等离子体熔融钛与羟基磷灰石混合粉颗粒的形态和相组成

利用等离子喷涂设备将Ti与羟基磷灰石（HA）的混合粉末喷射入水，采用扫描电子显微镜和X射线衍射仪研究了Ti HA入水颗粒的形态和相组成，结果表明，经等离子熔融喷射入水后，钛粒子的尺寸小于HA粒子，主要原因之一是HA内形成了空心结构，空心结构的形成是由于HA在熔融时生成气相P2O5和H2O，它们在颗粒内聚集形成气泡，入水Ti HA粒子主要是由晶相和非晶相HA，分角相磷酸三钙（TCP）和磷酸四钙（TTCP）以及Ti的化合物所组成，由于与Ti的混合，HA的分解加剧，而Ti与HA粒子的融合及元素的扩散在飞行过程中已经发生。     

晶须转动及其对SiC_W／Al－Ni复合材料高温压缩变形流变应力的影响

本文测定了ＳｉＣＷ／Ａｌ－Ｎｉ复合材料高温压缩变形的应力－应变曲线，讨论了该种复合材料高温压缩变形时所表现出的应变软化现象，利用ＳＥＭ观察了ＳｉＣＷ／Ａｌ－Ｎｉ复合材料在高温压缩变形中晶须的转动，并对晶须长轴的取向分布函数及其与复合材料压缩流变应力之间的关系进行了较为详细的研究．研究结果表明，在压缩变形过程中，ＳｉＣＷ晶须的长轴要发生转动，并趋向垂直于压缩方向分布，晶须取向的重新分布是造成复合材料应变软化的主要原因．     

烧结对羟基磷灰石微球微观结构和性能的影响

利用扫描电镜（SEM）、激光粒度分析仪（LDPSA）、X射线衍射仪（XRD）以及比表面积分析仪（SSA）等检测方法，研究了烧结对于羟基磷灰石微球的微观结构、形貌以及粒径、比表面积和孔隙率等性能的影响。结果表明，经800℃热处理，微球的比表面积、孔隙率及其表面形貌均会发生明显的变化；经1000℃烧结后，部分羟基磷灰石相发生热分解，生成较多的的     

Effects of anodizing voltage on the anodized and hydrothermally treated titanium surface

Anodic oxidation is the process of creating a titanium oxide layer with various defects more dense and stable. In this study, a dense, stable and porous oxide layer was formed using anodic spark oxidation on pure titanium surface and hydroxyapatite crystals were formed on its surface via a hydrothermal treatment. A mixture of 0.02M−GP (Glycerolphosphate disodium salt) and 0.2M-CA (Calcium acetate) was used as an electrolyte. By increasing the anodizing voltage to 220, 260, 300, and 360 V, the effects of the anodizing voltage were examined by evaluating the film properties after anodization and a hydrothermal treatment. Breakdown occurred around 230 V. As the voltage increased after breakdown, the pore size increased. After the hydrothermal treatment, the amount of HA crystal precipitation was also increased as the voltage increased. The mean surface roughness (Ra) of the anodizing surface was also increased as the voltage increased. The Ra value was larger in the hydrothermally treated group compared with the group treated with anodization as a result of the HA crystals present on the surface after the hydrothermal treatment. Corrosion resistance of the surface modified by anodization was significantly increased in a saline solution compared to that for the non-treated group; this increased further after the hydrothermal treatment. These increases were most likely due to a thick stable oxide layer formed through anodization. Thus, it is believed that titanium with its surface modified through anodic spark oxidation would be a suitable biomaterial due to its corrosion resistance and biocompatibility.     

钛合金表面声电沉积／碱热处理法制备HA涂层研究

为了使钛合金（Ti-6Al-4V）具有生物活性，可在其表面施加生物活性羟基磷灰石（HA）涂层。对比了声电沉积法和碱热处理法实验结果，采用扫描电镜（SEM）、X射线衍射仪（XRD）、电子能谱（EDS）、傅立叶红外透射光谱（FTIR）以及划痕测试等进行了分析。结果表明，直接采用声电沉积法在钛合金表面制备的羟基磷灰石涂层，经热处理后存在龟裂剥落现象；通过碱热处理法，对钛合金基体表面进行预处理，然后，借助声电沉积法，在钛金属表面沉积了透钙磷石涂层，经热碱液处理转变成的羟基磷灰石涂层，涂层完整，未出现剥落。经进一步高温烧结处理，所制涂层仍呈片状形貌，其由部分含钠的羟基磷灰石组成，而且HA涂层破坏的临界载荷未烧结前的4．365N提高至烧结后的8．175N。     

硼酸铝晶须增强Al复合材料的性能及界面结构

采用挤压铸造工艺制备出复合良好的9Al_2O_3 2B_2O_3晶须增强6061Al合金及纯Al复合材料研究表明,T6处理不能提高9Al_2O_3 2B_2O_3w/6061Al复合材料的力学性能,其原因是T6处理后复合材料中的界面反应明显加重利用透射电子显微术对此复合材料界面的观察与分析认为,界面上存在着严重的化学反应,反应物为Al_2MgO_4将制造态与T6态的界面结构对比发现,正是这种界面化学反应对材料的性能产生不利影响而在9Al_2O_3 2B_2O_3w/纯Al界面上未发现任何化学反应。界面能谱EDS成分分析结果表明,上述界面化学反应是由材料制造过程中基体合金中的Mg在界面上原子偏聚造成的     

Thermal spraying of biomaterials

Osteoconductive hydroxyapatite coatings for metallic endoprostheses for hip and knee joint replacement provide a state-of-the-art template for enhanced in-growth of bone cells. However, the high temperature of the plasma jet leads to large scale dehydroxylation and decomposition of the starting powder. A model is being developed to explain the formation of chemically and mechanically inhomogeneous porous calcium phosphate coatings deposited by atmospheric plasma spraying onto titanium alloy substrates. In addition the biofunctionality is being discussed of titania bond coats and their influence on the in vivo performance of hydroxyapatite-titania duplex coating systems.     

硼酸铝晶须的试验研究

利用固体粉末法在不同的加热温度制备出硼酸铝晶须。ＳＥＭ分析其形貌，ＴＥＭ确定其结构，并对晶须形成机理和影响因素进行了研究。     

STUDY OF K_(2)O·6TiO_(2) WHISKER REINFORCED AI COMPOSITES FOR THEIR MECHANICAL PROPERTIES AND INTERFACIAL STRUCTURES

A newly developed whisker K_2O 6TiO_2 reinforeed 6061Al composite was prepared bysqueeze casting process.The flexural strength of the composite is 518MPa,and deereasesto 490MPa after T6 treatment.The hardness of the composite also shows the similarchange while T6 treating.The results of HRTEMobservation may explaine this property.change.It was considered that there is a continuous TiO layer at the whisker-matrix inter-face,which is easily to react with the segregated Mg and to form MgTi_2O_4,MgAl_2O_4.Thethickening of TiO layer after T6 treatment is the main reason resulting is strength degra-dation of composite.     

INTERFACIAL REACTION IN K_2O·8TiO_(2(w))/ ZL109 COMPOSITE UNDER THERMAL EXPOSURE OR THERMAL CYCLING

在５００℃下热暴露１００ｈ以上时，Ｋ_２Ｏ·８ＴｉＯ_２晶须与ＺＬ１０９铝基体金属发生界面反应生成了新相Ｔｉ_７Ａｌ_５Ｓｉ_（１２），随着热暴露时间的延长，反应产物增多，热循环比热暴露更明显地促进了界面反应。在所有的状态下，这种晶须与基体之间都存在ＴｉＯ过渡层。