规模化电动汽车充电对配电网电缆老化的影响

电动汽车规模化且带有随机特性的充电行为将给城市电网运行和维护带来新的挑战。提出了计及充电随机特性的电动汽车充电负荷模型,考虑了电动汽车接入水平、用户出行和充电习惯,在此基础上,研究了规模化电动汽车充电对配电网电缆老化的影响。所提出的电缆老化模型计及了不同季节、不同环境下每一负荷周期内电缆所承受电应力、热应力的随机特性,提高了电缆剩余寿命估算的准确性,解决了规模化电动汽车入网后如何确定电缆寿命所受影响这一技术难题。     

一种油浸式电力变压器纸绝缘老化评估新特征量

针对油中糠醛含量随变压器运行时间变化的分散性较大,难以准确评估油浸式变压器纸绝缘老化状态的不足,对甲醇、乙醇等低分子醇作为变压器纸绝缘老化评估新特征量进行了理论分析与实验研究。对绝缘纸的老化机理以及化学键断裂进行分析,从理论上探究甲醇、乙醇等低分子醇的产生原理及主要生成途径。采用气相色谱-质谱联用法对现场2台老旧变压器绝缘油样品中的甲醇、乙醇及糠醛含量进行了测定。实验结果表明,2组样品中均未检测到糠醛,但却检测到数量可观的乙醇。进一步地,对现场2台刚投运变压器的检测结果对比分析,分析结果揭示了乙醇可以作为一种有效表征变压器绝缘纸老化的新特征量,且比糠醛特征量相比更为有效。     

Effects of Moisture on Furfural Partitioning in Oil-Paper Insulation System and Aging Assessment of Power Transformers

The furfural concentration in oil is a well-accepted chemical marker indicating the aging condition of power transformers. However, recent researches suggest that the furfural concentration in oil is affected by moisture, because moisture influences the furfural partitioning ratio in oil-paper insulation system. In this study, the correlation of moisture and furfural partitioning ratio was investigated. The accelerated thermal aging test and moisture absorption test were conducted to prepare oil-paper samples with different furfural and moisture concentrations. For samples with different moisture concentrations, the furfural partitioning ratios between oil and paper were compared. Results showed that samples with high humidity exhibited a high furfural mass fraction in oil. This finding implied that high humidity promoted the furfural diffusion from paper to oil. Further, the interference of moisture on aging assessment of insulation paper was analyzed. Results showed that the increase of moisture concentration in oil-paper system would significantly affect the accuracy of insulation paper aging assessment. A corrected equation for aging assessment of insulation paper with different moisture concentrations was established. Verification result showed that the equation could effectively correct the interference of moisture and enhance the accuracy of the aging assessment of insulation paper.     

Methodology to evaluate variations in piezoelectric constants after aging process

ABSTRACT

Piezoelectric ceramic properties change with time. Detected aging effects for PZT ceramics are; the difference in the value of the dielectric constants diminishes, whereas dielectric losses and elastic stiffness increases. In this work, an optimisation technique based on adjusting a finite element model to reproduce the complex impedance curves of a resonant piezoceramic disk is analysed aiming to detect changes due to aging. This technique allows estimating all material parameters, both their real and imaginary parts. The optimisation uses the constitutive equations of the piezoelectric effect in the linear regime. The evolution of elastic, piezoelectric and dielectric constants is evaluated after 5 years of aging. To compute the ten complex parameters, the piezoelectric model is adjusted to minimise the difference between finite element simulations and the experimental data. Results presented here, show that the proposed technique is sensitive enough to detect changes in the individual parameters due to aging process.     

光电耦合器件低频噪声特性与可靠性老化研究

在宽的输入偏置电流范围条件下,开展了光电耦合器件低频噪声特性测试与功率老化和高温老化的可靠性试验研究。结果表明,光电耦合器件的低频噪声主要是内部光敏晶体管1/f噪声,并随输入偏置电流的增大呈现先增大后减小的规律,这与器件的工作状态密切相关。功率老化试验后,高输入偏置电流条件下的低频噪声有所增大,这归因于电应力诱发的有源区缺陷。高温老化试验后,整个器件线性工作区条件下的低频噪声都明显增大,说明温度应力能够更多地激发器件内部的缺陷。相对于1/f噪声幅度参量,低频噪声宽带噪声电压参量可以更灵敏准确地进行器件可靠性表征。     

