Nano Sized Copper Selenide Thin Film Pre-Cursor by A Liquid Phase Chemical Growth Process

The deposition of copper selenide(CuSe)thin films was carried out using liquid phase chemical bath deposition process at the optimized growth parameters as:60℃deposition temperature,90 minutes deposition time,pH equal to 10.5±0.1 and 72±2 r/min speed of mechanical rotation.The as-grown deposits exhibited excellent uniformity and physical adherency with the substrate surface and are smooth and diffusely reflecting with colour changing from yellowish orange to dark chocolate during deposition.The layer is of the order of 300 nm thick.The EDS analysis technique gave film composition to be nearly stoichiometric(Cu=47.89%,Se=52.11%).An X-ray diffraction analysis showed CuSe to be polycrystalline hexagonal with a good match of d-values and intensities of reflections.The crystallite size is in the nanorange(50-60 nm).The as-deposited CuSe exhibited a high coefficient of absorption(α=105cm-1)with a direct optical band gap of 1.81 eV.Compared to other chalcogenides,CuSe films exhibit low resistance;room temperature electrical resistivity being 1.55×103?cm.The electrical conductivity decreased with increase in temperature up to 473 K;showing totally unusual behaviour from that of the semiconducting property.The thermo probe measurements showed n-type conduction of the samples.     

Oleogels from Glycerol‐Based Lyotropic Liquid Crystals: Phase Diagrams and Structural Characterization

In the course of our studies on structured reverse lyotropic liquid crystals (LLC) as oleogels, a system was designed with the desired physical and rheology properties for cosmetic and pharmaceutical applications. The aqueous phase was partially replaced by glycerol to minimize bacteriological problems and obtain specific rheology characteristics. The constructed phase diagrams are based on ternary mixtures of glycerol monooleate (GMO), decane, water, and glycerol. The main lyotropic mesophase obtained in this study was reverse hexagonal derived from dilution line 8:2 (72 wt% GMO and 18 wt% decane) and 10 wt% water; or water:glycerol (wt ratios 3:1 and 1:1) mixture. It was found that heat‐cool fluctuation caused formation of new pseudo‐equilibrium structures with mesomorphic transformations to more fluid and less ordered mesostructures. Replacing up to 50 wt% of the water by glycerol significantly increases the gel phase region in the phase diagram, meaning more structural compositional options. The structural parameters were determined using cross‐polarized light microscopy (CPLM), differential scanning calorimeter (DSC), powder X‐ray diffraction (PXRD), and small angle X‐ray scattering (SAXS). Rheological measurements revealed viscoelastic properties of lyotropic liquid crystals with a decrease in the elasticity (G′), plasticity (G″), and complex viscosity (η*), as a function of increasing the glycerol content.     

阀体流道孔清理的一种新方法

液压阀体及阀板零件中存在许多交叉孔道,为了能加工出交叉孔就从零件结构上增加了一些工艺孔,加工完毕后焊堵堵死,但是这给交叉孔道的清理增加了困难。在生产实际中,为了便于清理这些交叉孔道内的残留物,建议设计将焊堵的结构改成丝扣的结构,安装上调垫及内六角螺塞,再进行水压试验,保证安装紧密。     

紫砂造型艺术中直线和六方的韵律——简析“六方抽角壶”的形态结构与视觉感应

通过分析直线的性质和"六方抽角壶"的形态结构,探讨直线应用在紫砂光素方器中所产生的节奏韵律,以艺术审美的评判标准论证"六方抽角壶"刚柔并济、虚实相间、层次递进的视觉感应。     

异型六边形斜管沉淀器在工业废水中的应用

斜板(管)沉淀装置是工业废水处理技术中的基本操作单元,在国内外获得广泛应用,但近年来六边形蜂窝斜管除材质外,管型及工艺性能几乎没有变化,长期处于停滞状态.试验表明一种新型异型六边形斜管具有沉淀面积和沉淀效率大于六边形蜂窝斜管的特性.     

脉冲激光沉积方法生长硅基ZnO薄膜的特性

用脉冲激光沉积法(PLD)在n型硅(111)平面上生长ZnO薄膜.X射线衍射(XRD)在2θ=34°处出现了唯一的衍射峰,半高宽为0.75°;傅里叶红外吸收(FTIR)在414.92cm-1附近出现了对应Zn-O键的红外光谱的特征吸收峰;光致发光(PL)测量发现了位于370和460nm处的室温光致发光峰;扫描电子显微镜(SEM)和选区电子衍射(SAED)显示了薄膜的表面形貌以及晶格结构.利用PLD法制备了具有c轴取向高度一致的六方纤锌矿结构ZnO薄膜.     

Pd/Ce-HMS介孔材料的结构和表面化学态

为了制备新型负载型Pd催化剂,采用合成后组装法和浸渍法室温合成了Pd/Ce-HMS介孔材料,产物用XRD、N2吸附、FTIR及XPS谱等手段进行表征。结果表明,Ce、Pd引入后六方介孔结构仍保持完好。产物的BET表面积为742.9 m2·g-1,孔容0.803 cm3·g-1,表面Pd、Ce物种主要以PdO2和CeO2形式存在。研究表明,Ce前驱体通过与孔表面富集的Si—OH基团作用而嵌入骨架或键合于孔表面,Pd担载时由于模板剂仍留在孔道中,因而没有造成孔道堵塞。     

准八面体CBN单晶的合成研究

通过对原料、触媒及合成工艺的研究,采用国产DS-029B型六面顶压机在4．2—5．3GPa,1350。1470℃的范围内,从hBN-单质触媒体系中合成出近乎完美的黑色八面体和截角八面体立方氮化硼单晶体。确定了该种形态的CBN晶体的生长区域。CBN晶体的尺寸在100—400μm,峰值粒度为125—150μm。对所得的晶体进行考察,发现这种CBN晶体结晶形貌发育比较完整、棱角尖锐、晶粒饱满,并且有较高的抗压强度。上述结果表明所用的单质触媒具有使CBN晶体均匀生长的能力,是一种合成CBN晶体的有效触媒,该种CBN晶体具有较好的破碎强度。     

彩色图像三维六边形离散余弦变换编码

为了适应人眼视网膜细胞的正六边形结构的排列方式并充分利用彩色图像各颜色分量间的相关性,提出了一种基于六边形采样的三维离散余弦变换方法。该方法根据传统的矩形采样和正六边形采样之间的关系来完成两者的转换; 然后在已有的六边形离散余弦变换的基础上提出三维六边形采样的离散余弦变换,并验证它的能量集中性。最后,在同一个模型下建立彩色图像的空间位置和颜色分量,并利用提出的方法分别以不同的子图大小对不同的图像进行整体变换。实验结果表明：相对于传统的矩形采样,提出方法的压缩比提高了约51.1%,峰值信噪比提高了约16.3%,从而有效地降低了彩色图像各颜色分量间的相关性。得到的结果表明,利用六边形采样技术可以提高采样率,降低编码速率。