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1.
The motional transition and heterogeneity of semi‐interpenetrating networks (SIPNs) based on polyurethane (PU) with carboxylic groups and methacrylic copolymer (PM) with tertiary amine groups were studied by the electron spin resonance (ESR) spin probe method. The concentration of functional groups in both prepolymers varied from 0 to 0.45 mmol g?1. Spin‐probed SIPNs show that the temperature‐dependent spectra are sensitive to polymer interactions imposed by functional groups. These interactions determine the free volume distribution in the matrix and temperature at which motional transition takes place. The fraction of free volume increases with functional group concentration and reaches its maximum at 0.25 mmol g?1. Further increases in the functional group concentration reduce the free volume. The results of the networks with strong interactions are discussed in terms of the interference of the plasticizing effect of the PU component and the formation of possible cluster cross‐links, which restricts segmental motions. Copyright © 2003 Society of Chemical Industry 相似文献
2.
A general numerical model is described for the dissolution kinetics of spherical particles in binary systems for any combination of first order reactions at the particle-matrix interface and long distance diffusion within the matrix. The model is applicable to both finite and infinite media and handles both complete and partial particle dissolution. It is shown that interfacial reactions can have a strong effect on the dissolution kinetics, the solute concentration at the particle-matrix interface and the solute concentration profile in the matrix. 相似文献
3.
César I. Beristain Ebner Azuara Hugo S. Garcia & Eduardo J. Vernon-Carter 《International Journal of Food Science & Technology》1996,31(5):379-386
The water and oil uptake of mesquite and arabic gums in powdered form was studied at temperatures of 23, 35 and 45°C. A previously proposed equation to predict osmotic equilibrium was tested using the experimental data with both gums and a good statistical fit was obtained. Mesquite gum showed the highest water and oil absorption at all temperatures studied. Temperature dependence of the reciprocal of the S1 and WL∞ were determined using an Arrhenius equation. The activation energy for water and oil absorption for gum arabic was 21.98 and 39.57 kJ mol−1 , compared to that of mesquite gum having values of 15.79 and 46.16 kJ mol−1 , respectively. A second order kinetic model was obtained for water and oil absorption for both gums. 相似文献
4.
本文提出了激光功能微调技术在高精度混合集成电路上的应用,讨论了关键技术问题,并以实例具体说明。该技术的应用为研制高精度混合集成电路开辟了新途径。 相似文献
5.
6.
William Kent 《Computer Standards & Interfaces》1991,13(1-3):201-206
OSQL is the object-oriented database language developed for the Iris object-oriented database management system at Hewlett-Packard Laboratories. Its three fundamental constructs are objects, types, and functions. This paper provides an overview of the underlying concepts and some important features of OSQL. 相似文献
7.
Summary Recent progress in the modelling of exchanged Cu sites and their interactions with small molecules, based on DFT cluster calculations, is briefly reviewed. 相似文献
8.
SW233 PIN驱动器自动测试系统的研制 总被引:1,自引:0,他引:1
介绍了一种集成电路自动测试系统,该系统采用计算机并口作通信接口,用VB6编程,实现了对外围测试电路的控制,用IEEE-488接口卡控制测试仪器,可对SW233电路的36个参数进行自动测试,并将测试结果自动保存在数据库中。该测试系统具有自动化程度高、操作方便、测试结果精确等特点。 相似文献
9.
B. E. Rytsar 《Cybernetics and Systems Analysis》2007,43(2):192-207
The paper considers the set-theoretical approach to the joint decomposition of systems of Boolean functions of variables specified
in different representation forms. The approach is based on the method of q-partitions of conjuncterms and concept of decomposition
clones. Theorems on joint decomposition of a system of full and partial functions are formulated. The approach is illustrated
by examples.
Parts I and II of this article are published in No. 5 (2001) and No. 1 (2002).
__________
Translated from Kibernetika i Sistemnyi Analiz, No. 2, pp. 39–58, March–April 2007. 相似文献
10.
DS2000-M1是高性能、开放式的LED控制系统,本文从软硬件两方面简述其设计原理。 相似文献