Polymerization behavior and polymer properties of eosin-mediated surface modification reactions

Surface modification by surface-mediated polymerization necessitates control of the grafted polymer film thicknesses to achieve the desired property changes. Here, a microarray format is used to assess a range of reaction conditions and formulations rapidly in regards to the film thicknesses achieved and the polymerization behavior. Monomer formulations initiated by eosin conjugates with varying concentrations of poly(ethylene glycol) diacrylate (PEGDA), N-methyldiethanolamine (MDEA), and 1-vinyl-2-pyrrolidone (VP) were evaluated. Acrylamide with MDEA or ascorbic acid as a coinitiator was also investigated. The best formulation was found to be 40 wt% acrylamide with MDEA which yielded four to eightfold thicker films (maximum polymer thickness increased from 180 nm to 1420 nm) and generated visible films from fivefold lower eosin surface densities (2.8 versus 14 eosins/μm²) compared to a corresponding PEGDA formulation. Using a microarray format to assess multiple initiator surface densities enabled facile identification of a monomer formulation that yields the desired polymer properties and polymerization behavior across the requisite range of initiator surface densities.     

Facial detection and location based on skin color and eye characteristic

This paper comes true a system of facial detection and location. Firstly, it realizes the facial detection of candidate region used skin color for the given image, and considers the influence of similar skin. Secondly, it realizes the location for eye region used the gray characteristic of eye and correction of central measurement, and makes further selection for facial candidate region. The end, it normalizes the facial image and makes it as front standard image, so realizes the facial characteristic location.     

The Fabrication and Characterization of Single‐Component Polymeric White‐Light‐Emitting Diodes

By using Ni⁰‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m^–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33).     

垂直定向液晶光阀及光电特性的研究

系统地讨论了排列相畸变模式液晶光阀结构，原理和制作，结合实际测试对其等效电路和电学匹配进行了分析，详细讨论了它的光电特性及相互关系，实测的液晶垂直排列方式工作的液晶光阀性能指标为，分辨率大于５０ｌｐ／ｍｍ，白光输入灵敏度为６．７７μＷ／ｃｍ＾２，响应时间为２００ｍｓ／３００ｍｓ，白光输出对比度为２００：１。     

Influence of zero-loss filtering on electron optical phase contrast

Complex scattering amplitudes are used to calculate the phase contrast of colloidal gold particles. Comparison of measurements of the phase contrast intensity at the centre of the gold particle as a function of defocus for unfiltered and zero-loss filtered images demonstrates the increase in phase contrast achieved by zero-loss filtering even for a thick carbon substrate film. The granulation of amorphous germanium films is measured by the spatial rms (root mean square) values of image intensity in a defocus series.     

Influence of Two Salicylate Components on the Particle Size of an Oil-in-Water Emulsion with Nonionic Surfactants

This paper reports a study undertaken using techniques of static and dynamic light scattering to investigate the influence of sodium salicylate and methyl salicylate on droplet size of oil-in-water emulsions. The rates of changes were measured by determining the size and distribution of the oil droplet in the material. All emulsions showed a bimodal size distribution; the mean diameters and polydispersity were calculated from intensity. These data were analyzed with nonlinear regressions and bootstrap methodology. An amount of methyl salicylate component induced a decrease of mean diameter and standard deviation. On the contrary, sodium salicylate entailed the growth of all droplet populations and coalescence for the highest concentration.     

单液晶光阀彩色大屏幕投影显示

设计一电路,将彩色图象信息编码到黑白CRT的亮度之中,并将其写入液晶光阀,用白光读出,当编码合适时,读出的象颜色可与原图像一致。本文讨论了这一技术原理并进行了单液晶光阀彩色大屏幕投影的实验验证。     

Behaviour of mesogenic side group polyacrylates in dilute and semidilute regime

The solution behaviour of a new mesogenic side group polyacrylate in tetrahydrofuran and toluene has been investigated by static and dynamic light scattering. In the dilute regime the polymer behaves as typical polydisperse linear chains in good solvent and the dynamics is dominated by a single fast mode. Cluster formation was detected starting at a concentration around 50 g l⁻¹. It seems to be independent of the solvent as well as of polymer molecular weight. In the semidilute regime, the behaviour of the reduced osmotic modulus leads to the conclusion that repulsion between the chains is stronger than in linear macromolecules. The appearance of larger clusters was revealed above a characteristic concentration and is slightly dependent on the polyacrylate molecular weight. The dynamics was generally characterised by a fast mode related to the cooperative diffusion and by a slow mode associated with large clusters. The existence of a network of multiconnected clusters is envisaged with increasing solution concentration.     

新型微光探测器滤光玻璃

系统分析了微光探测器的结构及其原理。鉴于当前器件存在的激光致盲威胁,提出了新的改进思路。着重介绍了具有特殊激光防护性能的滤光材料,并对其原料及制备、加工过程作了系统地介绍,同时给出了一些重要的性能特征。     

Treatment of slices from carrot (<Emphasis Type="Italic">Daucus carota</Emphasis>) using high intensity white pulsed light

Experiments with washing of carrot slices using distilled water and 0.9% (w/w) NaCl in combination with varying number and pulses of high intensity white were carried out. Slices of carrot 3.5 cm in diameter and 2 mm thick were inoculated using diluted dispersions of yeasts (Saccharomyces cerevisiae) for varying time (0–240 min) and then the slices were treated with high intensity pulsed white light (one pulse = 0.7 J/cm²) using from none to 24 pulses. The major part of the yeast cells were killed using two pulses of light. The studies included washing of inoculated slices up to five times using salt 0.9% (w/w) NaCl and distilled water and inoculation at 22 °C for between 5 and 120 min. It was concluded that treatment of carrot slices with high intensity white light may reduce the load of yeast cells with up to 6 log cycles. Inoculation time at 22 °C had no effect on the maximum load of yeast cells.