氧气氧化脱除模拟柴油中的二苯并噻吩

The potential of carrying out oxidative desulfurization (ODS) using oxygen as an oxidant was explored in this work. Octane firstly reacted with oxygen to produce hydroperoxides in-situ, which were then used as oxidants to oxidize the dibenzothiophene (DBT) in the absence of catalysts. The hydroperoxides generated in-situ were effective in oxidizing DBT to its corresponding dibenzothiophene sulfone (DBTO2) which was characterized by FT-IR and H1-NMR. The removal of DBT can reached to 98.4% at 140 °C, 4 h, oxygen partial pressure 0.4 MPa. The influences of different hydrocarbon components in diesel oil on DBT removal were investigated. The results showed that cyclohexane and n-dodecane had no effect on the removal of DBT, but the xylene had a slight negative effect on DBT removal. The possible oxidation mechanism was proposed and the concentration of hydroperoxides in both O2-oxidized octane and model diesel oil were detected.     

复合苦荞粉通便作用的研究

通过对小鼠做通便药效试验,研究复合苦荞粉的通便作用。以小鼠为试验对象,随机分为5组,即空白对照组、模型对照组和复合苦荞粉低、中、高3个剂量组。采用复方地芬诺酯灌胃建立小鼠便秘模型,通过测定小肠推进率、首次排黑便时间、排黑便粒数以及排黑便质量,判断复合苦荞粉对小鼠肠道蠕动和排便功能的影响。在连续灌胃14 d后,高剂量组小鼠的墨汁推进显著高于模型对照组(p0.05);高剂量组的小鼠排黑便粒数高于模型对照组,呈极显著差异(p0.01),低、中剂量组的排黑便粒显著高于模型对照组(p0.05);各剂量组的排黑便质量均极显著高于模型对照组(p0.01);而首次排黑便时间各剂量组与模型组之间无显著差异。复合苦荞粉能有效增强肠道蠕动并促进排便,改善便秘。     

热稳定剂在全钢载重子午线轮胎胎面胶中的应用

研究两种热稳定剂SL-9090和HS-80在全钢载重子午线轮胎胎面胶中的应用。结果表明:在胎面胶中加入热稳定剂,胶料的门尼粘度减小,硫化速度减慢,抗硫化返原性提高,且与热稳定剂用量呈正比,加入2份热稳定剂HS-80的胶料抗硫化返原性最好;硫化胶的物理性能变化不大,生热相当,其中加入3份热稳定剂SL-9090的胶料耐高温性能最优。     

反舰导弹红外复合制导电子干扰评估方法研究

本文首先分析了电子干扰对抗反舰导弹的工作原理及方法,在分析红外复合制导反舰导弹作战使用的基础上,通过建立多维度指标体系描述电子干扰对反舰导弹干扰能力。采用综合评估方法对电子干扰对抗红外复合制导进行评估,给出的相关结论对提高电子干扰对抗反舰导弹作战能力具有指导意义。     

Microstructure and thermal behavior of Sn-Zn-Ag solders

The microstructure and thermal behavior of the Sn-Zn-Ag solder were investigated for 8.73–9% Zn and 0–3.0% Ag. The scanning electron microscopy (SEM) analysis shows the Ag-Zn compound when the solder contains 0.1% Ag. X-ray diffraction (XRD) analysis results indicate that Ag₅Zn₈ and AgZn₃ become prominent when the Ag content is 0.3% and above. Meanwhile, the Zn-rich phase is refined, and the Zn orientations gradually diminish upon increase in Ag content. The morphology of the Ag-Zn compound varies from nodular to dendrite structure when the Ag content increases. The growth of the Ag-Zn compounds is accompanied by the diminishing of the eutectic structure of the Sn-9Zn solder. Differential scanning calorimetry (DSC) investigation reveals that the solidus temperature of these solders exists at around 198°C. A single, sharp exothermic peak was found for the solders with Ag content less than 0.5%. Liquidus temperatures were identified with the DSC analysis to vary from 206°C to 215°C when the Ag content ranges from 1.0% to 3.0%     

李世忠，王国宏，吴 巍，苏少涛

在强对抗条件下雷达/红外双模复合制导跟踪中,雷达采用间歇工作方式可以减少敌方导弹拦截概率和电子支援措施锁定概率。文中在导弹复合制导跟踪中提出了一种雷达间歇工作下的雷达与红外序贯滤波融合算法,该算法针对雷达、红外量测时间不一致的特点,采用顺序处理结构的多传感器集中式融合方法对目标进行跟踪,在跟踪中使用了基于交互多模型和扩展卡尔曼(IMM-EKF)的序贯滤波方法,利用滤波过程中的状态估计协方差与测量误差方差进行比较控制雷达间歇工作。该算法可以自动适应雷达间歇工作,不需要在单/双传感器跟踪模式之间切换,最后通过仿真的方法分析了传感器数据率和雷达间歇工作对跟踪精度的影响。     

基于近红外波段激光光谱吸收的丙烷探测研究

为了对石油气挥发性有机化合物的主要成分进行实时监测,实现石油化工行业的安全生产,采用激光光谱分析技术、利用宽谱光源分析了丙烷在1686.00nm~1687.00nm波段的光谱吸收特征,获得了吸收系数随波长变化的洛伦兹线型,其半峰半宽为0.21nm。选择中心波长为1686.30nm的分布反馈式半导体激光器作为光源,在丙烷宽谱吸收峰范围内进行波长扫描,得到了一次谐波信号和二次谐波信号随丙烷体积分数的变化规律,并在丙烷的体积分数0.0050~0.0300范围内标定了二次谐波与一次谐波信号的比值与体积分数的线性关系。结果表明,实验系统有很好的稳定性与重复性,能够进行实时的丙烷在线检测。该研究为探测其它挥发性有机化合物气体提供了理论及实验参考。     

Co/BaTiO3纳米复合薄膜的PLD法制备及其Raman光谱

采用脉冲激光气相沉积（PLD）技术在MgO（100）衬底上生长了Co/BaTiO₃纳米复合薄膜,利用原子力显微镜、透射电镜、X射线衍射（XRD）及Raman光谱等测试分析手段对Co/BaTiO₃纳米复合薄膜进行测试分析。结果表明：薄膜表面均匀、致密,具有原子尺度的光滑性;Co纳米晶粒呈单分散、均匀分散在沿C轴呈单取向生长的BaTiO3单晶基体中;随着掺杂Co含量的增高,BaTiO3的Raman峰的峰强随之增大。     

液体介质三维光子晶体禁带可调性能研究

研究了宽频折射率可调液体介质在三维光子晶体上的应用。设计了完美结构的液体光子晶体,采用 平面波展开法和有限时域差分法研究了液体介质的介电常数对光子晶体带隙的影响规律;采用光固化快速成型技 术制造了完美结构光子晶体模型,通过灌注不同介电常数的液体介质,发现液体光子晶体的电磁带隙频率随液体媒 介介电常数的升高而向低频移动,其禁带相比于传统液晶可调光子晶体有所拓宽。     

InGaAs PIN光电探测器的暗电流特性研究

从理论上分析了In0.53Ga0.47As PIN光电探测器在不同掺杂浓度及反向偏压下的暗电流特性,并与研制的器件的实测结果进行了比较和讨论.模拟结果表明:在低偏压下,器件中的产生复合电流起主要作用,偏压增大时,隧道电流起主要作用,且In0.53Ga0.47As光吸收层的载流子浓度对器件的暗电流有很大的影响,实测器件特性与模拟结果完全符合.文中还对器件结面积和电极尺寸等对暗电流的影响进行了比较和分析.