2.0 Mt/a渣油加氢脱硫装置新氢压缩机性能标定

介绍了中国石化茂名分公司 2 .0Mt/a渣油加氢脱硫装置中的 4M80 30 /2 2 2 0 0 BX型新氢压缩机的特点、技术特征及标定情况。采用国际通用标准对压缩机气体组成、容积流量、轴功率、进排气压力和进排气温度等指标进行了测定。标定表明 ,该机组设计方案合理 ,运转平稳 ,性能指标达到设计要求 ,较好的满足了工艺操作的需要     

后压浆技术在杨凌国际会展中心基桩工程中应用效果的分析

本文叙述了杨凌国际会展中心基桩静力载荷试验的试验过程 ;通过对三根灌注桩承载力的试验结果分析 ,认为后压浆技术对提高灌注桩单桩极限承载力有很大作用     

淤泥质土状亚粘土的一些特征

珠江三角洲软土地区存在一种灰色亚粘土，其工程性能与淤泥、淤泥质土相似，但两者的物理力学性质却有明显的不同，这是一种在规范土名定义上处于过渡或边缘状态的粘性土，不是严格定义上的淤泥质土，也不是正常沉积的一般粘性土，土的强度和工程性质与淤泥质土类似，应该近沿海地区淤泥和淤泥质土对待，不应看成一般粘性土。     

Influence of Edible Films upon the Moisture Loss and Microstructure of Dietetic Sucrose-Free Sponge Cakes during Storage

The kinetics of changes in the bound water content in dietetic sucrose-free sponge cakes (DC) during storage was investigated. The effect of edible films of polymyxan, pectin, xanthan, and carboxymethylcellulose upon this kinetics was also investigated. The quantitative changes in both states of water (slightly bound water and strongly bound water) were registered by combined dynamic analysis (thermogravimetry analysis, TGA, and differential thermal analysis, DTA). The moisture changes in DC crumb were analyzed by drying out to constant mass. The rate constants were determined according the equation q = q_oe^-kt. The values of rate constants 'k', in day^-1, concerning the different edible films were as follows: for crumb moisture is (8.00 ≤ k ≤ 12.47) × 10^-3, for bound water is (3.07 ≤ k_w ≤ 6.26) × 10^-2, for slightly bound water is (4.22 ≤ k₁ ≤ 8.49) × 10^-2 and for strongly bound water is (2.02 ≤ k₂ ≤ 5.62) × 10^-2 as compared to 18.53 × 10^-3, 7.16 × 10^-2, 9.04 × 10^-2, and 5.36 × 10^-2 in the uncovered DC, respectively. The best water-retaining effect in respect to crumb moisture during storage was ascertained in the use of polymyxan and xanthan films. The lowest rate constant values for bound water and its two states were measured for DC covered with pectin. The relation between the kinetics of both bound water states during storage and ageing of the crumb of DC covered with different edible films and the crumb microstructure was represented. By means of scanning electron microscope was read the smallest change in crumb microstructure of pectin-covered DC on the sixth day of storage.     

Effect of Synergistic Anticorrosion Treatments on Cycling Stability of Mg-Based Hydrogen Storage Electrode

In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%.     

合成氨扩能改造中锅炉存在的问题及采取的措施

针对天脊集团年产30万t合成氨扩能改造,给2台225t/h高压锅炉带来的除氧器热量过剩、锅炉给水温度升高、主蒸汽温度降低等一系列问题,分析了产生问题的原因,从节约能源、提高锅炉效率考虑,提出了相应的解决问题的办法:利用热量分流、改造省煤器管、增加二级过热器受热面积。经过3年多的生产实践证明,取得了良好的效果。     

C60辅助下ZnNiS光催化分解水制备氢气的研究

通过在光催化剂掺杂ZnS中加入球笼化合物富勒烯C60,提高了光催化水分解的效率.并采用气相色谱法跟踪反应,发现氢气释放量是未加C60时的4倍多.同时,对该催化反应的机理进行了初步的探讨.     

Coal liquefaction using a hydrogenated creosote oil solvent: H-atom transfer from hydrogen donor components in the solvent

The presence of hydroaromatic, hydrogen donor components in a coal-derived solvent is one of the more important factors in the successful operation of a non-catalytic coal liquefaction process. Various hydrogen donor species present in a hydrogenated creosote oil have been identified. Their rate of disappearance under conditions that are consistent with a short residence time coal liquefaction process has been used to rank the reactivities of the various hydrogen donors. 1,2,3,10b-Tetrahydrofluoranthene was found to be an exceptional donor while 4,5-dihydropyrene, the hexahydropyrenes and 9,10-dihydrophenanthrene were found to be quite active. Sym.-octahydrophenanthrene and 2a,3,4,5-tetrahydroacenaphthene exhibited moderate activity. Tetralin and the four methyltetralin isomers were found to be unreactive under the coal liquefaction conditions employed.     

Thermal-lens and photo-acoustic methods for the determination of SiC thermal properties

In this paper we report the use of photothermal techniques such as Thermal lens (TL) spectrometry, Photoacoustic and heat capacity, ρc_p, to determine the thermo-optical parameters, such as thermal conductivity (K), thermal diffusivity (D), specific heat (c_p) and the optical path dependence with temperature (ds/dT), of an undoped polycrystalline 3C-SiC. To our knowledge, this is the first time that Thermal lens technique is used for wide band-gap systems. Results obtained for the polycrystalline sample with TL technique indicates that ds/dT is negative at room temperature. Moreover, the obtained values of thermal diffusivity and thermal conductivity are in good agreement with that found in the literature, indicating that the phototermal techniques can be used to obtain the referred parameters in circumstances where other techniques cannot be used, for example, in harsh environments.