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41.
低工作温度的氧化钨气敏材料 总被引:3,自引:0,他引:3
本文报道了一种可以在100℃左右工作的氢化钨气敏材料,它对氢气和一氧化氮有很高的灵敏度和良好的选择性,并可对空气中的一氧化氮进行探测 相似文献
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基于试样高温高压釜充氢方法 ,研究了氢对 2 2 5Cr 1Mo压力容器用钢力学性能的影响。对充氢前后的试样进行了拉伸和CVN冲击试验 ,结果表明 ,氢对 2 2 5Cr 1Mo钢的拉伸力学性能和冲击韧性影响不显著。 相似文献
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Jennifer K. Edwards Adrian Thomas Benjamin E. Solsona Philip Landon Albert F. Carley Graham J. Hutchings 《Catalysis Today》2007,122(3-4):397-402
The direct synthesis of hydrogen peroxide from H2 and O2 using a range of supported Au–Pd alloy catalysts is compared for different supports using conditions previously identified as being optimal for hydrogen peroxide synthesis, i.e. low temperature (2 °C) using a water–methanol solvent mixture and short reaction time. Five supports are compared and contrasted, namely Al2O3, -Fe2O3, TiO2, SiO2 and carbon. For all catalysts the addition of Pd to the Au only catalyst increases the rate of hydrogen peroxide synthesis as well as the concentration of hydrogen peroxide formed. Of the materials evaluated, the carbon-supported Au–Pd alloy catalysts give the highest reactivity. The results show that the support can have an important influence on the synthesis of hydrogen peroxide from the direct reaction. The effect of the methanol–water solvent is studied in detail for the 2.5 wt% Au–2.5 wt% Pd/TiO2 catalyst and the ratio of methanol to water is found to have a major effect on the rate of hydrogen peroxide synthesis. The optimum mixture for this solvent system is 80 vol.% methanol with 20 vol.% water. However, the use of water alone is still effective albeit at a decreased rate. The effect of catalyst mass was therefore also investigated for the water and water–methanol solvents and the observed effect on the hydrogen peroxide productivity using water as a solvent is not considered to be due to mass transfer limitations. These results are of importance with respect to the industrial application of these Au–Pd catalysts. 相似文献
47.
Atomic force microscopic analysis of hydrogen peroxide bleached kraft northern black spruce fibres 总被引:1,自引:0,他引:1
Hydrogen peroxide is a potent, relatively inexpensive oxidant that chemically degrades chromophoric components in pulps and textiles. Oxidation of cellulose is a byproduct of this process step that decreases the tensile strength of individual fibres. The residence time of pulp in the bleaching reactor must be optimized to achieve the desired brightness and minimizing fibre degradation. To evaluate the impact of peroxide bleaching at the microfibrillar level, a single black spruce tree was chosen and kraft pulped. Peroxide bleaching was conducted via benchtop polyethylene bag bleaching in a temperature-controlled waterbath. Atomic force microscopy (AFM) topographical images acquired before and after the bleaching step show dramatic changes in fibre structure consistent with delignification and defects in the surface topography. This was further verified by X-ray work at Brookhaven National Laboratory, NY, U.S.A. 相似文献
48.
铂与氢、水和苯分子相互作用的量子化学研究 总被引:2,自引:1,他引:1
采用量子化学程序Gaussian98(A.9)从头算的B3LYP方法,全优化计算铂对氢、水和苯的化学吸附作用,得到了3种相关络合物PtX、PtXX和Ptxxx(X=H,H2O或C6H6)的平衡几何构型和电子结构信息,并探讨了这些络合物的成键性质,以及苯环与铂原子之间的分子轨道作用性质。结果表明,苯环与铂原子之间有很强的成键作用,并随着游离氢原子和水分子的参与,作用强度有很大变化。苯分子吸附在金属铂上,它的芳香性得到不同程度的降低,苯环被活化,苯环与铂原子之间形成η^2型π键络合物;水参与作用后,苯环与铂原子之间形成σ络合物;氢和水同时参与作用后,苯环与铂原子之间仅有很弱的π轨道作用。 相似文献
49.
The kinetics of disproportionation of methylamine to dimethylamine and ammonia in the presence of hydrogen have been investigated over a silica-supported palladium catalyst. At a fixed partial pressure of methylamine, the reaction rate generally increases with decreasing hydrogen partial pressure, approaching a limiting or maximum value at sufficiently low pressures of hydrogen. The existence of a maximum is supported by the observation that the presence of some hydrogen appears to be necessary for the reaction to proceed at a conveniently measurable rate. At a fixed hydrogen partial pressure, the reaction rate increases with increasing methylamine partial pressure. When the methylamine partial pressure is sufficiently low or the hydrogen partial pressure is sufficiently high, the reaction order with respect to methylamine can be somewhat higher than one. At such conditions, a mechanism involving a bimolecular reaction between two partially dehydrogenated methylamine molecules on the surface appears to make a significant contribution to the overall catalytic reaction. 相似文献
50.
主要介绍20.4K低温氦气经过加温后给液氧贮箱增压的试验技术。对试验设备、试验方法、试验过程及试验结果做了简要的介绍。 相似文献