二元稀土系AB5型贮氢电极合金的放电容量与晶胞体积和4f电子浓度的关系

制备了6个系列通式为AαA‘1-αB5的RE(NiCoMnTi)5贮氢电极合金(其中，AαA‘1-α为La，Ce，Pr，Nd4个元素中任意2个的组合)，测定了它们在100次循环中的最大放电容量Cmax及部分合金的晶胞体积Vcell．结果表明：Cmax主要由Vcell决定，Cmax先随Vcell的增大而增加，在Vcell≈85．66x10^-^3。nm^3时达到一极大值，然后又随Vcell的增大而减小；同时，Cmax还与4f电子浓度ne4f／naRE有关，A侧具有相同4f电子浓度的合金其Cmax随4f电子浓度的变化趋势相似．     

Hyperhomocysteinemia and Cardiovascular Disease: Is the Adenosinergic System the Missing Link?

The influence of hyperhomocysteinemia (HHCy) on cardiovascular disease (CVD) remains unclear. HHCy is associated with inflammation and atherosclerosis, and it is an independent risk factor for CVD, stroke and myocardial infarction. However, homocysteine (HCy)-lowering therapy does not affect the inflammatory state of CVD patients, and it has little influence on cardiovascular risk. The HCy degradation product hydrogen sulfide (H₂S) is a cardioprotector. Previous research proposed a positive role of H₂S in the cardiovascular system, and we discuss some recent data suggesting that HHCy worsens CVD by increasing the production of H₂S, which decreases the expression of adenosine A_2A receptors on the surface of immune and cardiovascular cells to cause inflammation and ischemia, respectively.     

基于动态模式分解的移动用户信道容量预测算法

在多输入多输出环境下,为了能够连续预测出移动用户的信道容量并以此合理地分配用户资源,提出了一种基于动态模式分解（DMD）的信道容量预测方法及其优化方法：基于经验模态分解的选择性归一化动态模式分解（ESN-DMD）.仿真结果表明,DMD算法只适用于预测低移速低复杂度的用户信号,ESN-DMD算法可以预测不同移速的用户信道容量.     

多孔纤维型重整微反应器的等效电阻网络建模

针对应用于重整制氢微反应器的复杂多孔金属纤维载体（PFS）的流速场高效分析难题,建立载体中随机微通道的等效电阻网络分析模型. 基于复杂随机纤维结构的统计网络模型,将纤维载体中三维联通的随机微通道结构及与之相连的进出口腔简化为规则的网络通道结构.借鉴基尔霍夫定律,建立纤维载体的等效电阻网络模型,并确定求解方法. 纤维载体流速场实例分析的结果表明,基于等效电阻网络模型求解的纤维载体流速场与计算流体力学(CFD)方法的结果之间的皮尔森相关系数约为98%,且求解效率约为CFD方法的2.9×10⁴倍. 研究成果为多孔纤维型重整制氢微反应器的设计制造提供了新的支撑方案.     

大型软包锂离子电池的热物性实验研究

针对大型软包锂离子电池热物性参数的测定问题,提出适用于该型电池的热参数表征方法. 基于准稳态导热原理,建立电池的传热理论模型. 开展实验研究电池的比定压热容和导热系数与温度的依变关系,分析热损对测试结果的影响,对测试方法的有效性进行验证. 结果表明,电池比定压热容随着温度的升高而线性增大,导热系数受温度的影响较小. 在900 s内可以测得电池热参数在10~60 °C下的变化状况,实验验证结果显示测算精度高于92.3%,具有测算周期短、准确度高和测试灵活等优势.     

