公路面层脱硫石膏—粉煤灰混凝土试验研究与应用

脱硫石膏和粉煤灰按比例混合后,掺入适量改性剂复合而成一种新型活性矿物掺合料,并制备C30～C40脱硫石膏-粉煤灰混凝土,试验研究其主要技术性能。结果表明,脱硫石膏-粉煤灰按质量比例掺入30%以上,混凝土不离析、不泌水,施工和易性优于普通混凝土;力学性能满足公路面层设计要求;180d干缩率小于450×10-6、磨耗量仅为标准限值的60%左右,抗冻等级大于D300。脱硫石膏-粉煤灰混凝土成功应用于常德桃花源-花岩溪旅游公路路面试验段施工,社会经济和环保效益显著。     

系统粉粉色、麸星含量与面片色泽之间的关系

以小麦加工不同系统的20个粉样为原料,研究了系统粉粉色、麸星含量与面片色泽之间的关系.结果表明:麸星含量主要影响面粉的白度,对面片的色泽影响很小,面粉的白度与面片的色泽关系显著.面粉的色泽与面片色泽之间呈显著正相关,尤其是面粉的红度、黄度对面片的色泽影响极大.     

粉煤灰掺量对相同浆体体积比砂浆性能的影响

为了研究粉煤灰掺量对砂浆性能的影响,采用相同浆体体积比,分别以0％、10％、20％和30％的粉煤灰掺量配制砂浆,进行强度和碳化深度对比试验.结果表明,当水胶比一定时,随粉煤灰掺量的增加,砂浆的流动性不会明显降低;早期掺粉煤灰的水泥砂浆的强度会随着粉煤灰掺量的增加而降低,但其后期强度随着龄期的增长会逐渐提高并超过未掺粉煤...     

粉煤灰-脱硫石膏水泥基材料水化活性及微结构

采用DTA—TG、XRD、SEM以及宏观水化收缩和强度试验等手段研究了粉煤灰一脱硫石膏一水泥三元复合胶凝体系的水化过程、活性效应及微观结构等,根据试验结果总结了复合胶凝材料的水化动力学过程。结果表明,粉煤灰一脱硫石膏水泥石的钙矾石吸热峰强于基准样;在各组分相互活性激发和外掺激发剂作用下,粉煤灰一脱硫石膏水泥石中2次水化效应明显;SEM、XRD表明水泥石早期有明显的钙矾石生成,同时粉煤灰颗粒的表面侵蚀现象明显,进一步说明复合胶凝体系的早期活性得到有效激发,硬化后综合性能得到有效保证。且宏观收缩及强度试验也从侧面印证了微观试验结果。粉煤灰一脱硫石膏水泥基复合胶凝材料体系的研发可大量消耗燃煤电厂的工业废渣,具有显著的“绿色”效应。     

Methods of Modifying the Brittle Behavior of Cementitious Composites

We put forward effective methods of increasing the tensile strain of cementitious composites with 2% PVA fiber and high fly ash content. The test results show that curing condition has a significantly effect on the tensile performance. It is approved that the specimens incorporated appropriate volume fraction rubber powder and lightweight aggregate greatly increase the tensile strain of composites at medium-term age, but indefinitely at long-term age. To a certain extent, EVA can limitedly enhance the tensi...     

Effect of silica fume and fly ash on heat of hydration of Portland cement

Results of calorimeter tests on Portland cement-silica fume-fly ash mixtures are presented. Data indicate that silica fume accelerates cement hydration at high water/cementitious ratios and retards hydration at low water/cementitious ratios. On the other hand, fly ash retards cement hydration more significantly at high water/cementitious ratios. When silica fume and fly ash are added together with cement, the reactivity of the silica fume is hampered and the hydration of the cementitious system is significantly retarded.     

粉煤灰作橡胶填料的影响因素

以钛酸酯偶联剂为表面处理荆，对粉煤灰进行表面处理，制得橡胶填料，测试了该填料对橡胶的补强作用。实验表明，表面改性后的粉煤灰对橡胶具有较好的补强作用。可完全替代碳酸钙、碳酸镁或陶土，产生较好的补强效果，用来替代部分发黑，可以减少发黑的用量，降低橡胶的成本。     

Efficiency of mineral admixtures in mortars: Quantification of the physical and chemical effects of fine admixtures in relation with compressive strength

This work is the fourth part of an overall project the aim of which was the development of general mix design rules for concrete containing different kinds of mineral admixtures. The two first parts presented the separation and quantification, by means of an empirical model based on semi-adiabatic calorimetry measurements, of the different physical effects responsible for changes in cement hydration (short terms) when chemically inert quartz powders were used in mortars. Part three dealt with an intensive experimental program, presenting and commenting more than 2000 compressive strength measurements. This program concerned 1 day to 6 months old mortars containing up to 75% of inert and pozzolanic admixtures. All these compressive strength results are analyzed in this fourth part and the influence of three effects, namely dilution, heterogeneous nucleation and the pozzolanic effect, are discriminated and quantitatively evaluated. An efficiency concept is proposed in order to take into account the effect of mineral admixture in mortars from both the physical and chemical points of view. It uses an efficiency function ξ(p) that has notable properties: it is independent of time, independent of fineness and independent of the type of mineral admixture.     

粉煤灰水泥基材料的水化产物

用热重仪-差示扫描量热仪、扫描电子显微镜、透射电子显微镜、X射线能量散射、高分辩电子显微镜、压汞仪,测定了粉煤灰水泥基材料水化产物的形貌特征、微观结构、化学组成及水泥石的孔结构,讨论了水化产物性质及水泥石孔结构随粉煤灰掺量的变化规律。结果表明：粉煤灰的大量掺加,可以改善凝胶的化学组成。水化后期,粉煤灰与Ca(OH)2及由熟料水化生成的高n(Ca)／n(Si)的水化硅酸钙(C—S—H)凝胶发生二次水化反应,生成低n(Ca)／n(Si)的C—S—H凝胶,此种凝胶的固碱能力强,可减少碱-集料反应的危害性。同时,二次水化产物能够填充那些对水泥石强度和耐久性极为不利的孔隙空洞,使水泥石的结构更加致密,优化水泥石的孔结构,对提高水泥基材料的耐久性作用极大,为进一步提高工业废渣利用的技术水平奠定了基础。     

复合型絮凝剂PAFS的研制及性能

本文用钢厂废渣、浓硫酸及粉煤灰为原料制备了聚合硫酸铝铁（PAFS）。在合成中通过正交试验，从中探索了适宜的反应条件。产品经化学分析，鉴定了它的成分和性质。并以黄河水为原水，通过与市售聚铝（PAC）做絮凝对比试验取得了良好的絮凝效果。而且原水的pH值在4．5～9之间，去浊率达到99％以上．