Preparation, Characterisation and Catalytic Behaviour of a New TeVMoO Crystalline Phase

TeM_xMo_1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N₂. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb₄Mo₁₀O₃₁ and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene.     

塑料挤出型材车间公用工程设计

鉴于当今人们对塑料门窗需求量的增大，通过对5个塑料挤出型材车间的设计，将其公用工程设计整理成文，总结出塑料挤出型材车间的采暖通风设计，压缩空气系统设计，制冷系统设计的较详尽的方案，以供有关设计技术人员参考。     

试论会计电算化系统的内部控制

阐述了会计电算化系统产生和发展对内产控制的影响，以及内部控制的实施方法。     

Shell渣油气化装置油气掺烧时控制系统的改造

对Shell渣油制氨装置改为渣油和炼厂干气掺烧时控制系统的改造进行了分析论证 ,提出了控制系统的具体改造方案     

中国石油未来油气勘探重点领域分析

根据近几年来的研究认识与勘探成果分析,未来几年中国石油油气勘探主要集中于如下五大重点领域:大面积低渗透岩性油气藏、成熟区复杂隐蔽油气藏、前陆盆地复杂构造油气藏、海相碳酸盐岩油气藏和渤海湾滩海第三系油气藏。     

关于长江重大问题的思考

长江流域横跨我国华东、华中、西南三大经济区,地理位置优越,水资源得天独厚,是我国最重要的经济区域之一。新中国成立后,党和政府高度重视长江治理开发工作,组建了流域机构,开展了流域综合利用规划,初步建立了长江防洪、灌溉、水力发电、航运、水土保持和水资源保护体系,在保护     

中关村中心区水文地质及工程地质特征

本文全面、系统地分析了北京市中关村中心区的水文地质及工程地质特征 ,为该地区的工程建设提供可靠的地质资料     

挠性胶管的阻尼减振机理初探

建立了挠性胶管阻尼耗能的简化模型。以此为基础分析了挠性胶管的阻尼耗能的一般规律,并得出了一些新的结论。     

Trace elements in particles of motor vehicle exhaust in Shanghai

A nuclear microprobe with high spatial resolution and high analytical sensitivity was applied to analyze trace elements,especially lead,in vehicle exhaust of Shanghai city.The result shows that the chemical composition and its corresponding x-ray relative intensity are different among different vehicle exhausts.There are many kinds of metal elements in particles of vehicle exhaust.most are harmful to people,such as Ti,Cr,Mn,Pb,etc.We found that the lead concentration was 6820μg/g and the bromine concentration was 5300μg/g in the exhaust from Santana using leaded gasoline(SULG).which is higher than any other kinds of vehicle exhausts.We have also detected the minimum lead in the particles of unleaded gasoline and its content varies from one to another.Its mean concentration was 450μg/g and the highest reached 6210μg/g.The unleaded gasoline‘s Pb existed in the whole particle while the leaded gasoline‘s enriched in the surface of the particle and was more harmful to the human beings.     

Microscopic and Macroscopic Growth Rates of Fatigue Cracks in Steels and Alloys under the Influence of Crack Closure

On the basis of the experimental data, we show that the difference between the macroscopic and microscopic fatigue crack growth rates in the second section of the kinetic diagram of fatigue fracture is caused by the effect of crack closure within the limits of its existence. We establish the relationships between the macroscopic and microscopic fatigue crack growth rates and the structure of the material in the second section of the diagram for various values of the load ratio with regard for the effect of crack closure and propose a procedure of examination of the fracture processes in structural materials based on the analysis of microscopic and macroscopic fatigue crack growth rates.