焊接箱型截面构件在不同焊缝熔深下承载力性能试验研究

为了有效改善大跨度桥梁中管翼缘焊接箱型截面构件的耐久性的问题,提出采用耐候钢代替普通钢的管翼缘箱型截面梁。同时,为了研究耐候钢管翼缘焊接箱型截面构件填充混凝土后在全熔透和部分熔透条件下的单轴承载力性能,开展了焊接矩形截面在三种不同焊缝熔深下的耐候钢管混凝土截面轴压短柱试验研究。分别测试每个试件在单轴压力作用下的静态应变、动态应变,以及竖向位移和侧向位移。对比构件承载力的试验结果及理论分析结果,得出不同熔深下焊接箱型截面管翼缘组合构件的承载力性能。研究结果表明:1）耐候钢管翼缘焊接箱型截面构件的全熔透焊缝承载力高于部分熔透焊缝承载力。2）全熔透试件开裂时的竖向位移较部分熔透试件的位移值大,而不同熔深下构件的横向位移测点L4随轴压荷载的增大而有增加,L3测点横向位移规律不明显。3）不同耐候钢管翼缘焊接箱型截面构件横向整体受拉,局部在顶部角部位置受压。构件的混凝土内部和钢板表面应变情况复杂,规律不明显。     

卡盘的若干设计计算问题

以“夹持系数”取代传统的摩擦系数；对卡盘的主要零件重新进行了受力分析，推导出能满足各零件设计计算之用的计算公式；并提出了提高卡盘夹持能力的有效措施：（１）减小卡瓦和卡圈斜面之间的摩擦系数；（２）提高卡瓦和主动钻杆之间的夹持系数     

Structural stability of single-layered LaNi4.25Al0.75 film and its electrochemical hydrogen-storage properties

AB5-based hydrogen storage thin fdms （LaNi4.25Al0.75）, deposited on Cu substrate by dc magnetron sputtering were investigated in this study. X-ray diffraction （XRD） revealed that the microstructure of the layer was in crystal form. SEM and AFM analyses proved that the film appeared to be rather rough with numerous randomly sized pores of approximately 15-40 in nm diameter. Structural stability of the film was examined by the combined analyses of DSC, XRD, and SEM, which indicated that this film maintained its structural stability below 500 K or so, and a network structure was observed on the film after being heated at 700 K for 30 min. Electrochemical hydrogen-storage properties of the films were investigated by simulated battery tests. It was found that single-layered LaNi4.25A10.75 film exhibited electrochemical hydrogen-storage properties similar to typical AB5 alloys in bulk, and the maximum discharge capacity of the film was about 220 mAh/g. After 20 charge/discharge cycles, small needle-shaped aluminium oxide was formed on some fractions of the film surface.     

Implications from γ-globulin adsorption onto cation exchangers fabricated by sequential alginate grafting and sulfonation

Our previous work proved that high adsorption capacity and uptake rate of lysozyme were achieved on alginate(Alg)-grafted re sin with an ionic capacity(IC) of 240 mmol·L~(-1)(Alg-FF-240).Moreover,the salt-tolerant feature of Alg-FF-230 was improved by using sequential alginate grafting and sulfonation strategy.Inspired by the enhanced adsorption performance of lysozyme,we have herein proposed to investigate the static and dynamic adsorption behaviors of γ-globulin on a series of Alg-grafted resins with different grafting densities and sulfonation degrees.The adsorption ca pacity of γ-globulin decreased with increa sing alginate-grafting density(IC) from 160 to 230 mmol·L~(-1) at 0 mmol·L~(-1) NaCl because of the steric hindrance caused by the alginate-grafting layer.Effects of ionic strength(IS) indicated that the adsorption capacities of the resins with the IC value of 230-370 mmol·L~(-1) were much higher than CM Sepharose FF at 50-100 mmol·L~(-1) NaCl,and the uptake rate of Alg-FF-230 was about twice as much as that of CM Sepharose FF.This work demonstrated the important effects of alginate-grafting layer and IS in γ-globulin adsorption behavior,which would be helpful in the design of Alggrafted resins and the selection of proper IS condition for protein purification.     

金属陶瓷防腐蚀涂层替代镀镉或镉−钛工艺的研究

针对钢制零件采用镀镉、镀镉?钛工艺存在氢脆、镉脆风险及不利于环境保护的现状,研究采用涂覆IPcote9183或IPcote9183+IPseal9184形成金属陶瓷防腐蚀涂层(MCAC)的替代工艺。对比结果表明:上述2种金属陶瓷涂层的氢脆性和耐蚀性优于镉及镉?钛镀层,其他性能相当,能够完全替代它们应用于起落架钢制零件的表面防护。