Comparison of structural and photoluminescence properties of ZnO thin films grown by pulsed laser deposition and ultrasonic spray pyrolysis

ZnO thin films have been deposited by pulsed laser deposition (PLD) and ultrasonic spray pyrolysis (USP) method, respectively. X-ray diffraction and transmission electron microscopy characterizations indicate that ZnO film grown by PLD exhibits better crystallinity than that grown by USP. Photoluminescence spectra show that the near-band edge ultraviolet emission of film grown by PLD is narrower and shifts to higher energy, compared with that of film grown by USP. In the visible range, ZnO film grown by PLD exhibits four local level emission centered at 470 nm, 486 nm, 544 nm, and 613 nm, respectively, while the film grown by USP only presents a weak broad band emission centered at 502 nm. Hall measurement shows higher carrier density and lower hall mobility in ZnO film grown by PLD than that in film grown by USP. The higher density of intrinsic defects as well as higher crystallintiy is considered to account for the difference of photoluminescence in ZnO film grown by PLD with that in film grown by USP.     

The fabrication of ZnO/MgO multilayer films on Si (1 1 1) by PLD

ZnO/MgO multilayer thin films were fabricated on Si (1 1 1) substrates by pulsed laser deposition (PLD) at 600 °C for 30 min. The oxygen pressure and laser repetition were kept at 20 Pa and 5 Hz, respectively. The PL measurements suggest that the UV peaks have a blue excursion of 4 nm from 379 to 375 nm, compared with ZnO films. The XRD analysis indicates that the position of ZnO (0 0 2) peaks from ZnO/MgO multilayer films have about 0.12° shift from 34.421°, that of ZnO films, to 34.545°. From TEM images, the thickness of the films is about 200 nm. By HRTEM and SAD images, the crystal phases and the polycrystalline state were observed in the multilayer films.     

无损检测及其新技术

介绍了当前无损检测领域中常用技术,如超声、射线、渗透、涡流、磁粉等常规无损检测技术,以及迅速发展并受人们普遍关注的超声相控阵、激光、红外、微波等无损检测新技术,包括其基本原理、技术特点及应用范围.     

利用相位光栅的衍射检测啁啾飞秒激光脉冲

分析了一种0ˉπ相位光栅在啁啾飞秒激光脉冲照射下的菲涅耳衍射.通过选择相位光栅的结构,可以使衍射光的±1级分量最大.提取±1级衍射分量,并通过两反射镜将这束光在远处干涉.当飞秒激光脉冲的宽度一定时干涉条纹的强度与飞秒激光脉冲的啁啾系数有关.通过检测干涉条纹的强度,可以间接测量飞秒激光脉冲的啁啾系数.     

火力发电厂锅炉用碎渣机凸轮材料磨损性能研究

采用激光和等离子弧淬火表面硬化技术,对火力发电厂锅炉用碎渣机凸轮常用材料合金钢40Cr进行激光表面硬化处理,并将其在销盘式摩擦试验机上进行了摩擦磨损试验.结果表明,激光硬化处理的表面能够有效地改善材料表面硬度和耐磨性.     

XeCl准分子激光器泵浦电参数的优化设计

利用理论模拟方法计算XeCl准分子激光器的激光输出特性,用正交设计方法选择激光器的泵浦电源参数,通过优化分析寻找到了几种可行的最佳泵浦电源参数组合.     

激光熔覆生物陶瓷涂层及界面的热力学计算

在医用金属材料表面形成一层生物陶瓷是制备高性能、高可靠性生物植入材料的有效途径．采用激光处理技术在钛合金表面同步合成及熔覆了以羟基磷灰石为主的生物陶瓷涂层复合材料，激光熔覆制备生物陶瓷涂层覆界面反应是非常复杂的过程，其中包括很多的化学反应，从物理化学角度对涂层覆界面反应进行热力学计算，计算结果表明：在该实验条件下，完全具备合成羟基磷灰石、磷酸钙等生物陶瓷涂层的热力学条件，而且也满足界面处发生化学反应生成钛酸钙等新相的条件。     

The characteristics of arc beam shaping in hybrid plasma and laser deposition manufacturing

1 Introduction With the development of astronautical technology, more and more functions of the components of high-temperature materials are required. In order to meet the demand, far more advanced higher temperature materials, such as the high-temperature alloys or high-temperature melting point materials, should be first developed. In addition, the molding technological process of high-temperature materials should also be developed. Nowadays the traditional high-temperature technological pro…     

Numerical Simulation of Multi-track and Multi-layer Temperature Field on Laser Direct Metal Shaping

To improve the mechanical properties of the parts fabricated by Laser Direct Metal Shaping(LDMS),it is of great significance to understand the distribution regularities of transient temperature field during LDMS process.Based on the“el- ement birth and death”technique of finite element method,a three-dimensional multi-track and multi-layer model for the transient temperature field analysis of LDMS is developed by ANSYS Parametric Design Language(APDL)for the first time.In the fab- ricated modal,X-direction parallel reciprocating scanning paths is introduced.Using the same process parameters,the simulation results show good agreement with the microstructure features of samples which fabricated by LDMS.     

Sintering and Electronic Conducting Properties of Lao.7Ca0.3CrO3 Perovskite Synthesized by a Glycine-nitrate Process

La0.7 Ca0.3 CrO3 powder consisting of superfine and uniform particles （ 100-200 nm ） were synthesized using a glycine-nitrate process （ GNP ）. The sintering and electronic conducting properties of La0.7 Ca0.3 CrO3 were invetigated in the sintering temperature range of 1 200-1 450 ℃. The desired morphology of the powder significantly improved its sinterability. La0.7 Ca0.3 CrO3 ceramics sintered at 1 250-1 450 ℃ show high relative densities above 95 % . The ceramics sintered at 1 250-1 400 ℃ have very similar electronic conduct- ing properties, providing electronic conductivities around 55 Ω^-1 cm^-1 at a measuring temperature of 800 ℃ . Further increasing the sintering temperature to 1450 ℃ led to an apparent degradation of electronic conducting properties. This research demonstrates the advantage of the GNP in producing La0.7 Ca0.3 CrO3 with respect to the enhanced sintering properties and superior electronic conducting properties.