氧气顶吹转炉吹炼过程动态模型

通过炉气流量和成分的在线采样信息，用积分法计算熔池排出碳量，并根据熔炼体系中碳的守恒，动态推算熔池含碳量，由此来预报吹炼终点。较深入研究了提高炉气流量检测精度的方法，如心平衡修正和钢液成分反馈修正等，并采用了滤波算法，这些措施有利于提高动态模型的精度。     

油气吸收回收系统的研究及工业应用——(Ⅱ)工业试验及效果分析

在油气吸收回收系统中型试验的基础上，开发了常温常压吸收法工业化油气回收系统，并进行了工业应用。结果表明，该油气回收系统平均回收率可达95．13％，每年可回收汽油529t；装车期间装车口周围环境大气中总烃浓度平均降低98．06％。企业通过实施油气回收系统，节能及经济效益明显，且很好地改善了装车场所的作业环境，克服了油气排放带来的安全隐患。     

Flammability characteristics at applied heat flux levels up to 200 kW/m2

This paper documents the first of the two interrelated studies that were conducted to more fundamentally understand the scalability of flame heat flux, the motivation being that it has been reported that flame heat flux back to the burning surface in bench‐scale experiments is not the same as for large‐scale fires. The key aspect was the use of real scale applied heat flux up to 200kW/m² which is well beyond that typically considered in contemporary testing. The main conclusions are that decomposition kinetics needs to be included in the study of ignition and the energy balance for steady burning is too simplistic to represent the physics occurring. An unexpected non‐linear trend is observed in the typical plotting methods currently used in fire protection engineering for ignition and mass loss flux data for several materials tested and this non‐linearity is a true material response. Using measured temperature profiles in the condensed phase shows that viewing ignition as an inert material process is inaccurate at predicting the surface temperature at higher heat fluxes. The steady burning temperature profiles appear to be invariant with applied heat flux. This possible inaccuracy was investigated by obtaining the heat of gasification via the ‘typical technique’ using the mass loss flux data and comparing it to the commonly considered ‘fundamental’ value obtained from differential scanning calorimetry measurements. This comparison suggests that the ‘typical technique’ energy balance is too simplified to represent the physics occurring for any range of applied heat flux. Observed bubbling and melting phenomena provide a possible direction of study. Copyright © 2007 John Wiley & Sons, Ltd.     

国产50%离子膜法烧碱蒸发装置及运行情况

介绍了升降膜法双效逆流蒸发生产50%离子膜法烧碱的工艺流程、主要设备、装置特点及运行情况.     

联合循环余热锅炉螺旋鳍片管烟气放热系数研究

东南大学建造了1座IGCC余热锅炉鳍片管受热面流动和传热热态试验装置,并先后在其上进行了2个不同螺旋鳍片管组的传热特性研究,通过分析比较实测的烟气侧对流放热系数与无量纲准则式计算的结果,得出了完全热模拟公式更为准确的结论。     

F2.4微孔膜的制备及在膜蒸馏过程中应用的初步研究

采用相转化法制备了F2 4的疏水微孔膜 ,并对F2 4和PVDF微孔膜的机械性能以及疏水性等方面进行了对比 .结果表明 ,F2 4微孔膜在拉伸时的应变以及断裂伸长率约为PVDF微孔膜的 6～ 9倍 ;其接触角 (77 4°)也大于PVDF膜的接触角 (6 6 7°) .尽管膜蒸馏的数据显示F2 4微孔膜的蒸馏通量尚不及PVDF膜 ,但通过调节各项制膜参数 ,F2 4可能具有良好的应用前景     

Separation of weak and strong acids by electro-electrodialysis—Experiment and theory

The experimental results of the separation of acetic acid (HA) from the sulfuric acid by the electro-electrodialysis (EED) method and the modeling of process have been presented. The Neosepta membranes CMX and ACM have been used. It has been found that the efficiency of retention of HA is high (>0.9) when the process is conducted below the limiting current density with respect to HSO₄⁻ or SO₄²⁻ anions. The observed current efficiency of the H₂SO₄ removal was rather low (CE_S = ca. 0.7, when the initial concentration of H₂SO₄ in the mixture was 1 or 2 M) which was caused by the nonideal selectivity of the anion-exchange membrane. The experimental results have been described by the model based on the extended Nernst-Planck equation and the Donnan equilibrium. Since the efficiency of the process depended mainly on the selectivity of anion-exchange membrane (ACM), the concentration of fixed charges of that membrane, , and the ratio of volume fraction of pores to their squared tortuosity, V_p/θ², have been chosen as the main fitting parameters. It has been found that the fitting of the EED data depends mainly on , whereas in the modeling of diffusion experiment (or an EED experiment conducted at low current density) both parameters are important. The best fit has been obtained for , i.e. ca. one order smaller than that determined experimentally. The obtained optimal value of V_p/θ², equal to 0.013, is consistent with those previously obtained for other Neosepta anion-exchange membrane.     

Biosorption of heavy metals by Saccharomyces cerevisiae: Effects of nutrient conditions

Studies took place to investigate the effects of different nutrient conditions on the biosorption ability and selectivity of heavy metals by Saccharomyces cerevisiae. After having grown in media supplemented with additional glucose, ammonium, phosphate or cysteine, the yeast was exposed to an equimolar solution of lead, cadmium, zinc and copper. Lead removal from a mixed solution was significantly higher than that of copper, followed by zinc and cadmium. Generally, yeasts from cysteine-rich media showed greatest sorption capacity whereas phosphate addition influenced zinc selectivity. In addition, glucose, fructose and sucrose as carbon sources were examined. Cultures grown in glucose had a better uptake than those cultivated with fructose at an incubation time of 30 min.     

膜控晶体生长及纳米微粒的形成

膜控晶体生长不同于一般在溶液中的沉淀与结晶，由膜形成的有机界面具有空间定位和空间约束、定域化学控制及成核过程和晶体生长的立体化学专一的特性，使得晶体的结构、形状和尺寸上得到控制，并具有良好的重现性，由此可获得具有光、电以及磁特性的纳米功能材料。研究膜控晶体生长不仅可以模拟生物体系内的生物矿化作用，而且对于材料科学也有着特别重要的意义和应用前景。     

Effects of growth with ethanol on fermentation and membrane fluidity of Saccharomyces cerevisiae

Saccharomyces cerevisiae HSc was grown with ethanol at concentrations up to 10% (v/v). The immediate effects of additions of externally added ethanol on CO₂ production and O₂ consumption of washed organisms were studied by stopped-flow membrane inlet quadrupole mass spectrometry. Fermentative activities of organisms grown with ethanol (0–5% v/v) showed similar sensitivities to inhibition by ethanol, whereas those grown with 10% (v/v) ethanol had become protected and were markedly less sensitive. The fluidity of subcellular membrane fractions was measured by determination of the temperature dependence of the rotational order parameter of the spin label 5-doxyl stearic acid (free radical) by electron spin resonance. Mitochondria prepared from yeasts grown with 0, 7 and 9% (v/v) ethanol showed similar overall fluidity, although differences in temperature-dependent behaviour indicate altered lipid composition or lateral phase separations. On the other hand the microsomal fraction from organisms grown with 9% ethanol showed a remarkable increase in fluidity. These data suggest that the protective effects of growth with ethanol near the limit of tolerance on fermentative activities may arise from altered plasma membrane fluidity properties.