阻燃增塑剂溴化及溴氯化石蜡的合成工艺

综述了阻燃增塑剂溴化及溴氯化石蜡的各种合成工艺路线，讨论了相应的合成反应机理．包括反应历程和有关化学热力学计算，简要介绍了安徽省化工研究院已工业化的溴化及溴氯化石蜡合成工艺的特点。     

聚乙烯复合阻燃体系的研究及应用进展

综述了近年来国内外阻燃聚乙烯（PE）用有协同作用的复合阻燃体系：（1）卤-锑体系；（2）磷-氮体系；（3）金属氧化物体系；（4）膨胀型体系；（5）其他类等5类复合阻燃体系的研究和应用情况。     

热处理前后丙烯腈／溴乙烯共聚纤维的热性能和阻燃性能研究

分析了热处理前后丙烯腈／溴乙烯共聚纤维的热性能与溴乙烯含量、升温速率或热处理时间的关系，并对纤维的阻燃性与溴含量或热处理时间关系进行了研究。结果表明，溴含量的增加或热处理时间的延长对热稳定性和阻燃性的提高有较大影响，而且经热处理后纤维的阻燃性与溴无关。     

Zinc hydroxystannate and zinc stannate as flame‐retardant agents for flexible poly(vinyl chloride)

The flame‐retardant and smoke‐suppressant properties of inorganic tin compounds such as zinc hydroxystannate (ZHS) and zinc stannate (ZS) were investigated in a comparison with alumina trihydrate, magnesium hydroxide, and Sb₂O₃ through the limiting oxygen index test and smoke density test. The flame‐retardant mechanisms were studied through the char yield test, SEM, quantitative analysis, thermogravimetry and differential thermal analysis. The thermal degradation in air of flexible PVC treated with the above compounds was studied by thermal analysis from ambient temperature to 800°C. The results showed that tin compounds such as ZHS and ZS could be used as a highly effective flame retardant for flexible PVC, and it appears that the tin compound may exert its action in both the condensed and vapor phases, but mainly in condensed phases as a Lewis acid. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1469–1475, 2005     

防火涂料热降解的测试研究技术

介绍了防火涂料热降解的测试研究技术,并举例说明了这些技术在研究防火涂料热降解过程及机理中的作用,评述了各种测试研究技术的特点,说明采用多种测试技术联用是分析防火涂料热降解的方向。     

ZYBG型矿用瓦斯输送管道自动抑爆装置研制

为了保障瓦斯输送管道的安全性,采用主动抑爆技术研制了ZYBG型矿用瓦斯输送管道自动抑爆装置。该装置利用火焰探测器探测瓦斯爆炸信号,并将信号通过光电转换传输给控制器,控制器对信号进行判定和分析,在爆炸接近防护区间的瞬间快速打开高压抑爆器,释放抑爆介质,熄灭火焰,阻断爆炸的进一步传播。抑爆性能试验结果表明,该抑爆装置能够在5ms内快速捕捉火焰信息,并在35ms内迅速喷洒抑爆介质。     

固溶时效工艺对C194合金性能的影响

对采用热轧开坯法生产引线框架用C194合金带材过程中的固溶处理与时效处理工艺条件进行了研究．通过试验确立了合适的热处理工艺条件，使带材的抗拉强度达到538．5MPa，电导率达81．8％IACS。     

A computational fluid dynamic analysis of gas and particle flow in flame spraying

The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate. The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations compared fairly well with experimental results obtained with the optical DPV2000 system.     

铁547B合金热喷熔技术在高温高压阀门密封面性能强化方面的研究

用氧乙炔焰加熔剂助熔一步法在12Cr1MoV珠光体耐热钢高温高压阀门密封面基体上喷熔Fe547B合金粉末,对喷熔工艺及喷熔层的硬度、时效硬化特性、热耐久性能、抗擦伤性能等性能进行了较系统的试验研究。证明用喷熔Fe547B合金粉末工艺修复电站高温高压阀门密封面裂纹是可行的。     

SHS火焰喷涂梯度过渡陶瓷涂层的显微组织及耐磨性分析

以Ti-B4C-C团聚粉和Ni-Al“自粘结”复合粉的混合物为自蔓延反应火焰喷涂体系,在45钢基体表面制备Ti(Cx,Ny)-TiB2和NimAln梯度过渡的复相陶瓷涂层,分析研究了梯度过渡涂层的显微组织结构与耐磨性。研究表明:Ti(Cx,Ny)-TiB2复相陶瓷与NimAln金属间化合物实现了沿涂层厚度方向的梯度过渡连接。梯度过渡陶瓷涂层的耐磨性是普通45钢耐磨性的14倍。