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131.
D.J. Blundell 《Polymer》1982,23(3):359-364
Two rigid chain thermotropic liquid crystal polyesters have been examined by X-ray diffraction and thermal analysis in order to explore the nature of the crystallites in the solid state. A comparison of quenched and slow-cooled specimens indicates the presence in the quenched material of microcrystals that are too small to give clear X-ray lines. It is proposed that this is due to the very low surface energy associated with the nematic chain morphology. Both the enthalpy and entropy of fusion are much lower than in conventional polymers and are related to the molecular design of the thermotropic polymers. 相似文献
132.
This paper reports adsorption measurements that show molecular sieve effects in amorphous hydrogenated carbon (a-C : H) films deposited by d.c. magnetron discharge decomposition of acetylene. Adsorption of organic gases on the films is studied by using a quartz crystal microbalance technique. The sieve effect in this material depends on both deposition and annealing conditions. Films having significant molecular sieve effects are found to be typically microporous and to have a very small characteristic micropore dimension. It is suggested that the d.c. sputtered a-C : H film may be useful as a molecular sieve material in selective adsorption and gas permeation studies. 相似文献
133.
134.
Electro-rheological (ER) effect of a blend composed of two liquid crystalline materials with different molecular weights is described in this article. The results indicated that ER effect of the blend was observed at the temperature range where each neat sample did not show ER effect. Furthermore, both storage modulus (G′) and loss modulus (G″) decreased drastically at the temperature range for the blend in dynamic viscoelastic measurements. We show that steady ER effect could be obtained by using a blend made up of two liquid crystalline components, whereas remarkable increment in shear stress was not observed for each component under applied electric field. 相似文献
135.
介绍了一种软质电容式车辆动态称重系统.对该传感器静态特性进行了研究,分析了受力面积和时间的影响,针对橡胶材料粘弹性特性,提出了利用四元件模型对其建模.同时进行了动态实验,车辆总重量的测量误差在10%以内,其精度优于ASTME1318-02给出的Ⅰ类WIM系统精度(置信95%时总重误差±10%).实验结果表明:利用文中提出的车辆动态称重系统进行测量是可行的,它有助于随时测量,便于交通稽查. 相似文献
136.
为了解决全自动化晶体切片角分类机三个机械手协调工作的控制问题,设计了以MAS理论为基础的分布式网络控制器.系统利用黑板结构来实现全局动态目标下的状态信息的共享,采用多Agent理论对三个机械手进行协调工作控制,解决了机械手之间的运动耦合问题,使之能够在同一个时间和不同的空间内协调与配合工作,完成整体工作任务.基于此设计的设备可改善工人的劳动环境、提高生产效率、确保晶体切片切角的测量与分类准确. 相似文献
137.
通过DSC曲线研究了不同含量的ZrO2对CaO-SiO2系玻璃析晶的影响,根据JMA方程计算动力学参数(如析晶活化能E、频率因子ν、晶化指数n)。从计算结果可以看出,随着ZrO2含量的增加,析晶活化能E减少,而频率因子ν和晶化指数n增加。当ZrO2含量为7%时,E值最小:235.58kJ/mol;n值最大:4.70。说明ZrO2在CaO-SiO2玻璃体系是有效的晶核剂。 相似文献
138.
Research on hydropeaking in Austria started in the 1990s and the implementation of the WFD stipulated large research projects since the year 2009. The first research projects supported the process understanding and in a second investigation step, measures were evaluated. The mountains in the region of Tyrol create large heads and thus support the production of flexible energy. In this region, TIWAG is operating 9 large (>10 MW) and 27 small (<10 MW) hydropower plants, with an installed capacity of about 1,550 MW and a mean annual production of 3,000 GWh. As the governmental energy strategy foresees an extension of the hydropower production in Austria, suitable options were selected in 2004 by TIWAG and the water management framework plan for Western Tyrol was developed. This strategic planning instrument proposes five large power plants, with a generation of 1,800 GWh/year of renewable energy, which enables to reach the WFD targets, because the concept includes hydropeaking mitigation by combining buffer reservoirs (impoundments), diversion hydropower plants, and retention basins. We present our promising concept of hydropeaking mitigation and exemplify this based on the GKI, a hydropeaking diversion hydropower plants (HPP) at the Swiss/Austrian border as well as the Silz hydropeaking retention basin, with a volume of about 300,000 m3. As the presented case studies are the largest measures for hydropeaking mitigation being currently implemented in Central Europe, they have pilot-character. Thus, ongoing research and monitoring programs are expected to improve the knowledge about hydropeaking mitigation. 相似文献
139.
CHENG Bei YU Xiaoxiao YU Jiaguo ZHAO Xiujian 《稀有金属(英文版)》2006,25(4):382-388
BaCO3 whiskers exhibiting different morphologies were fabricated by a simple precipitation reaction of barium ch/oride with sodium carbonate in the absence and presence of poly-(styrene-alt-maleic acid) (PSMA) as a crystal growth modifier at room temperature. The as-prepared products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The influences of experimental parameters on the size and morphology of BaCO3 whiskers were investigated and discussed. It was found that the as-prepared BaCO3 whiskers are single crystals with diameter ranging from 100 to 300 run, and grow along the crystallographic a-axis or [100] direction. BaCO3 whiskers with different morphologies, such as branching and dendritic structure, can be obtained depending on the experimental conditions. With increasing PSMA concentration, the diameter of BaCO3 whiskers decreases. 相似文献
140.