Modeling the continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor

A model of continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor is developed using phase equilibria assumption and the method of molecular weight moments. The model equations can be simplified into a polynomial system that has 17 equations and 17 unknowns. Solution of the polynomial system gives out almost every aspects of the continuous transesterification process. Molecular weight and polydispersity index, end group ratio of hydroxyl to phenyl carbonate, contents of molecular species, and lost diphenyl carbonate fractions are studied in different operation parameters.     

Sicherer und wirtschaftlicher Betrieb von Kraftwerken – Ergebnis der Forschung im Bereich Werkstoffe,Auslegung und Instandhaltung

Safe and Economic Operation of Power Plants – Research Results in the Field of Materials, Design and Maintenance Components of power plants which undergo high temperatures are subjected to complex loading situations. The requirements on the used materials result from the special operation conditions of the plants and have to be adjusted to the steadily growing requirements on higher efficiency of the complete power plant as well as to those of safe and economic operation. The expenses for control and downtimes are directly connected with economic efficiency and availability. However, in case of new procedures or components it is not possible to revert to the existing know‐how. Different failure mechanisms than known before can occur. The same goes for the load situation. Therefore the knowledge base has to be extended to in‐advance or even parallely running scientific examinations that life assessment and maintenance strategies can be applied which guarantee the operational reliability and the efficiency of the plant. The main emphasis of these F&E works has to be put on condition monitoring based on actual operational data, the standard materials’ and component’s behaviour (deformation, damage and failure behaviour) in connection with design of components and the related material laws. In the framework of applied AVIF projects, following problems are handled:. – qualification of materials by determinating parameters related to practise. – optimal design of components by making available material laws and numerical tools. – economic manufacturing of components by qualifying processing methods such as welding. – The results can be transferred to concepts for safe and economic operation of power plants, especially for newly introduced materials for which there is no operational experience available.     

新型聚氨酯固-固相变储能材料的组成与热性能的关系

利用差示扫描量热仪、傅里叶红外光谱仪、广角X射线衍射仪研究了一种新型的以聚乙二醇为软段的聚氨酯相变储能材料。结果表明，当软段含量低于90％（质量分数，下同）时，即使温度高于聚乙二醇的熔点，此类材料仍不会熔化成液体，而表现出一种固-固相变行为。该聚氨酯储能材料相变焓较大，相变温度适中，且随着软段含量的减少，材料相变焓和相变温度呈递减趋势。其相变过程实质是聚氨酯软段聚乙二醇由结晶固态转变为无定形固态的过程。     

L520型智能中子仪测定农田土壤含水量的标定研究

通过对L520型智能中子仪测定农田土壤含水量的标定研究，在试验区草甸土类型的土壤中，在0～100cm的土层中得到了一条标定土壤含水量的回归直线，用此法测定土壤含水量较重量法快捷方便且误差小。     

城市RBD的成长机制与产业结构演变研究——以深圳华侨城为例

深圳华侨城是一个持续成长的休闲商务中心区的典型范例.在华侨城的成长和产业变迁过程中,休闲商务的发展具有很强的影响力.从城市边缘的华侨农场逐步发展为现代化城市中心区的RBD,华侨城演变的动力直接来源于4个方面:政策导向、市场导向、所有制导向和城市化导向.     

山岭重丘区公路工程技术方案的选择

对高填方与高架桥和深路堑与隧道两个典型技术方案，进行了费用分析，寻找方案选择的工程临界值，以提高工程设计的经济性和合理性。重点提出了工程可替代方案间填挖高判断值，对工程可行性研究阶段山岭重丘区的公路工程技术方案的选择有一定参考价值。     

Spatiotemporal aspects of jerky flow in Al–Mg alloys, in relation with the Mg content

The spatiotemporal aspects of the Portevin–Le Chatelier effect in Al–Mg alloys are investigated using direct observations of the sample surface with a digital camera. Optical measurements of the surface profile using a white light interferometer allow the estimation of the local strain and strain rate associated with the bands. The effect of Mg content on instability characteristics is analyzed. The reloading time is shown to depend on the Mg content only at the strain and strain rates where type C bands are observed.     

小城镇公共中心的规划与建设

从回首往昔、再看今朝和关注明天三个层面,分析小城镇公共中心的规划与建设中出现的一些问题,并结合工作多年的实际,提出自己对小城镇中心建设的一些想法。