ICP-AES法测定粉煤灰全组分化学元素的研究

采用偏硼酸锂熔样 ,电感耦合等离子体原子发射光谱 (ICPˉAES)法对粉煤灰实现一次熔样 ,全组分同时分析。对影响光谱测量的各种因素进行了较详细的研究 ,确定了最佳测定条件。该法的检出限为 0 .0 0 9～ 0 .83 1μg·ml-1,回收率为 91.5 4%～ 10 4.45 % ,RSD <3 .2 2 %。方法准确、快速、简便 ,用于粉煤灰中全组分测定 ,结果满意。     

面向动用计划的车辆装备备件预测研究

针对动用计划下的车辆装备备件的消耗特点,研究了车辆装备维修备件消耗量和库存控制两个预测优化问题。考虑动用计划期内车辆装备的预防性维修和修复性维修,实现定时定程维修和自然随机故障维修下装备维修备件的消耗量的预测。在此基础上,根据备件库存检查方式的特点,建立基于定期检查策略的联合补货库存控制模型,根据模型的结构特点确定决策变量界限,并利用多类种群位置更新方式改进了果蝇优化算法。仿真结果表明,改进的果蝇优化算法具有良好的求解效率,本文所提出的优化方法可为车辆维修保障资源优化提供决策依据。     

用水量对胶凝砂砾石抗压强度的影响

胶凝砂砾石材料是一新型筑坝材料,拥有广阔的发展前景。用水量是影响胶凝砂砾石强度的重要因素。通过抗压强度试验分析用水量对胶凝砂砾石抗压强度的影响,得出:最优用水量随胶凝材料掺量的增大而增大,随砂率的增大而增大,最优用水量为85~125 kg/m~3;最优水胶比随胶凝材料用量的增加而减小,随龄期的增加呈减小的趋势,最优水胶比为0.95~1.35。用水量对抗压强度的影响仅次于水泥用量,在施工过程中,应将其作为胶凝砂砾石材料的一项重要参数来控制,以保证胶凝砂砾石材料的性能。     

贵州地区粉煤灰种类对长龄期砂浆力学性能与孔隙率的影响

为了区别不同电厂Ⅱ级粉煤灰对长龄期砂浆性能的影响作用,采用贵州地区常见的4种粉煤灰（鸭溪、大方、六盘水和都匀Ⅱ级粉煤灰）,探索各粉煤灰对长龄期砂浆力学性能、孔隙率、吸水率和微观形貌的影响。结果表明：粉煤灰等质量替代水泥后,有利于提高长龄期砂浆的抗折强度和抗压强度,最大分别增大了94.6%和52.1%（鸭溪）、71.6%和49.5%（大方）,100.0%和92.0%（六盘水）以及51.8%和47.6%（都匀）;粉煤灰的掺量越大,砂浆的抗折强度和抗压强度的增加速率越大,孔隙率的降低幅度越大,分别为29.7%（六盘水）、40.0%(鸭溪)、28.7%（都匀）和34.9%（大方）,同时,4种粉煤灰砂浆的最大吸水率分别降低了21.6%（六盘水）、44.0%(都匀)、39.8%（鸭溪）和38.9%（大方）;综合分析发现,养护1 000 d后,粉煤灰仍主要发挥填充作用和火山灰效应,其中活性较低的粉煤灰仍以填充作用为主。     

660MW机组省煤器及脱硝输灰系统改造

马鞍山发电有限公司1、2号锅炉省煤器及脱硝飞灰在基建初期输送至各自渣仓,为使炉底渣与省煤器及脱硝飞灰分离,提高飞灰利用率,故对机组省煤器及脱硝输灰系统进行改造,极大的提高了经济和社会效益。     

粉煤灰负载钒氧化物低温SCR催化剂脱硝性能研究

目前,我国电厂普遍采用SCR法高含尘工艺对烟气中的NOx进行脱硝,催化剂存在严重堵塞、中毒等问题,SCR法低含尘工艺越来越引起重视。为了制备SCR法低含尘工艺中的低温SCR脱硝催化剂,本文将钒氧化物负载在粉煤灰和膨润土混合制成的复合材料载体上,制成V2O5/FA-BT催化剂,同时分别用全自动比表面及孔隙度分析仪(Micromeritics Tristar 3 000)和扫描电子显微电镜(SEM)对催化剂的比表面积和表面形貌进行表征。结果表明:不同V2O5负载量的V2O5/FA-BT催化剂在低温下有很好的脱硝效果,其中以V2O5负载量(质量分数)为11%的V2O5/FA-BT脱硝效果最好,当反应温度为130℃时,脱硝率达到89%;对催化剂进行酸改,CH3COOH酸改的催化剂比表面积较大且脱硝效果最好。     

