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31.
32.
交联型聚醚聚氨酯的表征、力学性能及其碱金属盐络合物的导电性能 总被引:1,自引:0,他引:1
采用三羟甲基丙烷(TMP)作交联剂与聚乙二醇(PEO-1540)和甲苯二异氰酸酯(TDI)反应,得到了具有较好力学性能的交联型聚醚聚氨酯(PEU),该聚合物与LiClO4的结合物具有较高的室温电导率(σ30℃=1.87×10 ̄(-4)S/cm)。采用全反射红外光谱(ATR-IR)对聚合物的结构进行了表征。对聚合物的组成、不同TDI类型及络合盐浓度对聚合物力学性能及其络合物电导率的影响进行了探讨。低度交联聚合物的络合物,其电导率与温度的关系符合建立在自由体积理论上的VTF方程,表明络合物中离子的传导主要是在无定形区域进行,与自由体积有关。 相似文献
33.
A. Palmeri F. Ricciardelli G. Muscolino A. De Luca 《Canadian Metallurgical Quarterly》2004,130(9):1052-1061
The equation of motion of linear dynamic systems with viscoelastic memory is usually expressed in a integrodifferential form, and its numerical solution is computationally heavy. In two recent papers, the writers suggested that the system memory be accounted for through the introduction of a number of additional internal variables. Following this approach, the motion of the system is governed by a set of first-order, linear differential equations, whose solution is quite easy. In this paper, the approach is extended to single-degree-of-freedom systems subjected to random, nonstationary excitation. The equations governing the time variation of the second-order statistics are derived, and an effective step-by-step solution procedure is proposed. Numerical example shows the accuracy of the procedure for white and nonwhite excitations. 相似文献
34.
Food products can be high‐pressure processed (HPP) either in bulk or prepackaged in flexible or semi‐rigid packaging materials. In the latter case the packaging material is subjected, together with the food, to high‐pressure treatment. A number of studies have been performed to quantify the effects of high‐pressure processing on the physical and barrier properties of the packaging material, since the integrity of the package during and after processing is of paramount importance to the safety and quality of the food product. This article reviews the results of published research concerning the effect of HPP on packaging materials. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
35.
Ioannis Arvanitoyannis John M. V. Blanshard Ioannis Kolokuris 《Polymer International》1992,27(1):7-15
Mastication of gutta percha (trans-polyisoprene) resulted in the selective scission of molecules, producing a narrower distribution of lower molecular weights. The mechanical properties of the samples also underwent a significant change due to mastication. The greater the content of incompatible substances (salts and oxides) in commercial gutta percha. the more substantial were these effects. The atmosphere (air, N2, O2) in which the experiments were conducted yielded significantly different results. The decrease in molecular weight was far greater in an O2 atmosphere than under a current of nitrogen or air, owing to the combination of double bonds with O2. 相似文献
36.
求解机械装配规划的新方法 总被引:6,自引:0,他引:6
本文提出一个求解机械装配规划的算法,其计算量~O(sN~2),其中s是零件所有可能装配方向的个数,N是工件的零件数(一般s~O(N)).而现行的求机械装配规划的算法,其计算量均随N的增加按指数律增加. 相似文献
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该文介绍一种简单、可靠、小巧的转速传感器。它的特点是在强振环境下仍具有很高的可靠,可用于坦克底盘、重型工程机械,燃气轮机组等机械作为转速监测。 相似文献
40.
Plastisols, which are a blend of poly(vinyl chloride) resin and a plasticizer (DEHP), were used as a toughening agent of a resol resin in order to improve the mechanical properties. It was not possible to formulate resol blends by adding more than 10 % of plastisol owing to a lack of apparent homogeneity in the systems, which also showed many air bubbles. The relationship between dynamic mechanical, mechanical and thermal properties and the amount of plastisol added was studied. It was determined from the infrared spectroscopy and dynamic mechanical results that the resol–plastisol blends seem to be formed by a reaction between the phenol and PVC giving a higher crosslinked structure. An improvement in the thermal resistance of the blends at lower temperatures was observed with an increase in the percentage of plastisol. Flexural analysis showed the elastic behaviour of the systems. However, it was not possible to observe the effect of the plasticizer (DEHP) owing to the low quantity of plastisol that was added to the resol. Copyright © 2004 Society of Chemical Industry 相似文献