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81.
ABSTRACT: The thermal evolution behavior of the organic free radicals induced in irradiated black pepper was studied by electron spin resonance spectroscopy. To analyze the time-dependent evolution process, we used the theory of transient phenomena, that is, an ordinal differential equation, as well as the nonlinear least squares numerical method. We found that the radical evolution that occurred in the irradiated pepper obeys a single exponential function and yields a unique time constant. The evolution of the organic free radical undergoes a simple reaction process of a single radical species. 相似文献
82.
浅谈小型局域网的组建与应用 总被引:1,自引:0,他引:1
李科峰 《网络安全技术与应用》2007,(3):31-32
随着计算机应用技术与通讯技术的发展以及在实践中的广泛应用,智能化和网络化成为必然趋势,局域网的应用可以营造一个现代化的高效、快捷、安全的环境,也可以使计算机以及其他硬件的功能得到充分的发挥。 相似文献
83.
Flavio S. Damos 《Electrochimica acta》2006,51(7):1304-1312
In the present work an investigation of the effects of the electropolymerization mode on the optical properties associated to the doping/dedoping processes of nanometric films of polypyrrole (PPy) is reported, monitoring in situ and in real time using simultaneously surface plasmon resonance and electrochemical techniques (ESPR). The electropolymerization of pyrrole was performed by potentiostatic, potentiodynamic and galvanostatic methods and the use of the ESPR technique showed that the electropolymerization mode is essential to the stability of polymer and the reversibility of its optical properties during the doping and dedoping processes. Thus, the optical properties of oxidized and reduced film were obtained by nonlinear least square fitting using Fresnel equations for a four-layer system. Then, the values of the real and imaginary parts of the complex dielectric constant for PPy fims were correlated with the polymer doping level. Finally, quartz crystal microbalance measurements were also applied to obtain correlation between doping/dedoping processes and the changes in the real and imaginary parts of the dielectric constant of the polypyrrole film, showing that the doping and dedoping processes in the polypyrrole film can act directly on its optical properties while the ESPR technique can give the same information indirectly. 相似文献
84.
为了改善筛分机械的使用环境,降低筛分机械的噪声,从噪声源入手,从内因和外因两个方面分析了筛分机噪声的形成原因。论述了USL和USK系列振动筛在降低噪声方面所采取的先进技术措施。 相似文献
85.
A localized surface plasmon resonance based immunosensor for the detection of casein in milk 总被引:2,自引:0,他引:2
Ha Minh Hiep Kagan Kerman Do-Kyun Kim Yuzuru Takamura 《Science and Technology of Advanced Materials》2007,8(4):331-338
In this research, a localized surface plasmon resonance (LSPR) immunosensor based on gold-capped nanoparticle substrate for detecting casein, one of the most potent allergens in milk, was developed. The fabrication of the gold-capped nanoparticle substrate involved a surface-modified silica nanoparticle layer (core) on the slide glass substrate between bottom and top gold layers (shell). The absorbance peak of the gold-capped nanoparticle substrate was observed at ∼520 nm. In addition, the atomic force microscopy (AFM) images demonstrated that the nanoparticles formed a monolayer on the slide glass. After immobilizing anti-casein antibody on the surface, our device, casein immunosensor, could be applied easily for the detection of casein in the raw milk sample without a difficult pretreatment. Under the optimum conditions, the detection limit of the casein immunosensor was determined as 10 ng/mL. Our device brings several advantages to the existing LSPR-based biosensors with its easy fabrication, simple handling, low-cost, and high sensitivity. 相似文献
86.
Evaggelia D. Tzika Vassiliki Papadimitriou Theodore G. Sotiroudis Aristotelis Xenakis 《European Journal of Lipid Science and Technology》2008,110(2):149-157
The autoxidation at alkaline pH and enzymatic oxidation by mushroom tyrosinase of oleuropein, the dominant biophenol present in the fruits and leaves of Olea europea, was followed by both electron paramagnetic resonance (EPR) and absorption spectroscopy. For comparison, the same oxidation processes were applied to 4‐methylcatechol, a simple polyphenol present in olive mill wastewaters. EPR spectra of stable o‐semiquinone radicals produced during autoxidation at pH 12 and short‐lived o‐semiquinone free radicals produced during autoxidation at pH 9.0 or tyrosinase action and stabilized by chelation with a diamagnetic metal ion (Mg2+) were recorded for both polyphenols, and the corresponding hyperfine splitting constants were determined. The UV‐Vis spectral characteristics of the oxidation of polyphenols were highly dependent on the type of polyphenol, oxidant type and the pH of the reaction. The kinetic behavior of tyrosinase in the presence of oleuropein and 4‐methylcatechol was followed by recording spectral changes at 400 nm (absorption maximum) over time. The tysosinase activity with oleuropein showed a pronounced pH optimum at pH 6.5 and a minor one around pH 8. From the data analysis of the initial rate at pH 6.5, the kinetic parameters Km = 0.34 ± 0.03 mM and Vmax = 0.029 ± 0.002 ΔA400 min–1 were determined for oleuropein. 相似文献
87.
88.
地方热电联产企业发展对策的探讨 总被引:2,自引:2,他引:0
介绍了泰州热电企业的运行情况,分析了各热电厂在技术改造、扩大热用户和强化内部考核管理方面的措施,探讨了地方热电企业应采取的对策和发展思路。 相似文献
89.
强潮河口桩式丁坝减冲促淤效果研究 总被引:3,自引:0,他引:3
钱塘江涌潮气势雄伟,世界闻名,但对海塘具有很大的破坏力.该文提出了一种新颖的丁坝型式——桩式丁坝,从现场观测资料对比、实体模型试验和机理分析三个方面,分析桩式丁坝的减冲促淤效果,探究丁坝护滩保塘的机理.与堆石丁坝比较,桩式丁坝具有设计合理、施工简易、坝体内无内压力、有效地减轻了局部冲刷、便于维护检修等一系列优点。桩式丁坝可广泛应用于各类河道整治、海塘保护等工程中. 相似文献
90.
潮州供水枢纽拦河闸计算机监控及运行调度 总被引:7,自引:7,他引:0
介绍了潮州供水枢纽工程的概况及拦河闸计算机监控系统的结构和主要功能,着重讨论了闸门的控制过程和自动运行调度,可供其他闸门工程的自动化建设参考。 相似文献