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91.
Ahmad Nozad Golikand Elaheh Lohrasbi Mohammad Ghannadi Maragheh Mehdi Asgari 《Journal of Applied Electrochemistry》2008,38(6):869-874
The effect of carbon surface oxidation on platinum supported carbon particles (Pt/C) with nitric acid was investigated by
cyclic voltammetry, electrochemical impedance spectroscopy, polarization experiments and chronoamperometry. Cyclic voltammograms,
polarization curves and electrochemical impedance spectra showed that the treated catalyst had much larger active surface
area and higher ionic conductivity than the untreated catalyst, and provided enhanced performance for oxygen reduction. The
formation of acidic groups was examined by IR spectra. The Pt/C surface oxidation had a large effect on the performance of
a gas diffusion electrode for oxygen reduction reaction. 相似文献
92.
A simple method has been devised for immobilization of acetylcholinesterase (AChE) covalent bonding to a multiwall carbon
nanotube (MWNT)-cross-linked cellulose acetate composite on a screen-printed carbon electrode (SPCE) and a sensitive and disposable
amperometric sensor for rapid determination of carbaryl pesticide is proposed. The immobilized enzyme was preserved on this
film because of the excellent biocompatibility and non-toxicity of cellulose acetate. Based on the inherent conductive properties
of the MWNT, the immobilized AChE had greater affinity for ATCl and excellent catalytic effect in the hydrolysis of ATCl.
MWNT improved the interface enzymatic hydrolysis reaction and increased the amperometric response of the sensor. Under optimum
conditions, the inhibition of carbaryl on AChE increased linearly with the increasing concentration of carbaryl in two ranges,
from 0.01 to 0.5 μg mL−1 and from 2 to 20 μg mL−1, with the correlation coefficients of 0.9985 and 0.9977, respectively. The detection limit was 0.004 μg mL−1 taken as the concentration equivalent to 10% decrease in signal. The sensor showed acceptable stability, accuracy and could
be fabricated in batches, thus it is economic and portable. This type of disposable enzyme-based amperometric sensor has extensive
application potential in environmental monitoring of pesticides. 相似文献
93.
Debasmita Das Purabi Rani Samaddar Pratik Kumar Sen Kaushik Das 《Journal of Applied Electrochemistry》2008,38(6):743-749
Galvanostatic steady state current potential measurements were carried out for oxidation of a series of aliphatic alcohols
having varying number of hydroxyl groups. The anodically deposited layer of MnO2 on platinum was used as the electrode material. The deposit was characterised by scanning electron microscopy (SEM), energy
dispersive X-ray analysis (EDAX) and electrode potential measurements. The catalytic role of MnO2 in the electro-oxidation of alcohols was indicated by the chronopotentiograms and the cyclic voltammograms. An analysis of
the electrochemical data indicated a catalytic EC mechanism in which Mn (V) is generated electrochemically and consumed chemically
in succession. Based on this and the hydrogen bonding interaction between alcoholic hydroxyl groups and MnO2 layer, a mechanism was proposed which accounts for the variation in the observed electrochemical reaction orders. Tafel behaviour
was found to be followed only approximately. Current efficiency of the electrochemical oxidation of polyols was studied. Replacement
of platinum by carbon as current collector was found to leave the electrocatalytic activity of the MnO2 deposit practically unaltered. 相似文献
94.
Teresa Łuczak 《Journal of Applied Electrochemistry》2008,38(4):469-476
The electrooxidation of phenylethanolamine (2-amino-1-phenylethanol) at a gold electrode in alkaline electrolyte has been
studied. Measurement of the differential capacitance of the electric double layer versus the electrode potential has shown
that the adsorption of phenylethanolamine at the gold-solution interface plays a significant role in the oxidation mechanism.
The effect of amine concentration, electrolyte pH and potential scan rate on the electrooxidation is analysed. 相似文献
95.
S. Zisekas G. Karagiannakis C. Kokkofitis M. Stoukides 《Journal of Applied Electrochemistry》2008,38(8):1143-1149
The reaction of NH3 decomposition was studied on Ag in a proton conducting double chamber cell-reactor. The proton conductor was a strontia-ceria-ytterbia
(SCY) perovskite of the form SrCe0.95Yb0.05O3−α. The reaction was studied at 350–700 °C and atmospheric total pressure. The proton transference number (PTN) was calculated
by simultaneous measurement of the imposed current and the proton flux and it was found to vary between 0.5 and 0.7. The effects
of imposed current, temperature and inlet gas composition on the reaction rate and the PTN, were examined. Although the faradaic
efficiency (Λ) remained near unity in all experiments, reaction rate enhancements (ρ) as high as 57 were achieved. An up to
90% decrease in the activation energy of the reaction was observed when protons were electrochemically “pumped” away from
the catalyst. 相似文献
96.
Kiyoaki Imoto Kohshin Takahashi Takahiro Yamaguchi Teruhisa Komura Jun-ichi Nakamura Kazuhiko Murata 《Solar Energy Materials & Solar Cells》2003,79(4):459-469
Here, we reported that a new carbon electrode prepared with an activated carbon was superior to a Pt sputtered electrode as the counter electrode of dye-sensitized solar cells. The photovoltaic performance was largely influenced by the roughness factor of carbon electrode. The open-circuit voltage increased by about 60 mV using the carbon counter electrode compared to the Pt counter electrode because of positive shift of the formal potential for I3−/I− couple. 相似文献
97.
98.
提高中高含水期油井压裂经济效益的方法 总被引:5,自引:5,他引:0
为提高葡北油田中高含水期油井压裂经济效益,合理选择压裂井层尤为重要。应用水驱特征曲线预测出油井压裂前可采储量,从而计算出剩余可采储量及可采储量采出程度,通过绘制油井压裂前剩余可采储量及可采储量采出程度与油井压裂后所创经济效益之间关系曲线,寻找出相关规律,进行优选压裂井,再根据精细地质研究成果,在剩余油富集区选择具体压裂层位。经实际应用,取得了较好效果,提高了油井压裂方案符合率,提高了经济效益,进而总结出一套适合葡北油田中高含水期油井压裂选井选层方法,对今后进一步搞好油井压裂增产工作具有指导意义。 相似文献
99.
粒度控制——页岩、煤矸石空心砖原料制备的关键 总被引:1,自引:0,他引:1
阐述了页岩、煤矸石的原料粒度对制砖性能的影响,介绍了几种典型的控制颗粒粒度的工艺方案;简要分析了几种筛分机械的优缺点,着重介绍MVS电磁振动高频振网筛在几个使用现场的应用结果,为制砖企业解决原料生产的难题提供了办法。 相似文献
100.
We report here a non-enzymatic detecting electrode strip for fast monitoring of uric acid in human whole blood. A single-use amperometric uric acid sensor strip, incorporating a three-electrode configuration, has been fabricated on a polypropylene substrate using low cost screen-printing (thick-film) technology. Both the working and counter electrodes were prepared by screen-printing commercial carbon ink. The integration on the same support of pseudo-reference electrode was obtained by screen-printing a commercial silver ink and subsequent electrochemical pretreatment. Simply by placing a 20 μl human whole blood drop on the strip is enough for uric acid analysis by square-wave voltammetry. Real human whole blood samples were analyzed by this method and compared to the phosphotungstic acid clinical test procedure with satisfactory results. 相似文献