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21.
22.
采用溶胶-凝胶法制备具有介孔结构的降硫基质材料,选择具有降硫选择性的活性元素对合成的基质材料进行改性处理,考察不同的改性方法对制得的催化裂化原位降硫助剂性能的影响,并对基质材料和降硫助剂的结构进行表征。采用美国进口的ACE-R小型催化裂化评价装置将降硫助剂与催化裂化催化剂匹配进行性能评价,在不改变原催化裂化产品分布和产品性质的同时,降低原料的总硫含量,总硫降低可达40%以上。 相似文献
23.
Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry 相似文献
24.
It is possible to optimize the performance of the inorganic-organic composites dispersing the inorganic component in the organic matrix on a nanomiter length scale. If dry the inorganic phase cannot be intimately dispersed during the incorporation in the matrix. When the particle surface is organically modified, and the incorporation is made starting from a liquid dispersion (particles in polymer solution), the resulting composites exhibit an excellent homogeneity. Here, monolithic [poly(methyl methacrylate)/monodisperse silica particles] nanocomposites have been prepared and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic light scattering (DLS), micro-hardness, and differential scanning calorimetry (DSC). 相似文献
25.
Polyurethane acrylate anionomer (PUAA)/silica composite gels were prepared by the sol‐gel reaction of tetraethoxysilane (TEOS) and methacryloxypropyl trimethoxysilane (MPTS) incorporated to PUAA gels by using a swelling method. The formation and structure of composites were confirmed by FTIR, X‐ray diffraction, and SEM. As a result, we found that silica components in composites are located within the ionic domains of their gels and interacted with PUAA via hydrogen bonding. This drastically enhanced the mechanical properties of the composites. Mechanical properties are also improved by MPTS, because MPTS improves the dispersibility and adhesion of silica components in PUAA/silica composite gels. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2327–2334, 2002 相似文献
26.
D Ganguli 《Bulletin of Materials Science》1993,16(6):523-531
The various parameters related to sol-gel processing are discussed with special reference to those which usually attract less
attention but depending on the final product in mind, can play important roles. The versatility of the sol-gel technique in
materials preparation is demonstrated by discussing the various products developed at the author’s laboratory by using this
processing method. 相似文献
27.
Oxygen Tracer Diffusion in Vitreous Silica 总被引:2,自引:0,他引:2
Joseph D. Kalen Rethia S. Boyce James D. Cawley 《Journal of the American Ceramic Society》1991,74(1):203-209
Oxygen diffusion in vitreous silica glass is studied using the gas exchange technique. The tracer concentration profiles are consistent with a model based on two mechanisms, one network and the other interstitial. These processes are coupled through limited network–interstitial exchange. Nuclear reaction analysis and secondary ion mass spectrometry techniques are performed and compared. These results are compared to experiments on transport in thin silica films grown on single-crystal silicon. 相似文献
28.
Y. Cohen K. Landskron N. Ttreault S. Fournier‐Bidoz B. Hatton G.A. Ozin 《Advanced functional materials》2005,15(4):593-602
The synthesis and characterization of a novel silicon–silica nanocomposite material are reported. A self‐assembly method allows the encapsulation of silicon nanoclusters within the channels of a periodic mesoporous silica thin film. The result is the formation of a silicon–silica nanocomposite film with bright, room‐temperature photoluminescence in the visible range, and a nanosecond luminescence lifetime. The properties of the nanocomposite material have been studied by several analytical techniques, which collectively show the existence within the channels of non‐diamondoid‐structure‐type silicon nanoclusters with various hydrogenated silicon sites. It is estimated that the silicon nanoclusters in the silica mesoporous films occupy up to 39 % of the accessible pore volume. The nanocomposite film shows improved resistance to air oxidation compared to crystalline silicon. The high loading and chemical stability to oxidation under ambient conditions are important advantages in terms of the development of silicon‐based light‐emitting diodes from this class of materials. 相似文献
29.
Barium copper oxalate was grown in silica hydrogel at ambient temperature. The effect of various parameters like gel pH, gel
density, gel aging and concentrations of reactants on the growth of these crystals was studied. The crystals grown were characterized
by chemical analysis, X-ray powder diffractometry, infrared spectroscopy, thermogravimetric and differential thermal analysis.
The results of these observations are described and discussed. 相似文献
30.
Jose Ivan Escalante-Garcia Victor M. Palacios-Villanueva Alexander V. Gorokhovsky Guillermo Mendoza-Suárez Antonio F. Fuentes 《Journal of the American Ceramic Society》2002,85(7):1788-1792
Mortars of blast furnace slag blended with a geothermal silica waste at various replacement levels of 0%, 5%, 10%, 15%, and 20% were cured for up to 90 days. The binder was activated by 6 wt% Na2 O equivalent of sodium hydroxide. Lime was added as an activating agent and also to promote pozzolanic reaction with the silica. It was found that the presence of the silica waste increased the reactivity of the cementitious materials, as measured by means of nonevaporable water. The compressive strength was increased in the presence of the silica, except at the highest replacement level of 20%, the optimum silica replacement was that of 5%–10%. The microstructures of blended slag showed less porosity than those of neat slag mortars. The lime was completely consumed after 90 days of hydration. 相似文献