国内CSP产品质量与控制

分析了国内CSP厂生产热轧薄板的产品主要质量问题及产生原因 ,对生产过程中的质量控制措施进行了概述。     

铁通资源管理系统的设计和实现

在分析铁路通信资源结构的基础上,利用地理信息系统技术、数据库技术和客户/服务器(C/S)模式,为铁通(ChinaTietong)各级分公司和运营部门提供一套较为完善的资源管理信息系统。文中分析了铁通资源的结构与资源之间的关联,介绍了系统功能、物理结构及体系结构,详细分析了数据库设计、地理信息系统和系统安全性所采用的关键技术。这套系统的应用对铁通网络管理的现代化将起到重要的推动作用。     

Ideally selective diisocyanate building blocks: New perspectives for dendrimers and coating binders

Using zirconium (IV) salts as catalyst, the reaction of a diisocyanate carrying one tertiary and one primary isocyanate group (IMCI, DIMP) with alcohols can be conducted with complete regioselectivity. This unique selectivity enables the use of a diisocyanate building block in unprecedented ways. Incomplete regioselectivity of diisocyanates, as commonly encountered in currently commercial ones like IPDI and TDI, inevitably leads to polydisperse products in reaction with polyols. The ultimate monodisperse polymer architecture, dendrimers, can now be made in a facile, straightforward manner using IMCI as the ideal diisocyanate building block. Coating applications of this unique building block are not restricted to these perfect branching polymers, but also include isocyanate-functional coating resins. Without any increase in polydispersity, a hydroxyl-functional polyester can be end-capped with the IMCI diisocyanate and subsequently serve as a crosslinker in powder coatings.     

热丝辅助ECR CVD制备cBN薄膜

立方氮化硼(cBN)是一种具有广泛应用价值的Ⅲ-Ⅴ族二元化合物，其优异性质可与金刚石相比拟或胜之．立方氮化硼的制备与性能研究是近二十年来材料领域关注的焦点之一．我们用热丝辅助ECR CVD方法制备了cBN薄膜，并初步探讨了热丝对cBN形成的作用．偏压并不是cBN形成的唯一主要条件，活性粒子也有非常关键的作用．     

In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

Surface structural change of ZnO-coated LiNi0.5Mn1.5O4 spinel as 5 V cathode materials at elevated temperatures

LiNi_0.5Mn_1.5O₄ powder was synthesized via sol-gel method and coated with ZnO in order to test the electrochemical cyclability of the material as a cathode for the secondary Li battery in the 5 V range at 55 °C. The ZnO-coated LiNi_0.5Mn_1.5O₄ powder nearly maintained its initial capacity of 137 mA h g⁻¹ after 50 cycles whereas the uncoated powder was able to retain no more than 10% of the initial capacity after 30 cycles. TEM analysis of the cycled cathodes suggests that the formation of the graphitic surface phase, hindering the Li migration, may be responsible for the rapid capacity loss of the uncoated material while no such phase was observed on the surface of the ZnO coated LiNi_0.5Mn_1.5O₄ powder.     

埋地管道三层PE外覆盖层及其检测方法研究

文章介绍了埋地管道三层PE外覆盖层系统的构造参数和性能特点,论述了两种用于埋地钢质管道外覆盖层状况检测的方法,一种是多频管中电流法,另一种是DCVG/CIPS组合检测技术。分别介绍了两种方法的工作原理、操作方法和设备,并结合工程实例进行了说明。这些方法和设备可分别或同时用于管道不开挖检测防腐层破损点的位置以及漏点大小。     

纳米涂层的研究现状与展望

简述了纳米表面涂层制备工艺的研究现状，分析了气相沉积、热喷涂、电刷镀、化学镀和电沉积等不同工艺在制备纳米表面层中的应用情况。介绍了纳米涂层在超硬耐磨、耐腐蚀、耐高温热稳定性等方面研究的新进展，并对纳米涂层的应用范围和领域作了展望。     

焚烧炉控制系统

化工废气、废液焚烧炉是一种常用的环保处理装置，就其工艺详细介绍焚烧炉燃烧过程的控制及其安全联锁措施。     

核壳乳液聚合中甲基丙烯酸用量对印花制品的影响

采用核壳乳液聚合法合成涂料印花粘合剂，考察了甲基丙烯酸(MAC)用量的改变对印花产品的牢度和色光的影响：在核中，当MAC的用量分别为0．0g，0．2g，0．4g，0．6g时，干摩牢度分别为25，2．5 ，3,0，3．5，色光由暗变亮；在壳中当MAC的用量分别为0．0g，0.2g，0．4g，0．6g时，干摩牢度分别为2.5，2．5 ，3．0，3．5，色光变亮，对得色量和鲜艳度影响不大。