渤海Q油田层间干扰定量表征技术及应用

针对渤海Q油田北区块油井多层合采导致的含水上升快、采油速度低、采出程度差异大等问题,对不同含水阶段的层间干扰现象进行分析,建立了层间干扰定量表征技术,并结合Q油田油藏类型和储层纵向非均质性,研究了底水关闭前后不同含水阶段的层间干扰规律,提出了高含水期细分层系开发的技术对策:对北区块进行调整,将原来的一套开发层系细分为三套开发层系,采用水平井开发,同时对老井进行关层。调整后全区含水率下降了10%,采油速度提高了0.5%,采收率提高了10.6%。     

用于微波/射频集成电路的一种新型低损耗介质——多孔硅及氧化多孔硅厚膜

提出在单片微波集成电路(MMIC)中用多孔硅/氧化多孔硅厚膜作微波无源器件的低损耗介质膜.研究了厚度为70μm的多孔硅/氧化多孔硅厚膜在低阻硅衬底上的形成,这层厚膜增加了衬底的电阻率,减少了微波的有效介质损耗.通过测量在低阻硅衬底上形成的氧化多孔硅厚膜上的共平面波导的微波特性,证明了在低阻硅衬底上用厚膜氧化多孔硅可以提高共平面传输线(CPW)的微波特性.     

蓝宝石衬底上使用氮化硅钝化的AlGaN/GaN高电子迁移率晶体管的研制与特性分析

本文研制了高性能的AlGaN/GaN高电子迁移率晶体管并进行了特性分析。诸如氮化铝插入层、氮化硅钝化、高宽窄比的T型栅、减小欧姆接触电阻和缩短漏源距离等技术被用于提高器件性能。使用半导体参数分析仪和矢量网络分析仪分别对前制器件的直流和交流特性进行了表征。所得80nm栅长的器件其最大漏极电流密度为1.41A/mm,该结果为到目前为止国内文献报道的最大值。同时测得峰值跨导为317mS/mm,特征频率为74.3GHz,最高振荡频率为112.4GHz。     

地下盐穴储气库盐岩热损伤机理

基于变质量热力学原理，建立盐穴储气库注采过程中的工程热力学分析数学模型，给出了单个注气和采气过程中温度和压力随时间变化的解析解，作为数值模拟的边界条件。根据金坛储气库的基本数据和盐岩实验研究参数，利用COMSOL Multiphysics有限元软件建立单腔盐穴注采过程的温度-应力耦合模型，模拟恒定注采速率下盐腔围岩的拉伸损伤、剪切损伤和膨胀损伤分布情况，研究夹层和热应力对围岩损伤的影响。基于热应力理论，结合模拟结果分析盐穴储气库注、采气过程中围岩的热损伤机理。模拟结果表明：在热应力存在的情况下，夹层的存在促进了围岩损伤的产生，无夹层时围岩无损伤发生，有夹层时围岩存在损伤；注气过程和采气过程的损伤发生位置存在差别：注气过程损伤多发生在夹层附近的盐岩中，采气过程损伤多发生在夹层中；膨胀损伤的范围最广，且损伤范围覆盖了前2种损伤，因此实际生产过程中推荐使用膨胀损伤判据，损伤评价结果更为保守。     

渤海L油田不同开发方式下注采井钻遇隔夹层位置优选实验研究

针对隔夹层发育的海上L油田剩余油挖潜难点,通过提取典型井组地质参数,分别设计注入井单独钻遇隔夹层和生产井单独钻遇隔夹层2种情况下的6种注采井间隔夹层分布模型,对每种隔夹层分布模型均开展水驱和早期注聚实验,一共完成12个二维平板可视化模型实验。实验结果表明,在基础井网下,对于注水井钻遇隔夹层和生产井钻遇隔夹层,其隔夹层相对长度为井距2/3的布井模型的采收率指标均最高。注聚井组筛选应优先考虑2种情况:第一种为注水井钻遇隔夹层且隔夹层相对长度为井距1/3的模型,注聚采收率增幅可达18.2%;第二种为生产井钻遇隔夹层且隔夹层相对长度为井距2/3的模型,注聚采收率增幅可达19.0%。     

有软弱夹层岩体边坡稳定分析安全系数的确定

具有软弱夹层的岩体边坡稳定性分析，是水利水电工程设计和施工中经常遇到的重要问题．在我国软弱夹层引起岩体边坡失稳的情况较多，已造成巨大的损失．从岩体边坡整体滑动的几种型式出发，述及了以往稳定分析方法与安全系数的选取，以及稳定安全系数大小与边坡失稳的关系，从而根据我国抗剪强度参数的取值原则与设计经验，建议了设计应该遵循的稳定安全系数．     

