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992.
A new dimeric lanthanum(Ⅲ) complex [La2(phen)2(C7H3N2O6)6](phen=1,10-phenanthroline) was synthesized by the hydrothermal method and determined by single crystal X-ray diffraction analysis. The La(Ⅲ) ion is coordinated to seven oxygen atoms from five carboxylate groups and two nitrogen atoms from a phen ligand,forming a monocapped square antiprismatic geometry. Six carboxylate groups coordinate to two La(Ⅲ) ions in three modes which are chelating bidentate,bridging bidentate and bridging tridentate. The crystal is triclinic with space group P-1,a=1.2030(4) nm,b=1.2962(5) nm,c=1.3330(5) nm,α=104.410(5)°,β=114.048(4)°,γ=100.054(4)°,V=1.7467(10) nm3,Mr=952.46,Z=2,Dc=1.811 g·cm-3,F(000)=944,S=1.017,μ=1.320 mm-1,with R1=0.0298 and wR2=0.0625. 相似文献
993.
Lü Manqi 《中国稀土学报(英文版)》2004,22(Z2)
The structure and hydriding performance of La0.6Nd0.4Ni4.8Mn0.2Cux (x = 0 ~ 0.4) alloys were investigated in order to develop suitable materials for metal hydride air conditioner. The effect of Cu addition on the crystal structure,equilibrium pressure, hydrogen capacity and hysteresis as well as hydrogen absorption/desorption kinetics were systematically studied by using the measurement of P-C isotherms, X-ray diffraction and scanning electron microscopy. As the amount of Cu increases, the plateau pressure increases and hydrogen absorption/desorption kinetics is improved, but the effective hydrogen storage capacity decreases. It is shown that variations in the basal plane parameter a can be used as an indication for the plateau pressure changes. With the increase of parameter a, the plateau pressure decreases. For La0.6 Nd0.4Ni4.8Mn0.2Cux(x = 0 ~ 0.4) alloys there is a relationship between the effective hydrogen storage capacities and the ratios of their unit cell parameters c and a. The effective hydrogen storage capacity decreases with increase of a/c. 相似文献
994.
TANG Qingguo Shen Shangyue Wang Lijuan LIANG Jinsheng Ding Yan Meng Junping LI Guosheng WANG Man 《中国稀土学报(英文版)》2004,22(Z3)
The magnetic liquid was prepared with ferric salt by inorganic gel technology. The effect of the doped rare earth elements on the properties of magnetic particles was analyzed. The magnetic liquid was composed with clay mineral into magnetic mineral composites. The crystal structure and micro-morphology of the nanoparticles were studied by XRD and TEM. The results show that the crystal structure of the magnetic particles doped 0.5 % of lanthanum is more complete, and the magnetic response capability is higher with doping agent. At the same time, the possibility of the clay mineral magnetic composites as the carrier of target drug was probed. 相似文献
995.
The algorithm is divided into two steps. The first step pre-locates the blank by aligning its centre of gravity and approximate normal vector with those of destination surfaces, with largest overlap of projections of two objects on a plane perpendicular to the normal vector. The second step is optimizing an objective function by means of gradient-simulated annealing algorithm to get the best matching of a set of distributed points on the blank and destination surfaces. An example for machining… 相似文献
996.
The vision of mass customization has driven a movement toward low volume, high variety mass customization production (MCP)
at low price. However, defect identification and defect tracking in such systems are extremely difficult because of the frequent
reconfiguration needed by the number of different part types and the interruption of the information flow about quality with
each reconfiguration of the system. It is important to quickly rebuild quality information flow with MCP system’s reconfiguration
synchronously. This paper introduces a defect tracking method based on Quality Function Deployment for every MCP system module.
A defects tracking matrix (DTM) based on the House of Quality directly connects manufacturing technologies with quality defects
inside a MCP module. Each MCP reconfiguration requires the DTMs’ rearrangement and DTM-chain is proposed. A dynamic reconstructing
algorithm synchronizes the DTM-chain with each MCP reconfiguration. A case study demonstrates the usefulness of the DTM and
DTM-chain.
相似文献
Hua WangEmail: |
997.
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999.
基于功率变化率的刀具破损监测系统 总被引:6,自引:0,他引:6
介绍一种以刀具切削功率变化率为信号,利用单片机进行处理与判断,实现加工过程刀具破损在线监测的系统组成和工作原理,讨论了提高刀具破损报警准确性的措施。 相似文献
1000.
为了精确测量镀锡板的镀锡量,提高镀锡板生产和进口的质量,用稀盐酸作电解液,根据电解剥离原理,采用微分电位法,解决了各层界面自动分层难题,研制出镀锡板镀锡量检测分析仪。仪器以Cygnal F005单片机作为智能部件,既可提供本机显示和打印测量结果的功能,又能通过USB接口与上位机配合使用。对双电层电容充电电流引起的测量误差作了修正。仪器小型轻便,操作界面友好。 相似文献