飞秒激光烧蚀研究进展

介绍飞秒激光烧蚀材料的机理论模型，阐述飞秒激光烧蚀的特性，揭示飞秒激光烧蚀的广泛应用前景。     

Measurement of Gibbs energies of formation of CoF2 and MnF2 using a new composite dispersed solid electrolyte

Gibbs energies of formation of CoF₂ and MnF₂ have been measured in the temperature range from 700 to 1100 K using Al₂O₃-dispersed CaF₂ solid electrolyte and Ni+NiF₂ as the reference electrode. The dispersed solid electrolyte has higher conductivity than pure CaF₂ thus permitting accurate measurements at lower temperatures. However, to prevent reaction between Al₂O₃ in the solid electrolyte and NiF₂ (or CoF₂) at the electrode, the dispersed solid electrolyte was coated with pure CaF₂, thus creating a composite structure. The free energies of formation of CoF₂ and MnF₂ are (± 1700) J mol⁻¹; {fx37-1} The third law analysis gives the enthalpy of formation of solid CoF₂ as ΔH° (298·15 K) = −672·69 (± 0·1) kJ mol⁻¹, which compares with a value of −671·5 (± 4) kJ mol⁻¹ given in Janaf tables. For solid MnF₂, ΔH°(298·15 K) = − 854·97 (± 0·13) kJ mol⁻¹, which is significantly different from a value of −803·3 kJ mol⁻¹ given in the compilation by Barinet al.     

标准物质在分析测试中的重要地位及发展前景

标准物质在分析测试领域中无论在定值，方法的研究，误差确定等方面都有着重要地位。标准物质的质量保证及正确使用也应引起我们重视。随着科学技术迅速发展标准物质有着广阔发展前景。     

熔融-固相缩聚法中固相聚合对聚乳酸合成的影响

以L 乳酸单体为原料 ,熔融 -固相缩聚法合成了聚乳酸 ,重点研究了固相聚合的工艺条件。结果表明 ,绝对压力 60Pa ,氯化亚锡为催化剂 ,分段控温 ,可使聚乳酸的粘均分子量提高到固相聚合反应前的 5 3倍。通过对固相聚合产物的结晶度和熔点的分析 ,探讨了固相聚合的机理。     

Preparation and Application of Active Composite Antibacterial Material Containing Ag~ and Zn~(2 )

1Introduction Harmfulbacteriaexistanywhereintheworldsuchas soil,air,water,surfacesofobjectsandourskins,etc.Thenumberofbacteriumisenormous,withmanydiffer entspecies.Theyhavethreatenedthehealthofhuman beingsseriously.Withthedevelopmentofeconomyand environme…     

Specification methods for material-handling control algorithms in flexible manufacturing systems

Good methods are needed to specify, test, and debug material-handling control logic. This article surveys a number of representative methods for defining and describing control algorithms for programmable material-handling equipment used in flexible manufacturing systems. The methods are evaluated with regard to their suitability for communication between people and as bases for interfaces to automatic program generators. It is concluded that no single method is entirely satisfactory. Three methods (position diagrams, function block diagrams, and operation networks) have potential to be combined into an effective hybrid approach that minimizes the need for the user to switch between various conceptual models.     

Electrocatalysis of chlorine evolution on different materials and its influence on the performance of an electrochemical reactor for indirect oxidation of pollutants

Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co₃O₄ were investigated for their electrocatalytic properties versus Cl₂ evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl₂/Cl⁻ couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co₃O₄ anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m⁻³ proved the process more economic than the homogeneous phase oxidation.     

Al/Fe2O3反应合成材料热力学

运用CALPHAD技术，基于多组元多相复杂平衡体系的吉布斯自由能最小化原理，用大型集成数据库F^*A^*C^*T系统，考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术，计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况；分析了原料初始温度、配料比和SiO2含量对绝热温度和平衡组成的影响。     

未增塑聚氯乙烯(PVC-U)异型材配方基础

PVC-U异型材配方十分复杂,常用原料通常在10种以上。根据大连实德集团实际生产情况,这10多种原料通常以7大组分的方式进行配料和生产。文中就该配方中7大组分的分类、特点及应用情况分别进行了详细介绍。     

土工合成材料在辽宁省水利工程中应用效益分析

截止2003年辽宁省水利工程中应用土工合成材料已达1450万多m^2，尤其在河道护岸、堤(坝)护坡、防渗工程上这种新型工程材料得到了广泛应用。结合辽宁省水利工程上应用的实际，对其效益进行了分析，分析结果表明：采用土工织物软体排护岸比传统柴排护岸节省投资35％～80％；堤坝护坡采用土工织物滤层比传统砂砾料滤层节省投资30％以上；土工膜防渗可比粘土防渗节省投资30％～50％。同时还取得了保护生态平衡、节省能源、促进化纤工业发展等十分显的社会效益。