Comparisons of Fly Ash and Deposition Between Air and Oxy-FuelCombustion in Bench-Scale Fluidized Bed with Limestone Addition

In Oxy-fuel circulating fluidized bed, the residual CaO particles may react with high concentration of CO₂ in flue gas to form bonded deposit on heat transfer surfaces in backpass when limestone is used as a sorbent to capture SO₂.In this paper, experiments were designed on ash deposition in a bench-scale fluidized bed under oxy-fuel and air atmosphere. A novel ash deposit sampling probe was used to simulate the tubes of tail surfaces. The chemical composition of fly ash and ash deposit from both air-firing and oxy-fuel firing cases were analyzed by Inductively Coupled Plasma-Atomic Emission Spectrometry(ICP-AES) and Scanning Electron Microscopy(SEM), respectively. The degrees of carbonation reaction of ash deposits were measured by Thermo Gravimetric Analysis. The results showed that there are distinct differences in fly ash deposition rate between oxy-fuel and air firing cases, and oxy-fuel combustion with limestone addition can affect chemical composition of fly ash and ash deposit, especially for elements of Ca, Na, K, and S. However, the carbonation reaction degree of ash deposits is found weak, which is due to the relatively low CaO content in ash deposit or not long enough of the sampling time.[JP]     

粉煤灰悬浮胶体的悬浮稳定性实验研究

针对煤矿生产中粉煤灰防(灭)火材料管路输送的管路阻塞问题,选择SC1,SC2,SC3,SC4,SC5,SC6,SC7和SC8共8种悬浮剂,配制成4种质量分数分别为0.5%,1.0%,1.5%和2.0%的粉煤灰悬浮胶体,采用沉降分析方法,研究其悬浮稳定性。结果表明:各粉煤灰悬浮胶体沉降速率出现类似"L型"变化,沉降到一定时间均达到平衡状态;悬浮剂可以减小粉煤灰悬浮体沉降速率变化,质量分数越低,初始沉降速率越大,质量分数越高,沉降速率变化越小;同时也可增大粉煤灰悬浮率,增加悬浮胶体的稳定性。     

Comparison of hydration properties between cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder

The hydration properties of cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder were compared. The experimental results show that the hydration rate of cement-GGBS- steel slag blended binder is higher than that of cement-GGBS-fly ash blended binder within 28 days, but lower than the latter after 28 days. The hydration of cement-GGBS-steel slag blended binder tends to produce more Ca（OH）2 than the hydration of cement-GGBS-fly ash blended binder, especially at late ages. Cement-GGBS- steel slag mortar exhibits higher strength than cement-GGBS-fly ash mortar within 28 days, but at late ages, it exhibits similar compressive strength with eement-GGBS-fly ash mortar and even slightly lower bending strength than cement-GGBS-fly ash mortar. Cement-GGBS-steel slag paste has finer early pore structure but coarser late pore structure than cement-GGBS-fly ash paste. Cement-GGBS-steel slag paste can get satisfied late pore structure and cement-GGBS-steel slag mortar can get satisfied late strength as compared with pure cement paste and pure cement mortar, respectively.     

Effect of curing conditions on the hydration and performance of CFBC ash cementitious system

Circulating fluidized bed combustion （CFBC） ash can be used as supplementary cementitious material for concrete production for its high pozzolanic activity. We investigated the effect of curing conditions on the hydration and performance of CFBC ash-Portland cement system （30： 70, by mass） including hydration products, paste microstructure, linear expansion ratio, chemically combined water content and compressive strength. The results show that tobermorite rather than ettringite is generated under the condition of autoclaved curing. The expansion and mortar strength of the system cured in water is higher than those cured in air at a given age, and the strength and bulk volume may retract under the condition of air curing. In addition, autoclaved curing facilitates the increase of strength gain at early curing ages （the increase rate lowers down in the following ages） and the improvement of system volume stability. It is suggested that sufficient water is necessary for the curing of CFBC ash cementitious system, and autoclaved curing may be considered where volume stability is a primary concern.