Chitosan Schiff base as effective corrosion inhibitor for mild steel in acid medium

An environment friendly inhibitor, chitosan thiophene carboxaldehyde Schiff base, was synthesized by a condensation reaction of the carbonyl group of thiophene 2‐carboxaldehyde and free amino groups of chitosan. The chitosan Schiff base was characterized by UV spectroscopy, Fourier transform IR spectroscopy, elemental analysis and thermal analysis. The surface morphology of the Schiff base derivative was examined by SEM. Gravimetric and electrochemical techniques were used to explore the behaviour of the chitosan thiophene derivative as a corrosion inhibitor for mild steel in an acidic environment. The effects of inhibitor concentration, exposure time and temperature were investigated. The chitosan Schiff base showed a good inhibition performance of 92% inhibition efficiency at room temperature for 12 h of immersion in a weight loss experiment. The electrochemical results showed that the chitosan derivative acts as an effective mixed type inhibitor. The adsorption of the inhibitor followed the Temkin isotherm model. SEM and AFM techniques were used to characterize the protective layer formed on the mild steel substrate. © 2016 Society of Chemical Industry     

In situ fibre‐reinforced composite films of poly(lactic acid)/low‐density polyethylene blends: effects of composition on morphology,transport and mechanical properties

This study aimed to investigate the effects of blend composition on packaging‐related properties of poly(lactic acid) (PLA) and low density polyethylene (LDPE) blown films. Blend films with PLA contents of 5–20 wt% were produced and compared. Scanning electron micrographs of cross‐sectional cryofractured surfaces of the blend films revealed that in situ fibre‐reinforced composites were obtained. Viscosity ratio of the polymer components of ca 1 confirmed that fibre formation was favourable for this blend system. PLA microdomains were dispersed throughout the film in forms of long fibres (length‐to‐diameter ratio > 100) and ribbons. The number of fibres and ribbons increased with an increase of PLA content. Critical content of PLA was found to be 20 wt% for effective improvement of both moduli and gas barrier properties. Incorporation of poly[ethylene‐co‐(methyl acrylate)] compatibilizer showed minimal effect on PLA structure. However, it did improve moduli and O₂ barrier properties when sufficient amount (1.5 pph) was used in 10 wt% PLA/LDPE. In short, flow behaviour, ratio of polymer components and degree of compatibility together played intricate roles in the morphology and hence mechanical and transport properties of PLA/LDPE immiscible blends. © 2017 Society of Chemical Industry     

Enzymatic Writing to Soft Films: Potential to Filter,Store, and Analyze Biologically Relevant Chemical Information

Sensor‐based chemical analyses commonly enlist either the molecular recognition capabilities of biology (e.g., enzyme biosensors) or advanced information processing algorithms (e.g., the electronic nose). Here, a hybrid approach is proposed in which an enzyme is used to “filter” chemical information and write this information to a film which then serves as a permanent storage medium that can be ‘read’ repeatedly, interactively, and by multiple sensor modalities. This approach is demonstrated by analyzing common dietary phenols that are reported to offer health benefits. Specifically, the enzyme tyrosinase is used to convert these phenols into reactive quinones that graft (i.e., write) to a chitosan film. Grafting can be detected by optical, mechanical, and electrochemical sensors. Importantly, grafting confers redox activity to the films and this redox activity can be probed interactively by advanced electrochemical methods that allow the intrinsic redox reactivities to be compared, redox interactions to be identified, and biologically relevant redox activities to be examined. The transfer of chemical and biological information to a film is envisioned to provide broader access to the extensive capabilities offered by sensor technologies and signal processing methodologies.     

A method for the determination of turbulence intensity by means of a fast response pressure probe and its application in a LP turbine

This paper describes the measurements and the post-processing procedure adopted for the determination of the turbulence intensity in a low pressure turbine (LPT) by means of a single sensor fast response aerodynamic pressure probe. The rig was designed in cooperation with MTU Aero Engines and considerable efforts were put into the adjustment of all relevant model parameters. Blade count ratio, airfoil aspect ratio, reduced massflow, reduced speed, inlet turbulence intensity and Reynolds numbers were chosen to reproduce the full scale LP turbine. Measurements were performed adopting a phase-locked acquisition technique in order to provide the time resolved flow field downstream of the turbine rotor. The total pressure random fluctuations are obtained by selectively filtering, in the frequency domain, the deterministic unsteadiness due to the rotor blades and coherent structures. The turbulence intensity is derived from the inverse Fourier transform and the correlations between total pressure and velocity fluctuations. The determination of the turbulence intensity allows the discussion of the interaction processes between the stator and rotor for engine-representative operating conditions of the turbine.     

