Dynamics of hydrated iron(II) cations in nafion polymer membranes

Mössbauer studies of Fe²⁺ in water-soaked nafion polymer membranes in the temperature range between 90 K and 250 K have been performed. Above a critical temperature (～ 180 K) the spectra exhibit both elastic narrow absorption lines and quasielastic broad lines. These spectra are typical of bounded diffusion phenomena observed by Mössbauer spectroscopy in macromolecular systems like haemoglobin, myoglobin and ferritin. Similar spectral shapes have been observed by quasielastic neutron scattering from water in nafion membranes. Within 50 K above the critical temperature the total Mössbauer absorption area decreases by an order of magnitude whereas the narrow absorption line decreases by two orders of magnitude. The results are interpreted in terms of bounded diffusive motion of the iron. Using a model based on overdamped harmonically bound Brownian motion, the essential parameters of the iron motion can be derived as a function of temperature. The iron motion most probably reflects the motion of a large Fe²⁺ complex, e.g. Fe(H₂O)²⁺₆, which is attached to the polymer side chains via the sulphonic group.     

拉伸速率对PP/GB复合材料力学性能的影响

应用Instron材料试验机考察了室温下拉伸速率对玻璃微珠填充聚丙烯复合材料的弹性模量和屈服强度的影响，结果表明，随着微珠含量的增加，试样的弹性模量（Ec）增大，且与拉伸应变速率呈近乎幂律函数关系，而屈服强度（бyc）则随着微珠体积分数（Φf）的增加呈线性函数形式下降，并随着拉伸应变速率的增加呈幂律函数形式提高，此外，讨论了Ec、Φf与бyc三者之间的关系。     

Sol-gel processing: A versatile concept for special glasses and ceramics

The various parameters related to sol-gel processing are discussed with special reference to those which usually attract less attention but depending on the final product in mind, can play important roles. The versatility of the sol-gel technique in materials preparation is demonstrated by discussing the various products developed at the author’s laboratory by using this processing method.     

改性玻纤增强尼龙610,1010塑料

研究了采用(准)中粘度级尼龙做基体树脂,加入成核剂改善尼龙的结晶过程,提高结晶速率和初始熔融温度;添加光、热氧稳定剂,防止尼龙在成型加工和使用过程中产生降解与老化,提高塑料制品的质量和减少性能的分散性;采用合理的工艺条件,确保添加剂的均匀分散与减少玻纤的磨损,得到适于军工、航空和机电等领域需要的高性能的受力结构工程塑料。     

Effects of Substrate Temperatures on the Structure and UV-shielding Properties of TiO_2-CeO_2 Films Deposited on Glass by Radio-frequency Magnetron Sputtering

1Introduction Theultravioletrays(UV)insunlight(-4%)cantransmitintoroomthroughcommonfloatglass,theUVcanmakethematerialsintheroom,eg,paper,furni ture,textilefabricandplastics,becoloredanddeterio rated.ShieldingfromUVirradiationisofinterestinmanyfields.Formu…     

锆钡镧铝氟化物玻璃的分相研究

本文综述了氟化物玻璃中的分相研究。在前人研究基础上应用透射电镜，X射线能谱，电子能量损失谱及X射线衍射，差热分析等研究了锆钡镧铝氟化物玻璃中的液-液分相，发现此种现象普遍存在于该类玻璃之中。对玻璃成分与分相形貌及微观结构之间的关系、对析出晶相种类及分相与析晶的相互影响进行了研究。提出欲降低氟化物玻璃的光损耗，分相与析晶一样是不容忽视的因素。     

磷酸盐玻璃中Er~(3+)离子的光跃迁和激光作用

给出了Li-Al磷酸盐玻璃中Er~(3+)离子发射特性(Ar、σ_ρ、β、τ_γ)的计算结果。报道了Cr~(3+)→Yb~(3+)→Er~(3+)的一种有效能量转移,并获得了室温下3J1.54μm波长的激光输出。     

水工钢闸门聚酯玻璃钢复合防腐处理方法

水环境的恶化，使水工钢闸门腐蚀加重，传统的防腐工艺保护效果下降。聚酯玻璃钢复合防腐层的水工钢闸门防腐工艺具有使用设备少，工艺简单、防腐效果好、成本低等优点，适用于在各种水环境中作各种形式的水工钢闸门防腐，效果良好。该文结合江苏省淮海农场工程施工经验，提出了水工钢闸门聚酯玻璃钢复合防腐层结构设计、施工工艺及质量标难，为今后的推广应用提供了一定的参考依据。     

Acoustic study of nano-crystal embedded PbO-P2O5 glass

Nano-crystal embedded PbO-P₂O₅ glass has been prepared and characterized by XRD and TEM measurements. The ultrasonic velocity and attenuation measured within the temperature range 80–300 K show significant structure and interesting feature with the presence of nano-crystalline region. The glass samples were prepared by melt-quench method and nano-crystals of different sizes were produced by heat treatment of the glasses for different durations of heating. All the processes were carried out at or above glass transition temperature. A theoretical model that takes account of the effects of thermally activated relaxation, anharmonicity as well as microscopic elastic inhomogeneities arising out of fluctuations has been successfully applied to interpret the variation of ultrasonic velocity and attenuation data. An interesting outcome of this application has been to propose a method for the determination of the size of nano-crystals from the ultrasonic attenuation data.     

Role of Specimen Geometry in the Effect of Fiber Orientation on the Thermal Conductivity of a Uniaxial Carbon-Fiber-Reinforced Aluminoborosilicate Glass-Matrix Composite

A study concerning the effect of fiber orientation on the thermal conductivity of a uniaxial carbon-fiber-reinforced borosilicate glass was conducted. For thin specimens, and thick specimens with specimen sides cut parallel to the fiber direction, the dependence of thermal conductivity on fiber orientation showed excellent agreement with theoretical behavior predicted for a composite infinite in extent. In contrast, the thermal conductivity data for rectangular thick specimens fell well below the data for the thin and angled specimens. For fiber orientation of 45° and higher, at which the heat was directed toward the side of the specimen rather than across, the thermal conductivity values showed excellent agreement with theoretical behavior predicted for a finite composite strip with insulated sides.