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101.
ZHU Xianjun ZHAN Hui LIU Hanxing ZHOU Yunhong 《稀有金属(英文版)》2006,25(4):303-308
Samples of LiNi0.95-xCoxAl0.05O2 (x = 0.10 and 0.15) and LiNiO2, synthesized by the solid-state reaction at 725℃ for 24 h from LiOH-H2O, Ni2O3, Co2O3, and AI(OH)3 under an oxygen stream, were characterized by TG-DTA, XRD, SEM, and electrochemical tests. Simultaneous doping of cobalt and aluminum at the Ni-site in LiNiO2 was tried to improve the cathode performance for lithium-ion batteries. The results showed that co-doping (especially, 5 at.% A1 and 10 at.% Co) definitely had a large beneficial effect in increasing the capacity (186.2 mA.h/g of the first discharge capacity for LiNio.s.42OoaoAlo.0502) and cycling behavior (180.1 mA-h/g after 10 cycles for LiNio.85CooaoAlo.osO2) compared with 180.7 mA.h/g of the first discharge capacity and 157.7 mA.h/g of the tenth discharge capacity for LiNiO2, respectively. Differen- tial capacity versus voltage curves showed that the co-doped LiNio.95_xCoxmlo.osO2 had less intensity of the phase transitions than the pristine LiNiO2. 相似文献
102.
正极添加CNTs对MH /Ni电池高倍率性能的影响 总被引:1,自引:0,他引:1
对正极中添加多壁碳纳米管(CNTs)的MH/Ni电池的高倍率放电性能进行了研究。结果表明:正极中添加少量CNTs的Ni/MH电池具有优异的高倍率放电性能。利用正极中添加少量CNTs制成的标准AA型电池的内阻在14mΩ左右;在高倍率放电条件下电池有更高的放电平台,3C放电中值电压在1.167V左右,5C放电中值电压在1.108V左右;电池循环容量保持率也高于正极中不加CNTs的电池。随着循环次数的增加,正极中添加少量CNTs的电池内阻升高幅度较小。 相似文献
103.
基于SOC的串联锂离子电池组均衡策略研究 总被引:1,自引:0,他引:1
由于一致性问题的存在,成组电池在可用容量、使用寿命等方面远不及单体电池,电池组的均衡管理对电池的成组使用者有着重要的实际意义.论文就针对锂离子串联电池组的均衡技术进行了研究,首先介绍了电池组一致性问题产生的原因,指出均衡管理的重要意义,分析了锂离子电池组SOC的一致性和基于SOC的均衡策略,详细阐述了基于SOC的均衡技术实现,最终搭建实验平台进行测试,验证了所使用的均衡策略和硬件电路的有效性. 相似文献
104.
105.
Engineering Transition Metal Layers for Long Lasting Anionic Redox in Layered Sodium Manganese Oxide
Natalia Voronina Jun Ho Yu Hee Jae Kim Najma Yaqoob Olivier Guillon Hyungsub Kim Min-Gi Jung Hun-Gi Jung Koji Yazawa Hitoshi Yashiro Payam Kaghazchi Seung-Taek Myung 《Advanced functional materials》2023,33(5):2210423
Oxygen-redox-based-layered cathode materials are of great importance in realizing high-energy-density sodium-ion batteries (SIBs) that can satisfy the demands of next-generation energy storage technologies. However, Mn-based-layered materials (P2-type Na-poor Nay[AxMn1−x]O2, where A = alkali ions) still suffer from poor reversibility during oxygen-redox reactions and low conductivity. In this work, the dual Li and Co replacement is investigated in P2-type-layered NaxMnO2. Experimentally and theoretically, it is demonstrated that the efficacy of the dual Li and Co replacement in Na0.6[Li0.15Co0.15Mn0.7]O2 is that it improves the structural and cycling stability despite the reversible Li migration from the transition metal layer during de-/sodiation. Operando X-ray diffraction and ex situ neutron diffraction analysis prove that the material maintains a P2-type structure during the entire range of Na+ extraction and insertion with a small volume change of ≈4.3%. In Na0.6[Li0.15Co0.15Mn0.7]O2, the reversible electrochemical activity of Co3+/Co4+, Mn3+/Mn4+, and O2-/(O2)n- redox is identified as a reliable mechanism for the remarkable stable electrochemical performance. From a broader perspective, this study highlights a possible design roadmap for developing cathode materials with optimized cationic and anionic activities and excellent structural stabilities for SIBs. 相似文献
106.
