熔融碳酸盐燃料电池(MCFC)用γ-LiAlO_2粉末的制备

本文简介了熔融碳酸盐燃料电池(MCFC)及其优点;叙述了合成LiAlO_2的方法,用Al_2O_3(a,γ)成功地制得了稳定的适合于MCFC用的γ-LiAlO_2,在MCFC工作温度(923K)下,β-LiAlO_2是不稳定的;973-1073K时,β-LiAlO_2向γ-LiAlO_2转变速度明显增大;a-LiAlO_2要在1073K以上转变为γ-LiAlO_2.     

Al掺杂对锰酸锂结构与性能的影响

采用固相法合成了Al掺杂的尖晶石LiAlxMn2-xO4(x=0～0.4).通过X射线衍射对LiAlxMn2-xO4的物相进行了研究,并探讨了Al掺杂对材料的充放电性能和电子电导率的影响.合成的LiAlxMn2-xO4均为纯尖晶石相.随着Al的掺入,LiAlxMn2-xO4的充放电循环性能得到改善,Al含量越高,循环过程中的容量衰减越小.电子电导率测试结果表明:掺杂Al后,降低了材料的电子电导率,这与Al的掺入降低了晶体中电子的离域作用有关.     

LiCoxMnyNi1-x-yO2电极材料的研究进展

LiCoxMnyNi1-x-yO2电板材料是当前锂离子电池新一代正板材料的研究热点之一。介绍了锂离子电池正板材料LiCoxMnyNi1-x-yO2的结构与性能,总结了制备方法、制备工艺参数对其性能的影响,对LiCoxMnyNi1-x-yO2的掺杂改性作了综述,并对锂离子电池正板材料的发展方向作了展望。     

注碳外延硅的荧光特性研究

研究了注碳外延硅经氢气退火及电化学腐蚀处理后的荧光特性。经能量为50keV,剂量为2×1016cm-2的碳离子注入后的外延单晶硅片,在氢气氛下高温退火及电化学腐蚀处理。荧光谱仪分析表明电化学腐蚀是蓝光发射的前提,并且不同的电化学腐蚀条件对发光强度和峰位影响极大。不同的激发光波长亦可影响发光谱的峰位。     

串联蓄电池均衡充电系统

用电感、二极管和开关器件构成串联蓄电池充电的均衡电路,使蓄电池在串联的情况下,实现均衡充电.分析了均衡器的工作原理,指出该均衡器具有动态分配过充电能的特点.利用蓄电池的充电电压和充电状态之间的关系,用蓄电池的状态估计法和倒推法,解决了均衡器中开关器件的PWM脉冲占空比的计算问题.整个串联蓄电池充电系统具有结构简单、灵活和可扩展的优点.     

Energy Deposition around Swift Carbon-Ion Tracks in Liquid Water

Energetic carbon ions are promising projectiles used for cancer radiotherapy. A thorough knowledge of how the energy of these ions is deposited in biological media (mainly composed of liquid water) is required. This can be attained by means of detailed computer simulations, both macroscopically (relevant for appropriately delivering the dose) and at the nanoscale (important for determining the inflicted radiobiological damage). The energy lost per unit path length (i.e., the so-called stopping power) of carbon ions is here theoretically calculated within the dielectric formalism from the excitation spectrum of liquid water obtained from two complementary approaches (one relying on an optical-data model and the other exclusively on ab initio calculations). In addition, the energy carried at the nanometre scale by the generated secondary electrons around the ion’s path is simulated by means of a detailed Monte Carlo code. For this purpose, we use the ion and electron cross sections calculated by means of state-of-the art approaches suited to take into account the condensed-phase nature of the liquid water target. As a result of these simulations, the radial dose around the ion’s path is obtained, as well as the distributions of clustered events in nanometric volumes similar to the dimensions of DNA convolutions, contributing to the biological damage for carbon ions in a wide energy range, covering from the plateau to the maximum of the Bragg peak.     

