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31.
The temperature dependence of the viscosity of the undercooled melts exhibits an important role in the study of nucleation,
crystal growth and the glass-forming ability of materials. Several attempts have been made to study the viscous behaviour
of the glass-forming melts and these investigations are mainly based on free volume theory as well as on the configurational
entropy model. In the present investigation, an attempt has been made to correlate the thermodynamic parameters with the viscosity
of the glass-forming melts and to study the temperature dependence of the viscosity of undercooled liquids on the basis of
the free volume theory as well as on the basis of the configurational entropy model of Adam and Gibbs. The entire study is
confined on the expression for thermodynamic parameters reported by the authors recently. The expression obtained has been
successfully applied to study the temperature dependence of the viscosity of the metallic, molecular and oxide glass-forming
liquids. 相似文献
32.
镀锌层上有机物无铬钝化涂层的耐蚀性 总被引:23,自引:9,他引:14
选择了一种无毒的水溶性丙烯酸树脂(AC)加入至钼酸盐、磷酸盐中(M)得到一种钝化液(ACM),对镀锌层进行钝化处理以代替有毒的铬酸盐钝化。通过盐雾试验、扫描电镜、电化学测试等手段,研究了该纯化膜的耐蚀性及耐蚀机理。结果表明,热浸镀锌层采用该无毒钝化液进行钝化,可以推迟镀锌层出现白锈的时间,其抗蚀性已接近铬酸盐钝化水平;ACM钝化膜耐蚀性的提高是由于钝化膜中的钼酸盐与丙烯酸树脂产生交联作用,抑制钝化膜裂纹的扩展,同时由于膜层中钼酸盐的缓蚀作用,提高了镀锌层的抗蚀性。 相似文献
33.
催化氧化法合成脂肪醇醚羧酸盐的研究进展 总被引:2,自引:0,他引:2
详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20~60℃,反应时间3~6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50~90℃反应2~6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95%,选择性达90%以上。 相似文献
34.
35.
Xiuming Huang 《Machine Translation》1988,3(2):101-120
This paper concerns the resolution of lexical ambiguity in a machine translation environment. We describe the integration of principles of selection restrictions. Preference Semantics, and intelligent relaxation of constraints in handling lexical ambiguity. The approach differs from many previous MT systems in that it is more powerful than brute force systems, while more realistic than systems that assume a large degree of coded encyclopedia information for full understanding. 相似文献
36.
S. L. Oswal R. G. Sindhe A. T. Patel J. P. Dave S. G. Patel B. M. Patel 《International Journal of Thermophysics》1992,13(4):617-628
Viscosities of several mono-, di-, and trialkylamines have been measured in the temperature range 298 to 333 K. It is observed that viscosities are highly dependent on shape, size, and association through H-bond or through dipole. Following the transition state theory, energy, Gibbs free energy, and entropy of activation of viscous flow have been calculated. The values of expansion energy for these liquids have also been calculated using free volume theory, and subsequently amines have been classified as volume-restrained or energy-restrained liquids. The group contribution method of Van Velzen, Cardozo, and Langenkamp for estimating viscosity has been examined with the present and literature data, and the new group contribution increments N
i and B
i for amines have been evaluated. 相似文献
37.
The specific heat at constant pressure, C
p, of aluminum measured by Ditmars, Plint, and Shukla has been reduced to the volume V
0 appropriate for 0 K employing the Murnaghan equation. The C
v0 thus obtained is compared with the theoretical C
v0 calculated in the harmonic and the lowest-order anharmonic approximation from three different pseudopotentials (Harrison, Ashcroft, and Dagens-Rasolt-Taylor) as well as a phenomenological Morse potential. The higher-order (
4) anharmonic contributions are calculated from the same nearest-neighbor Morse potential as in the lowest-order anharmonic theory. The role of the vacancy and the higher-order anharmonic contributions to C
v0 has been examined and we conclude that the
4 contributions to C
v0 are much smaller than the vacancy contribution. After removal of the vacancy contribution, the reduced C
v0 is found to be in excellent agreement with the Ashcroft and Harrison pseudopotentials as well as the Morse potential including the
2 and
4 contributions to C
v0. 相似文献
38.
39.
Autism spectrum disorder (ASD) is a heritable neurodevelopmental condition associated with impairments in social interaction, communication and repetitive behaviors. While the underlying disease mechanisms remain to be fully elucidated, dysfunction of neuronal plasticity and local translation control have emerged as key points of interest. Translation of mRNAs for critical synaptic proteins are negatively regulated by Fragile X mental retardation protein (FMRP), which is lost in the most common single-gene disorder associated with ASD. Numerous studies have shown that mRNA transport, RNA metabolism, and translation of synaptic proteins are important for neuronal health, synaptic plasticity, and learning and memory. Accordingly, dysfunction of these mechanisms may contribute to the abnormal brain function observed in individuals with autism spectrum disorder (ASD). In this review, we summarize recent studies about local translation and mRNA processing of synaptic proteins and discuss how perturbations of these processes may be related to the pathophysiology of ASD. 相似文献
40.
Sevinj Sultanli Soni Ghumnani Richa Ashma Katharina F. Kubatzky 《International journal of molecular sciences》2021,22(5)
Plumbagin is a plant-derived naphthoquinone that is widely used in traditional Asian medicine due to its anti-inflammatory and anti-microbial properties. Additionally, plumbagin is cytotoxic for cancer cells due to its ability to trigger reactive oxygen species (ROS) formation and subsequent apoptosis. Since it was reported that plumbagin may inhibit the differentiation of bone resorbing osteoclasts in cancer-related models, we wanted to elucidate whether plumbagin interferes with cytokine-induced osteoclastogenesis. Using C57BL/6 mice, we unexpectedly found that plumbagin treatment enhanced osteoclast formation and that this effect was most pronounced when cells were pre-treated for 24 h with plumbagin before subsequent M-CSF/RANKL stimulation. Plumbagin caused a fast induction of NFATc1 signalling and mTOR-dependent activation of p70S6 kinase which resulted in the initiation of protein translation. In line with this finding, we observed an increase in RANK surface expression after Plumbagin stimulation that enhanced the responsiveness for subsequent RANKL treatment. However, in Balb/c mice and Balb/c-derived RAW264.7 macrophages, these findings could not be corroborated and osteoclastogenesis was inhibited. Our results suggest that the effects of plumbagin depend on the model system used and can therefore either trigger or inhibit osteoclast formation. 相似文献