长期荷载作用对矩形钢管混凝土轴心受压柱力学性能的影响研究

考虑长期荷载作用效应的影响 ,进行了矩形截面钢管混凝土 (以下简称矩形钢管混凝土 )轴心受压构件变形和承载力的试验研究。基于美国混凝土学会 (ACI 1992 )提供的混凝土徐变和收缩模型 ,对长期荷载作用下矩形钢管混凝土构件的变形进行了计算 ,理论结果和试验结果吻合较好。利用数值方法分析了考虑长期荷载作用影响时 ,矩形钢管混凝土轴心受压柱的荷载 -变形关系曲线 ,理论计算曲线和试验曲线基本吻合。在系统分析了长细比、截面含钢率、钢材种类和混凝土强度等因素影响的基础上 ,提出了考虑长期荷载作用影响时矩形钢管混凝土轴心受压柱承载力的简化计算公式     

背面Ar~+轰击对n~-沟MOSFET特性的影响

研究了低能量背面 Ar+轰击对 n-沟 MOSFET特性的影响 .用低能量 (5 5 0 e V)氩离子束轰击 n-沟 MOSFET芯片的背面 ,能改善其阈值电压 VT、跨导 gm、沟道电导 gd 和有效迁移率 μeff等参数 .结果表明 ,随着轰击时间的增加 ,阈值电压先减小 ,随后变大 ;而跨导、沟道电导和有效迁移率先增大 ,随后减小 .实验证明 ,上述参数的变化是由于界面态密度和固定电荷密度变化的结果     

Synthesis and XPS investigation of superdense lithium-graphite intercalation compound, LiC2

The superdense lithium-graphite intercalation compound (GIC),LiC₂, first synthesized by the author was prepared by the original technique in a piston-cylinder high-pressure chamber with internal heater. Cleaved surfaces of this compound, LiC₃, LiC₆ and pristine graphite were studied by the X-ray photoelectron spectroscopy (XPS) technique. It was shown that chemical shifts of carbon do not vary in the range LiC₆ to LiC₂ which suggests that the additional lithium intercalation into LiC₆ gives no significant change in the charge transfer rate per carbon atom. Carbon/lithium atom ratios were obtained for freshly cleaved surfaces and for the surfaces after argon ion bombardment. It was shown that the bombardment results in the surface decomposition of LiC₂-GIC.     

Wear behavior of AISI D2 steel by enhanced ion nitriding with atomic attrition

An experimental study was performed to investigate the effect of atomic attrition on wear behavior of AISI D2 steel. Wear tests were conducted under three different loads (5, 10, and 20 N) and sliding speeds (100, 200, and 500 rpm), using ball-on-disk type tester and SiC ball. After wear test, the specimen nitrided with ion bombardment showed superior wear behavior. The enhanced hardness by ion bombardment could have a beneficial effect on increased wear resistance. In addition, a wider and more adhesive oxide layer formed on the worn surface of ion-bombarded specimen, because of the rougher structure on the surface by ion bombardment, could lead the surface to withstand wear for longer duration time, acting as a protective layer.     

哌嗪乙氧基雌酮的电子电离质谱和快原子轰击电离(－)质谱测定及裂解途径

哌嗪乙氧基雌酮是一种可望用于防治骨质疏松症的全新合成的雌激素类化合物，本文采用EI-MS、FAB (－) -MS 、ESI-MS三种质谱技术分别对其结构和裂解途径进行了研究。采用FAB(－) -MS，获得m/z 404［M+Na-H］^-、382［M］^-、381［M-H］^-质谱峰；采用EI-MS, 获得m/z 382 M^+•；采用ESI-MS, 获得m/z 383［M+H］⁺。分子离子m/z 382 M^+•和主要特征子离子与其结构特征相符，并解释了其中的主要特征子离子，对其结构和裂解途径进行了确证。     

The multi-structure of oxidized-reduced tungsten carbide surface(s)

The XPS of bulk tungsten carbide, partially oxidized WC surfaces at 373 and 573 K as well as tungsten trioxide have been reported. Bulk WC has been prepared from WO₃ as a starting material in a mixture of CH₄ (20%) and H₂ (80%) at 1150 K for 4 h, while partially oxidized WC surfaces were prepared by oxygen chemisorption on a clean WC surface at 200 K, then the temperatures were raised to 373 and 573 K respectively. The XPS of a freshly prepared WC reveals the presence of a small amount of WO₃ on the surface and a slightly higher concentration in the bulk. The oxygen-exposed fresh WC surfaces and surfaces treated at temperatures higher than 373 K show the presence of WO₃ in a considerable quantity depending on the length and the treatment temperature. Ar⁺ bombardment of this partially oxidized surface reduces WO₃ to WO₂ and W(0), while WC is partially reduced to W(0). Isomerization reactions of alkanes on oxygen-exposed WC surface occurs in reality on a composite surface structure containing WC, WO₃, WO₂ and elemental W(0).     

软电离质谱法与聚合物分析

本文简要叙述了软电离质谱法在聚合物分析中的应用实例。     

离子轰击膏剂渗硼试验

通过增加辅助阴极,提高无附加热源的离子渗氮炉的升温速度和使用温度,以满足离子渗硼的需要,对以硼铁为供硼剂的渗硼膏剂进行试验,选出在本试验条件下的最佳渗硼膏剂。利用此膏剂,对45钢在850℃×3h条件下进行离子渗硼,得到180μm厚的渗硼层。