面向锂电池少量循环的二维支持域直推式健康状态预测

锂离子电池的健康状态(SOH)是反映电池老化程度的关键指标,但由于电池老化的非线性和不确定性使得SOH难以精确估计,并且受到电池数据收集的高时间成本和容量再生现象的影响,传统的数据驱动方法在历史充放电循环数较少时效果较差.针对上述问题,本文创新性地提出了一种二维支持域直推式学习(2D-RoSTL)建模思路,建立了数据由粗到细的精准划分方法,用于少量充放电循环下的SOH预测.一方面,考虑同型号多块电池的批次特性,利用历史数据和批次数据构造二维支持域扩充模型信息来源,提供了粗范围的大量可供选择的样本;另一方面,首次尝试以直推式学习的方式解决SOH预测的任务,利用离线和在线样本特征空间的信息,对每个样本进行细致划分,提升少量充放电循环情况下模型的预测可靠性.基于NASA的公开数据集,所提出的二维支持域直推式建模方法在4个电池上的预测误差均小于1.56%,实现了对锂电池充放电历史初期及再生点的精确预测.     

Superhydrophobic Paper-Based Microfluidic Field-Effect Transistor Biosensor Functionalized with Semiconducting Single-Walled Carbon Nanotube and DNAzyme for Hypocalcemia Diagnosis

Hypocalcemia is caused by a sharp decline in blood calcium concentration after dairy cow calving, which can lead to various diseases or even death. It is necessary to develop an inexpensive, easy-to-operate, reliable sensor to diagnose hypocalcemia. The cellulose-paper-based microfluidic field-effect biosensor is promising for point-of-care, but it has poor mechanical strength and a short service life after exposure to an aqueous solution. Octadecyltrichlorosilane (OTS), as a popular organosilane derivative, can improve the hydrophobicity of cellulose paper to overcome the shortage of cellulose paper. In this work, OTS was used to produce the superhydrophobic cellulose paper that enhances the mechanical strength and short service life of MFB, and a microfluidic field-effect biosensor (MFB) with semiconducting single-walled carbon nanotubes (SWNTs) and DNAzyme was then developed for the Ca²⁺ determination. Pyrene carboxylic acid (PCA) attached to SWNTs through a non-covalent π-π stacking interaction provided a carboxyl group that can bond with an amino group of DNAzyme. Two DNAzymes with different sensitivities were designed by changing the sequence length and cleavage site, which were functionalized with SPFET/SWNTs-PCA to form Dual-MFB, decreasing the interference of impurities in cow blood. After optimizing the detecting parameters, Dual-MFB could determine the Ca²⁺ concentration in the range of 25 μM to 5 mM, with a detection limit of 10.7 μM. The proposed Dual-MFB was applied to measure Ca²⁺ concentration in cow blood, which provided a new method to diagnose hypocalcemia after dairy cow calving.     

SO_4~（2－）／ZrO_2超强酸催化剂的结构表征

用ＢＥＴ法分析了制备条件对ＳＯ＿４￣（２－）／ＺｒＯ＿２超强酸催化剂的比表面和孔结构的影响，用ＳＥＭ观察了催化剂的表面形貌。结果表明，引人ＳＯ＿４￣（２－）后催化剂的比表面和比表面的热稳定性都增大了，在Ｈ＿２ＳＯ＿４浓度为１．０ｍｏｌ／１和焙烧温度约７７３Ｋ时催化剂的比表面较大。制备Ｚｒ（ＯＨ）＿４时用浓氨水得到的催化剂的比表面、平均孔径和孔体积都较大。ＳＯ＿４￣（２－）／ＺｒＯ＿２催化剂的孔为平均孔径３－５ｎｍ的中孔。ＳＥＭ结果表明，ＳＯ＿４￣（２－）／ＺｒＯ＿２催化剂的表面为很不平整的蜂窝状。     

基于状态的测控设备维护决策方法

为解决定期预防性维护存在的弊端,提出了基于状态的测控设备维护决策方法,并参照OSA-CBM标准,构建了适用于测控系统的维护决策系统。通过对状态监测、故障诊断、性能评估、状态预测等关键技术的研究表明,该方法切实可行,可进一步提升测控设备维护管理水平。