基于热重和拉伸实验的XLPE电缆绝缘热老化状态分析及机理研究

工况下交联聚乙烯电缆绝缘材料的老化会导致其较预期相对较早达到寿命终点,威胁输电系统的可靠运行。采用热老化来模拟工况环境下电缆的老化过程,选取100℃、120℃和140℃和160℃4个不同的老化温度,在每个温度点选取6个老化阶段,研究不同老化温度和老化时间对XLPE电缆绝缘试样性能的影响。通过热重和拉伸测试研究电缆的热性能、机械性能及其结构随老化程度的变化,得到电缆绝缘试样的热老化活化能、起始分解温度、最快分解温度、终止分解温度、断裂伸长率和拉伸强度等参数。研究结果表明:活化能、起始分解温度、最快分解温度和断裂伸长率对电缆老化状态较为敏感;随着老化温度从100℃增加到160℃,这些参数均呈现先略微增大后迅速减小的趋势,说明XLPE电缆绝缘材料热老化在低温范围以结晶作用为主,而在高温范围以热裂解为主。     

时效态18Ni钢切削过程中的热塑剪切失稳实验

不同切削速度下对18Ni马氏体时效钢进行切削试验，并用光学显微镜和电子显微镜观察切屑根部，发现有热塑剪切失稳现象，分析其组织结构特征及影响因素；再按热塑剪切失稳判据及显微组织分析热处理对热塑剪切失稳的影响。     

Long‐term stable hydrophilic surface modification of poly(ether ether ketone) via the multilayered chemical grafting method

The aging phenomena of a poly(ether ether keton) (PEEK) surface hydrophilically modified via various protocols was investigated. The use of plasma treatment or chemical etching methods offers a relatively convenient surface modification route. However, the effects of hydrophilic treatment quickly disappeared and its original surface property was recovered within a few hours or a few days when stored at ambient conditions. Surface treatment based on a single‐layered chemical grafting method rendered an excellent hydrophilic surface with an initial contact angle of <15° and an improved retardation of surface aging. However, the contact angle of the modified PEEK specimen gradually increased with time and eventually reached ～50° after 23 days. A new method for the long‐term stable hydrophilic surface treatment of PEEK using a multilayered chemical grafting strategy was also developed. With this regard, aging of the modified surface could be significantly retarded over ～90 days. It was believed that the effectiveness of the surface modification and the retarded aging phenomena via the multilayered hydrophilic treatment could be attributed to mechanical and chemical stability of the covalently bonded active surface groups on the grafted polymer networks. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46042.     

Effect of phosphotungstic acid blending on properties of sulfonated poly(ether ether ketone)–poly(ethylene glycol) crosslinked membranes

This study shows the effect of phosphotungstic acid (PWA) blended into a sulfonated poly(ether ether ketone) (SPEEK) and poly(ethylene glycol) (PEG) crosslinked membrane on the membrane's electrochemical and mechanical properties. The PWA weight percentage was varied from 0 to 50%. All of the membranes were equilibrated with water at room temperature (27 °C) and elevated temperature (60 °C), and their properties were investigated. A scanning electron microscope with energy dispersive X‐ray was used to ascertain the tungsten concentration remaining in the membrane after water treatment. A systematic decrease in tungsten concentration was seen with the increase in the initial PWA percentage. The membrane blended with 10% PWA showed the best properties, having the highest conductivity (0.11 S cm^?1), mechanical strength, and chemical stability. Membranes with 10% PWA and without PWA were studied in a H₂/O₂ fuel cell. The membrane blended with 10% PWA gave 33% more power density than the membrane without PWA. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46667.     

Effects of aging on poly(1‐trimethylsilyl‐1‐propyne) membranes irradiated with vacuum ultraviolet radiation for gas separation

In this study, we investigated the effects of physical aging on the surface and gas‐transport properties of highly gas permeable poly(1‐trimethylsilyl‐1‐propyne) membranes irradiated with vacuum ultraviolet (VUV) radiation. VUV excimer lamp irradiation was performed on one side of the membrane for 6 or 60 min. The gas permeabilities for carbon dioxide (CO₂) and nitrogen (N₂) were determined through a volumetric measurement method at 23 °C. The gas permeabilities for CO₂ and N₂ increased temporarily at 7 days after 6 and 60 min of VUV irradiation of the membranes. The change in the gas permeability for N₂ was more remarkable than that for CO₂. These changes were related to the C?O or SiO_x ratio. The C?O ratio was related to the gas permeability of the membranes VUV‐irradiated for 6 min, whereas the SiO_x ratio was related to the gas permeability of the membranes VUV‐irradiated for 60 min. These changes affected the gas selectivities of the membranes. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45973.