Preparation of lithium-ion polymer battery using LiNi1/3Co1/3Mn1/3O2 as a cathode material and its electrochemical properties

In this work, LiNi_1/3Mn_1/3Co_1/3O₂ powders were synthesized from co-precipitated spherical metal hydroxide. In the voltage range of 2.8–4.2, 2.8–4.4, and 2.8–4.6 V, the discharge capacities of LiNi_1/3Mn_1/3Co_1/3O₂ electrode were 163, 177, and 193 mAh⋅g⁻¹, respectively. A gel polymer electrolyte (GPE) was also prepared using polyoxyalkylene glycol acrylate (POAGA) as a macromonomer. LiNi_1/3Mn_1/3Co_1/3O₂/GPE/graphite cells were prepared and their electrochemical properties were evaluated at various current densities and temperatures. The ionic conductivity of the GPE was more than 6.2 × 10⁻³ S⋅cm⁻¹ at room temperature. POAGA-based cells were showed good electrochemical performances such as rate capability, low-temperature performance, and cycleability.     

Preparation of a sensor substrate using functionalized mesoporous silica on a gold film for surface plasmon resonance (SPR) spectroscopy

The use of surface plasmon resonance (SPR) spectroscopy has been applied to a wide variety of fields such as biosensors and surface analysis instruments. In general, a SPR substrate is prepared using self-assembled monolayer (SAM) method of organic molecules as receptor for the target on a layer of gold or silver. However, mesoporous inorganic materials such as SBA-15 have benefits as sensor substrate for SPR. Mesoporous silica has a large surface area which receptor molecule can be attached and has a rigid body which has an excellent stability in the extreme condition compared to organic sensing layer. We prepared an organic modified mesoporous silica and successfully immobilized it on a gold surface, in an attempt to use as a substrate for SPR spectroscopy. For the comparison of sensitivity of prepared substrate, Pt²⁺ detection was selected as a model system. Substrate prepared in this study exhibited the capability of selective sensing for Pt²⁺ ions.     

一种环保化学储能电池——钒氧化还原液流电池

可再生能源需要性能优良的储能电池与之配套，因此，研究和开发价廉、高效率的储能系统是十分必要的。本文通过介绍钒氧化还原液流电池的原理和特点，指出钒电池是一种潜力巨大的新型环保储能电池。同时介绍钒电池制备和应用时的三大技术关键及一定的解决方法。     

离子交换过程数学模型及仿真研究

根据离子交换原理建立了离子交换系统模型。并以钨离子交换为例。编写仿真软件求解该模型，获得淋洗曲线及各交换参数，通过与实验结果验证，计算机仿真数据与实验结果大致一致。     

Using selective precipitant for uranyl ions — Fundamental studies for evaluating the precipitant performance

We have developed a simple reprocessing process for spent FBR fuels using N-cyclohexyl-2-pyrrolidone (NCP) which has selective precipitation ability for UO₂²⁺ ions. It was confirmed that NCP has sufficient precipitation ability for UO₂²⁺ ions, decontamination capability (separation of UO₂²⁺ from simulated fission products), and resistance to γ-ray radiation in nitric acid solutions. These findings indicate that NCP is applicable to our reprocessing process. We have also evaluated performances of other precipitants such as N-n-propyl-2-pyrrolidone (NProP), N-n-butyl-2-pyrrolidone (NBP), and N-n-butyl-2-pyridone (NBPyr). It was found that higher decontamination factors (DFs) are obtained by using NProP and NBP. This can be interpreted that the hydrophobicity of NProP and NBP is lower than that of NCP. Furthermore, we have obtained an experimental result that the resistance of NBPyr to γ-ray radiation is superior to that of NCP.     

液态金属离子源发射系统电场的模拟分析

发射系统是液态金属离子源的关键部件之一，它的性能的优劣直接影响到整个离子源的工作稳定性和可靠性。因而对其发射系统进行仿真分析，可以很好地指导液态金属离子源的设计制造。本文采用国际上重视的动态喷流柱模型，利用模拟电荷法对液态金属离子源的发射系统的电场进行了计算分析，画出了发射尖端电场强度随不同参数变化的曲线，得出发射尖端表面场强与球冠半径、发射体突出臂长度密切相关，而与引出电极的结构关系甚小的结论，因此液态金属离子源发射特性（如角电流强度）的改善，必须在发射尖的设计制作上下功夫。从而为液态金属离子源的设计提供了一个有效的辅助工具。     

端部中空离子源的磁路研究

研究了端部中空离子源的磁路设计.在简要叙述端部中空离子源的基本原理及其对磁场要求的基础上,考虑了在设计离子源磁路时的关键问题和解决方法,并给出了实验结果和分析结论.     

用于处理高浓度钨酸钠溶液的离子交换新工艺

开发了离子交换新工艺用于处理高浓度钨酸钠溶液。与传统工艺相比,新工艺既保持了传统工艺的优点,又突破了对交前液浓度的限制,可在高的WO3浓度、高的NaOH浓度的条件下实现钨的吸附、净化和转型。吸附时对溶液流速的限制也大幅度放宽。由于采用高浓度溶液进行离子交换,稀释用水可以大幅度削减。相应车间建筑空间和动力消耗也得以下降,设备的处理能力则相对上升。另外交后液体积锐减,易于处理甚至处理后回用以降低化工原料NaOH的消耗和环境污染。     

离子束辅助沉积铌提高铀的抗腐蚀性能研究

利用离子注入技术在铀表面进行了离子束辅助沉积铌和离子注入铌形成表面改性层，并对改性层的厚度、注入元素的分布进行俄歇电子能谱（AES）分析和表面相及结构的X射线衍射谱（XRD）分析，用电化学极化法测试抗腐蚀性能。结果表明：离子束辅助沉积表面改性层比离子注入表面改性层明显增厚，铀的耐蚀性得到进一步改善。最后讨论了注铌改性层耐蚀性提高的原因。     

Modification of Boundary Parameters and Fluctuations by IBW and LHCD in the HT-7 Tokamak

Measurements of boundary parameters and their fluctuations have been performed in ohmic (OH) plasma and Ion Bernstein Wave (IBW) and Lower Hybrid Current Drive (LHCD) enhanced confinement plasma using a pneumatically driven Langmuir probe array on HT-7 toka-maX. In the enhanced confinement plasma~ the gradients of electron density and temperature become higher and a transport barrier comes into being in the vicinity of the limiter. The boundary potential shows a clear modification in the same region. The fluctuation levels are significantly depressed and the coherences between fluctuations are reduced evidently in the enhanced plasma.Meanwhile, we obtained the spectral features and the poloidal phase velocity of fluctuations us-ing a two-point correlation technique and found obvious modifications of the turbulence and the poloidal flow. The results suggest that the improved confinement in the IBW and LHCD enhanced plasma is at least partially due to the modification of the boundary parameters and the suppression of the boundary fluctuations and fluctuation induced fluxes.