐钛型TiO2粉末。在紫外线照射下，乙酸经Ti02光催化反应12h后，残余量小于初始量的20％。     

Stickiness, Functionality, and Microstructure of Food Powders

Three major aspects of food powder are described and discussed. Stickiness is one issue that can cause production and product handling difficulties. Stickiness has been interpreted in a number of ways and thus measured differently. Functionality of the primary (single) particles or agglomerated powders is of practical interest to the consumers. The desired quality will have to be matched or exceeded by the powder manufacturers. Finally, microstructure provides a key linkage between the production and the functionality. Its formation has impacts on both the stickiness and functionality.     

用保护共沉淀法制备纳米ZrO2(Y2O3)粉体

用Tween-80保护共沉淀法制备了ZrO2(Y2O3）纳米粉体，用差热分析，热重分析，X射线衍射及透射电子显微镜等技术研究所了粉体的特征，结果表明：在700℃燃烧0.5h后ZrO2(Y2O3)粉体的平均粒径为3－9nm，比表面为128.5-134.5m^3g^-1,在1250℃煅烧8h后ZrO2(Y2O3)粉体已完全形成了立方相的ZrO2L大溶体，并且有非常好的烧结性能。