Edible mushrooms: a potential source of essential amino acids,glucans and minerals

The main chemical and biochemical constituents of nine edible mushrooms were evaluated in this study. An enzymatic method was used to determine the α‐ and β‐glucan contents, and the amino acid (AA) profiles were evaluated by RP‐HPLC‐DAD. The recommended dietary allowance (RDA) of the nutrients was evaluated. Finally, principal component analysis (PCA) was used to group the mushrooms according to their AA, glucans and chemical composition. All mushrooms evaluated can be considered as a potential and alternative source of dietary fibre (24.4–46.62%) and protein (16.47–36.96%) in a diet, with low contents of fat (1.40–2.08%). Phosphorus, potassium, iron, copper and zinc were the main minerals found in the mushrooms, whereas sodium concentration was negligible. All essential AA were detected in the mushrooms, with Pleurotus ostreatus (black oyster) representing the main source of essential amino acids among the samples. The contents of β‐glucan ranged from 1.58 to 16.91 mg g^?1 of dry matter among the mushrooms and Pleurotus eryngii presented the highest amount of this component. Pleurotus ostreatus (black oyster) and P. eryngii were also grouped together due to similarities in their phosphorous and arginine contents. Among the main results, it can highlight the high concentration of dietary fibre and essential amino acids of the edible mushrooms.     

低温压力容器用不锈钢(二)

讨论了各种低温下不同类型的压力容器构件所用奥氏体不锈钢的类型、牌号、性能及其检验。评述了奥氏体不锈钢中的奥氏体相转变为马氏体相的机制和主要影响因素,应对某些技术问题进行研究。     

Carboxymethyl sago pulp/chitosan hydrogel as an immobilization medium for activated sludge for p-nitrophenol biodegradation

In this study, carboxymethyl sago pulp (CMSP) derived from sago waste was successfully crosslinked with ferric ions in the presence of chitosan forming a novel immobilization matrix for p-nitrophenol (PNP)-acclimated activated sludge. On the basis of the shortest biodegradation time of PNP, the optimized operational conditions of immobilization were found to be: 7 w/v% CMSP, 9 g L⁻¹ of activated sludge, 0.1 M ferric ion, and 15 min of crosslinking time. Observable inhibited PNP biodegradation was exhibited by the suspended activated sludge at the initial PNP concentration of 400 mg L⁻¹. In contrast, complete mineralization was achieved by the CMSP/chitosan-immobilized activated sludge (CMSP/Ch-AS) beads. The results revealed the important role of CMSP/Ch hydrogel in protecting activated sludge from the toxicity of PNP. The CMSP/Ch-AS beads could be reused consecutively up to three and two cycles, respectively, for the biodegradation of PNP at 200 and 400 mg L⁻¹, with the attainment of more than 99% of PNP removal at each cycle. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47531.     

低气味UV光固化木器涂料的制备

通过结合欧盟RoHS指令中测试项目及标准限值、REACH法规和生产实践,对家具(UV)紫外光固化涂料做了大量的技术研发工作,通过对树脂、光引发剂等原料的筛选,研制了低气味UV光固化木器涂料。     

基于HGO12864A液晶的显示控制设计

传统的显示设备需要供应电压较高,功耗较大,已无法适应便携式仪器仪表的要求,文中介绍了一种低电压、低功耗的液晶显示器HGO12864A,设计了倍压电路,只需3 V的电压便可驱动,采用MSP430直接控制,并给出了串口显示控制方案,能显示字符、图片。通过在单片机RAM区模拟显示,能动态地显示曲线,通过实验证明,得到了很好的显示效果。     

基于富氧燃烧CCS技术对我国低碳发展的研究

本文介绍了低碳发展的理念和实现路径,分析了CCS技术为低碳发展提供了切实可行的技术基础;介绍了燃烧前捕集、富氧燃烧捕集和燃烧后捕集技术,认为富氧燃烧捕集技术综合效益较高,对于发展低碳经济而言或许是一项技术创新的解决方案。