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41.
液氨贮存设计分析 总被引:3,自引:0,他引:3
马朝玲 《硫磷设计与粉体工程》2004,(1):20-22
氨是生产含氮肥料及尿素的基本原料,为确保原料供应,必须设置其贮存设施。介绍了常温中压、降温低压和低温常压三种不同的液氨贮存工艺及其特点,并以某大型氨站设计为例,分析了液氨贮存工艺流程、主要设备、材料的选型和工艺参数的确定。 相似文献
42.
The stereoselective hydrogenation of thymol was studied in liquid phase over several nickel catalysts, modified by coimpregnation of inorganic compounds containing chlorine. The total activity of all catalysts studied was decreased and was on the same order of magnitude, indicating that chlorine even after reduction remains on the surface and is responsible for the poisoning effects. Such blocking of accessible sites results in similar reaction rates for the catalysts studied. Selectivity and stereoselectivity to menthols and menthones changed significantly. The modifiers could influence the rate of keto-enol transformations, which is thought to be the key selectivity and stereoselectivity governing step. 相似文献
43.
44.
Taisuke Ito 《Polymer》1982,23(10):1412-1434
Results for the compressibilities of a wide range of polymer crystals along the fibre- and the transverse crystal axes are presented. Good agreement is found between the theoretical and the experimental results of different authors. 相似文献
45.
Phase transitions of canola oil sediment 总被引:3,自引:0,他引:3
H. Liu C. G. Biliaderis R. Przybylski N. A. M. Eskin 《Journal of the American Oil Chemists' Society》1993,70(5):441-448
Canola sediment was obtained from an industrial filter cake by solvent extraction. When heated in the differential scanning
calorimeter (DSC) (5–100°C), the sediment exhibited a single narrow melting peak at around 74.8°C. No solid-state polymorphic
transformation of the material could be detected over this temperature range. The X-ray powder diffraction pattern of canola
sediment resembled waxes from other sources with an orthorhombic unit cell. The phase transition behavior of canola sediment
in oil was studied by both DSC and polarizing microscopy. With increasing ratio of oil/sediment, a reduction in both melting
temperature and transition enthalpy was observed. The shape of the supercooling curve resembled that of the melting curve.
The induction time was determined by spectrophotometry and was used to calculate the interfacial free energyσ between sediment and oil; σ=4.71 erg/cm2. The effect of temperature and sediment concentration on the clouding time of canola oil was studied; the clouding time was
the shortest at 5°C. 相似文献
46.
采用Nova-Pak C18不锈钢色谱柱进行反相液相色谱分析,以甲醇:水=65:35(V/V)为注动相,以邻苯二甲醇二乙酯为内标物,用内标法测定田草灵除草剂中苄嘧黄隆和异丙甲草胺的含量,结果表明,各有效成分与内标物色谱峰分离完全,杂质无干扰,测定结果,苄嘧黄隆和异丙甲草胺的变异系数分别为0.74%和1.07%,回收率分别为99.4% ̄100.8%和99.1% ̄101.3%。 相似文献
47.
纤维素科学与技术研究进展 总被引:3,自引:0,他引:3
梁锋 《纤维素科学与技术》1993,1(3):1-14
本文综述纤维素科学与技术的研究进展。阐述了纤维素结构、纤维素的合成、纤维素液晶、功能纤维素、纤维素溶剂、纤维素裂解和纤维素的废物利用等的最新动态。 相似文献
48.
Three-dimensionally ordered long-range macroporous carbon structures were prepared using commercially available phenolic resin
by utilizing sacrificial colloidal silica crystalline arrays as templates that were subsequently removed by HF etching after
pyrolysis in an argon atmosphere. SEM, TEM, and BET were employed to characterize the morphology and the surface area of the
porous carbon structures. The pore size (150–1000 nm) and BET surface area, which reflect pore volume (298.6 m2/g (1.32 cm3/g) ∼ 93.7 m2/g (0.12 cm3/g)), of the macroporous carbon structures produced were approximately proportional to the size (150–1000 nm) of the sacrificial
silica sphere templates used (annealing temp. 550°C). The achieved 550 nm porous carbon structures were examined to function
as potential catalyst carriers and were successfully impregnated with Ag or Pt-Ru on their inner walls after borohydride reduction
at room temperature. In addition, porous carbon patterns were fabricated using the ‘micromolding in capillary’ technique,
which has potential applications in the microreaction technology. 相似文献
49.
本文由无限稀释活度系数求取混合物MH-81状态方程的二元相互作用参数,预测了二元混合物的汽液平衡,获得了较满意的结果。 相似文献
50.
K. Remananda Rao 《加拿大化工杂志》1993,71(5):685-688
A unique characteristic linear dimension (d), defined as the cube root of the specific liquid holdup (hsp) in the packed column, was used to correlate successfully the liquid film mass transfer coefficient kLa for gas absorption-desorption for sparingly soluble gases in liquids below loading. To produce this simple, dimensionless correlation, kLa data reported in literature were used, covering a wide range of physical properties of liquids, packings and operating conditions. This new approach showed operating holdup as an important factor in gas liquid mass transfer. 相似文献