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Fluorinated amorphous hydrogenated a-C:F:H carbon thin films were deposited using radio frequency plasma enhanced chemical vapor deposition(RF-PECVD) reactor with CF4 and CH4 as source gases and were annealed in a N2 atmosphere. The properties of these films were evaluated by FTIR spectrometry, UV-VIS spectrophotometry and single-wavelength spectroscopic ellipsometry. A correspondence relativity connection between the deposition rate and technology was found. The chemical bonding structures and the content of CHx and CFx in the films are transformed and the optical band gap decreases monotonically with increasing temperature after annealing.The dielectric constant is increased with decreasing content of F in the films and the optical band gap is decreased with decreasing the content of H in the film. 相似文献
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Y.S Wong M Rahman H.S Lim H Han N Ravi 《Journal of Materials Processing Technology》2003,140(1-3):303-307
Similar to EDM, in micro-EDM, intense heat is generated between the workpiece and tool electrode by the discharge through a dielectric medium to result in the formation of a microcrater that is much smaller in size. In this study, a single-spark generator has been developed to study the erosion characteristics from the microcrater size. Using a simple heat transfer model, the efficiency at different discharge condition is also deduced. It is found that at lower-energy (<50 μJ) discharges, the energy required to remove the unit volume of material, defined as the specific energy, is found to be much less than that at higher-energy discharges. Additionally, the ratio of the standard deviation to the measured microcrater size is found to be lower at lower discharge energy, indicating greater consistency in shape and size when the discharge occurs at lower energy. The fundamental erosion mechanism of material is discussed by considering melting and evaporation phenomena using theoretical modeling. The average efficiency of erosion, when estimated to be due primarily to melting or evaporation alone, is found to be up to an order of magnitude higher at lower-energy discharges than that at higher-energy discharges. 相似文献
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针对经典联合树推理算法的信息传播共享和推理时间等问题, 提出一种高效联合树推理算法. 该算法基于获得的证据信息和查询节点对原始的网络结构化简, 然后在化简后的网络结构上进行联合树推理. 在信息传递过程中, 该算法可以实现不同证据下的信息共享. 经仿真验证, 高效联合树算法能够在保证准确率的同时, 以更短的时间作出诊断推理. 基于现场收集的数据, 建立水泥回转窑故障诊断系统模型并应用改进的算法实现了精准且快的故障诊断.
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Density functional theory (DFT) studies on adsorption of several gaseous homo- and hetero-diatomic molecules (AB) including H2, O2, N2, NO and CO on external surface of H-capped pristine armchair (5, 5) single-walled carbon nanotube (SWCNT) were conducted. Structures of C70H10 and the corresponding C70H10–AB adducts were fully optimized at the B3LYP/6-311G* level of theory. Calculated HOMO/LUMO energy gaps (Eg), 13C NMR chemical shifts and IR/Raman parameters were analyzed and critically compared with available experimental data. Significant changes of carbon NMR atom chemical shifts (up to −100 ppm) and shielding anisotropies (up to −180 ppm) at sites of addition were observed. Functionalized SWCNTs produced IR and Raman spectra different from the pristine nanotube model. The selective changes in vibrational spectra will help in assigning the topology of functionalization at the nanotube wall. 相似文献
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Artificial neural networks modeling have recently acquired enormous importance in microwave community especially in analyzing and synthesizing of microstrip antennas (MSAs) due to their generalization and adaptability features. A trained neural model estimates response very fast, which is nearly equal to its measured and/or simulated counterpart. Thus, it completely bypasses the repetitive use of conventional models as these models need rediscretization for every minor changes in the geometry, which itself is a time‐consuming exercise. The purpose of this article is to review this emerging area comprehensively for both analyzing and synthesizing of the MSAs. During reviewing process, some untouched cases are also observed, which are essentially required to be resolved for antenna designers. Unique and efficient neural networks‐based solutions are suggested for these cases. The proposed neural approaches are validated by fabricating and characterizing of the prototypes too. © 2015 Wiley Periodicals, Inc. Int J RF and Microwave CAE 25:747–757, 2015. 相似文献
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