The Effect of Moisture Content in Epoxy Film Adhesives on their Performance. III: Bulk Properties

Humidity absorbed by epoxy film adhesives during low temperature storage or exposure to atmosphere may result in reversible changes and irreversible modifications. Vacuum treatment may partially remedy the reversible changes. The consequences of vacuum drying are manifested in enhancement of both the peel and shear properties of bonded joints (Part I and Part II of this series of papers) and the thermal, physical and mechanical properties of the bulk adhesive, characterized in the present study.

Experimental results have shown that the bulk properties of structural epoxy based adhesives are highly correlated with the aging processes caused by water absorption in the prepolymerized adhesive. Applying the vacuum process is harmful to fresh unaged adhesive due to devolatization of low molecular species of the film adhesive.

The characterization of bulk properties for the purpose of following the aging and recovery processes is advantageous, since the bulk is independent of geometrical and interfacial effects which dominate in the case of property evaluation of the adhesive in a bonded joint.     

Investigation on the electrocatalytic characteristics of SnO_2 electrodes with nanocoating prepared by electrodeposition method

SnO2 electrodes have many advantages in the degradation of toxic or bio-refractory organic wastewater,and SnO2 is a kind of anode material which has the potential to be widely used.Electrocatalytic effi-ciency and service life of Ti\SnO2 electrodes are key factors that can influence its applications.In order to enhance the electrocatalytic characteristics of Ti\SnO2 electrodes,a type of electrocatalytic electrode with nanocoating was prepared by direct current(DC)electrodeposition method and thermal oxidati...     

无机分离膜

本文综述了无机膜的结构及特性,无机膜的分离机理、无机膜的制备方法。介绍了常见的几种无机膜及其在气体、液体以及生化产品的分离、废水处理、啤酒、饮料的滤菌、海水淡化等领域中的应用。展望了无机膜在硫化氢分解制氢、丙烷、环己烷和乙苯脱氢等反应中实现反应分离一体化的前景。     

钯－银合金膜分离氢气的研究

采用厚为５０μｍ的Ｐｄ／Ａｇ（２３）合金膜进行了氢气渗透系数的测定和Ｈ＿２／Ｎ＿２混和气分离的研究，得出温度、压力、膜厚、进料气流量、膜的预处理和再活化及膜表面中毒等因素对氢气渗透的影响。分离Ｈ＿２／Ｎ＿２混和气可获得高纯氢气。     

Reactive Hot Melts on the Basis of Polyester and Polyamide

Hot melts show many advantages over other adhesives, for instance, their lack of solvent and their very short setting time just by cooling. The weak point of hot melts in comparison to thermosetting resins is their limited thermal resistance. There is no doubt that the high performance hot melts on the basis of polyester and polyamide show a better heat performance than the widely-used rubbery hot melts. Nevertheless, it is true that the thermal resistance is limited by the melting point of the hot melt. To improve the heat performance, without losing the favourable hot melt properties, crosslinkable hot melts have been created. For the example, copolyamide/blocked isocyanate blends, it can be shown that crosslinkable hot melts are achievable in a wide range of reactivities. After curing, which takes place during the bonding process, these hot melts withstand temperatures of over 220°C even if the melting point of the initial hot melt was 100°C.     

Aperture-Adjustable and Repairable Metal-Based MOFs Catalysis Membrane for Water Purification

Precise adjustment of the pore size, damage repair, and efficient cleaning is all challenges for the wider application of inorganic membranes. This study reports a simple strategy of combining dry-wet spinning and electrosynthesis to fabricate stainless-steel metal–organic framework composite membranes characterized by customizable pore sizes, targeted reparability, and high catalytic activity for membrane cleaning. The membrane pore size can be precisely customized in the range of 14–212 nm at nanoscale, and damaged membranes can be repaired by targeted treatment in 120 s. In addition, advanced oxidation processes can be used to quickly clean the membrane and achieve 98% flux recovery. The synergistic actions of the membrane matrix and the selective layer increase the adsorption energy of active sites to oxidant, shorten the electron transfer cycle, and enhance the overall catalytic performance. This study can provide a new direction for the development of advanced membranes for water purification and high-efficiency membrane cleaning methods.     

阻燃剂的现状与发展趋势

通过对无机燃剂和有机燃剂的现状的分析，指出了阻燃剂的无卤化和无机阻燃剂的开发及改性已成为阻燃剂最主要的发展趋势。     

用于BaF2闪烁光慢成分抑制的膜系设计及制备

利用BaF2闪烁光快、慢成分处于不同波段的性质，设计出了具有特定带隙的膜系结构，用于抑制发射光谱中的慢成分。在保证快成分具有一定透过率条件下，实现了对BaF2闪烁光慢成分的全方向抑制，使晶体的快慢比得到很大提高。从膜系γ射线辐照损伤的结果可知：辐照对膜系透射带和截止带的影响不大，辐照后的膜系仍能满足抑制要求。