Improved performance of inverted polymer solar cells by utilizing alcohol-soluble oligofluorenes as efficient cathode interlayers

Two star-shaped oligofluorenes with hexakis(fluoren-2-yl)benzene as core are designed and synthesized, namely Tn0 and Tn1. Diethylamino groups are attached to the side chain of fluorene units of Tn0 and Tn1 and enable them alcohol solubility, additional hydrophobic nhexyl chains are grafted on the π-extended fluorene arms of Tn1. Power conversion efficiency (PCE) as high as 8.62% and 8.80% are achieved when utilizing Tn0 and Tn1 as cathode interlayers in inverted polymer solar cells, respectively. The work function of ITO effectively decreased by introducing interlayer, resulting in high Voc of the device, besides, the wetting properties of the interlayers can be tuned by modifying the oligofluorenes with π-extended structure, and the more hydrophobic interlayer will benefit the device performance with enhanced Jsc and FF.     

Photolithographic patterning of PEDOT:PSS with a silver interlayer and its application in organic light emitting diodes

A patterning scheme for poly(3,4-ethylenedioxythio-phene):poly(styrenesulfonate) (PEDOT:PSS) is reported. With a silver interlayer, the conductive PEDOT:PSS film can be patterned down to micrometer scales by traditional photolithography, and this patterning scheme can be applied on large-area flexible substrates. Through systematical investigations, the patterning processes have no obvious influence on both the bulk and surface properties of PEDOT:PSS films. Efficient organic light emitting diodes (OLEDs) are realized based on this patterned PEDOT:PSS anode, and they show comparable performance to those devices with an indium tin oxide (ITO) anode. High-resolution OLED pixel arrays are also demonstrated. Our interlayer approach here has an advantage of patterning PEDOT:PSS with high resolution and large scale, and it is also compatible with traditional photolithographic processes which substantially save the capital cost. Results indicate that the photographically patterned conductive PEDOT:PSS film becomes a promising candidate for eletrical eletrode material in organic electronic applications.     

Removal of Interlayer Water of two Ti3C2Tx MXenes as a Versatile Tool for Controlling the Fermi-Level Pinning-Free Schottky Diodes with Nb:SrTiO3

Striving for the sixth-generation communication technology discovery, semiconductors beyond Si with wider bandgaps as well as non-conventional metals are actively being sought to achieve high speeds whilst maintaining devices miniaturization. 2D materials may provide the potential for downsizing, but their functional advantage over existing counterparts still longs to be discovered. Along that path, surface-adsorbed or bulk-intercalated water molecules remaining after wet-chemical synthesis of 2D materials are generally seen as obstacles to high-performance achievement. Herein, the control of such water within the interlayers of solution-processed metallic 2D titanium carbide (MXene) by vacuum annealing duration is demonstrated. Moreover, the impact of water removal on work function (WF) and functional terminations is unveiled for the first time. Furthermore, the usefulness of such water for controlling a novel Schottky diode in contact with an n-type oxide semiconductor, niobium-doped strontium titanate (Nb:SrTiO₃) is observed. The advantage of MXene compared to conventional gold as facile processing, WF tunability, and lower turn-on voltage in the Schottky anode application is highlighted. This fundamental study shows the way for a novel Schottky diode preparation in atmospheric conditions and provides implications for further research directions aiming at commercialization.     

Scalable Construction of Multifunctional Protection Layer with Low-Cost Water Glass for Robust and High-Performance Zinc Anode

Zinc ion batteries (ZIBs) have recently attracted tremendous interest for being low-cost, environmentally benign, and high energy density. However, the large-scale practical application of ZIBs is hampered by well-known undesirable dendrite growth and serious side reactions of the Zn anode during the long-term cycling process. Herein, a multifunctional water-glass artificial protection layer with enormous Si─O functional groups is constructed on Zn anode through a simple spin-coating method. The theoretical and experimental investigation suggests that the as-constructed interface with rich Si─O hydrophilic functional groups on Zn anode could facilitate the even distribution of electric field distribution and homogeneous wettability, navigate uniform zinc deposition/stripping along the (002) plane, and subsequently lead to well-suppressed dendrite growth and effective prohibition of oxygen-involved corrosion. Consequently, the water glass-modified anode achieves highly reversible Zn plating/stripping over 1500 h at a high current density of 10 mA cm⁻² in symmetrical cells, and a high capacity retention ratio of 79.4% at the current density of 5 A g⁻¹ in full cells paired with V₂O₅ cathode. This proposed water glass coating layer design is cheap, up-scalable, and facile, which could substantially accelerate the rapid commercialization of zinc anodes and unleash the full potential of renewable ZIBs for next-generation large-scale energy storage.