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101.
Tadashi Hano Michiaki Matsumoto Takahisa Kawazu Takaaki Ohtake 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,62(1):60-63
The extraction equilibria of various di- and tripeptides with di-2-ethylhexylphosphoric acid (D2EHPA) were studied at low pH values. The complex extracted to organic phase consisted of one molecule of peptide and two molecules of D2EHPA dimer. The extraction constants of the peptides correlated well with the distribution coefficients of peptides between 1-octanol and water, which is a measure of hydrophobicity. The permeation rates of peptides through an emulsion liquid membrane were examined by using D2EHPA as a carrier, Span 80 as an emulsifier and kerosene as a diluent. The rates varied considerably with peptide type, depending upon the hydrophobicity. 相似文献
102.
M. Aigner M. Zeilinger H. Hofbauer 《Chemical Engineering and Processing: Process Intensification》1995,34(6):515-520
The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas. 相似文献
103.
乙烯氧化制环氧乙烷固定床反应器的模拟及稳定性分析 总被引:2,自引:0,他引:2
在筛选出合适的乙烯氧化制环氧乙烷动力学方程的基础上,对工业固定床氧化反应器进行一维和二维模型的模拟计算。考察操作工艺参数对反应器稳定性、转化率影响的敏感性以及N_2和CH_4做致稳气时反应温度和转化率的轴向、径向分布。 相似文献
104.
105.
有机-无机复合肥生产工艺 总被引:1,自引:0,他引:1
随着社会经济快速发展和城乡环境的污染已日趋严重。根据有机肥、无机肥各自的优缺点提出有机-无机肥生产的新工艺。 相似文献
106.
Selectivity of partial hydrogenation reactions performed in a pore-through-flow catalytic membrane reactor 总被引:2,自引:0,他引:2
The selectivity of partial hydrogenation reactions of unsaturated substrates was studied in a membrane reactor operating at 323 K and 40 bar hydrogen pressure. The reactor system was constructed as a loop of a saturation vessel and a membrane module in which the reaction mixture was resaturated with hydrogen up to 100 times. In a porous membrane made from cross-linked polyacrylic acid palladium nanoparticles were incorporated as catalysts. A well-defined residence time within the membrane was achieved due to a defined pore structure of the membrane and a convective mass flow of the reaction mixture through the membrane. The selectivity for the partially hydrogenated products was investigated as a function of the pore size of the PAA membrane and was compared to commercially available catalysts. Compared to experiments with supported catalysts (Pd/C and Pd/Al2O3) in a slurry and a fixed bed reactor the selectivity for the desired products could be increased by 3% (1-octyne) up to 40% (geraniol). 相似文献
107.
Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate.The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0 × 10−5 M) and a wide linear range (4.0 × 10−5 to 5.3 × 10−3 M). Also, they are free from interference versus other organic anions.The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed. 相似文献
108.
介绍了在高压环形反应器上采用连续聚合工艺进行的VAE(醋酸乙烯-乙烯共聚物)乳液新品种的开发。通过在普通型VAE乳液配方基础上调整保护胶体的品种和用量,并采用新型氧化-还原引发体系,生产出高固含(6S%)低粘度的VAE乳液,具有优异的粘接强度和干燥速度。用于包装行业的快速粘接和配制成木材拼板胶,效果优异。 相似文献
109.
介绍一种新型的恒通量的微滤膜———ISOFLUX 膜 ,该种膜的膜通量衰减比通常的微滤膜要小得多 ,对ISOFLUX 膜的原理和数学模型进行了推导 ,并给出了对牛奶进行冷杀菌过滤的结果 . 相似文献
110.