Duan Bin Yanyan Du Beibei Yang Hongbin Lu Yao Liu Yongyao Xia 《Advanced functional materials》2023,33(8):2211765
Aqueous rechargeable zinc batteries (ARZBs) are recently prevailing devices that utilize the abundant Zn resources and the merits of aqueous electrolytes to become a competitive alternative for large-scale energy storage. Benefiting from the unique inductive effect and flexible structure, the past five years have experienced a diversiform of phosphate-based polyanion materials that are used as cathodes in ARZBs. In this review, the most recent advances in the Zn2+ storage mechanisms and electrolyte optimization of the phosphate-based cathodes of ARZBs, which mainly focus on vanadium/iron-based phosphates and their derivatives are presented. Furthermore, in addition to significant progress on polyanion phosphate-based cathode materials, the design strategies both for electrode materials and compatible electrolytes are also elaborated to improve the energy density and extend the cycling life of aqueous Zn/polyanion batteries. 相似文献
107.
Huanran Zheng Shibin Wang Shoujie Liu Jiao Wu Jianping Guan Qian Li Yuchao Wang Yu Tao Shouyao Hu Yu Bai Jinxian Wang Xiang Xiong Yu Xiong Yongpeng Lei 《Advanced functional materials》2023,33(40):2300815
The rational design and construction of efficient and inexpensive bifunctional oxygen electrocatalysts are highly desirable for the development of rechargeable Zn–air batteries (ZABs). Although single-atom Fe sites anchored on N-doped carbon catalysts (Fe1/NC) ensure high oxygen reduction reaction activity, their unitary atomically dispersed active center faces difficult condition in catalyzing oxygen evolution reaction simultaneously. Herein, a composite catalyst containing heterointerface between Fe1/NC and selenides ((Fe,Co)Se2) is constructed. The obtained (Fe,Co)Se2@Fe1/NC exhibits extremely narrow potential gap of 0.616 V and remarkable stability in alkaline media, outperforming the benchmark catalysts (Pt/C+RuO2: 0.720 V). Experimental results and density functional theory calculations reveal that heterointerface between Fe1/NC and (Fe,Co)Se2 accelerates the electron transfer and provides more moderate adsorption sites, which endow (Fe,Co)Se2@Fe1/NC with extremely high bifunctional oxygen catalytic activity. This study not only provides a superior bifunctional catalyst for ZABs, but also enriches the application of single-atom catalysts in multifunctional energy storage and conversion devices. 相似文献
108.
Xiaolei Li Zifeng Lin Na Jin Lei Sun Xiaojiao Yang Ying Liu 《Advanced functional materials》2023,33(20):2214667
Polyoxometalates are intriguing high-capacity anode materials for alkali-metal-ion storage due to their multi-electron redox capabilities and flexible structure. However, their poor electrical conductivity and high working voltage severely restrict their practical application. Herein, the dinuclear polyoxovanadate Sr2V2O7·H2O with unusually high electrical conductivity is reported as a promising anode material for lithium-ion batteries. During the initial lithiation process, the Sr2V2O7·H2O anode experiences an electrochemically induced crystalline-to-amorphous transition. The resulting amorphous structure provides high redox activity and fast reaction kinetics via reversible V4.9+/V2.8+ redox couple through the intercalation mechanism. Furthermore, when coupled with the LiFePO4 cathode, the strong V O bonds of the amorphous anode provide excellent structural stability, with the full-cell capable of performing >12 000 cycles with a capacity retention of 72%. Another advantage of Sr2xV2O7-δ·yH2O (0.5 ≤ x ≤ 1.0) is its composition adjustability, which enables delicately regulating the Sr vacancy content without destroying the structure. The defect Sr2xV2O7-δ·yH2O (x = 0.5) electrodes show significantly improved specific capacity and rate capability without sacrificing other key properties, delivering a high specific capacity of 479 mAh g-1 at 0.1 mA cm-2 and 41.9% of its capacity in 2 min. Overall, the preliminary study points the way forward for the facile preparation of high-quality polyoxometalates for advanced energy storage applications and beyond. 相似文献
109.
Jiacheng Yin Na Li Ming Liu Zhigang Li Xuemin Wang Mingren Cheng Ming Zhong Wei Li Yunhua Xu Xian-He Bu 《Advanced functional materials》2023,33(21):2211950
Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g−1 at 300 mA g−1), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g−1), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO4 unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials. 相似文献
110.
Zhongzhe Li Yufang Chen Xiaoru Yun Peng Gao Chunman Zheng Peitao Xiao 《Advanced functional materials》2023,33(32):2300502
Lithium metal batteries (LMBs), due to their ultra-high energy density, are attracting tremendous attentions. However, their commercial application is severely impeded by poor safety and unsatisfactory cycling stability, which are induced by lithium dendrites, side reactions, and inferior anodic stability. Electrolytes, as the indispensable and necessary components in lithium metal batteries, play a crucial role in regulating the electrochemical performance of LMBs. Recently, the fluorinated electrolytes are widely investigated in high-performance LMBs. Thus, the design strategies of fluorinated electrolytes are thoroughly summarized, including fluorinated salts, fluorinated solvents, and fluorinated additives in LMBs, and insights of the fluorinated components in suppressing lithium dendrites, improving anodic stability and cycling stability. Finally, an outlook with several design strategies and challenges will be proposed for novel fluorinated electrolytes. 相似文献