松香及其衍生物在浮选分离中的应用

介绍了松香的来源、化学组成及理化性质；讨论了松香及其衍生物在非硫化物矿浮选分离、有色金属离子的浮选分离以及从水溶液中浮选分离有机物等方面的应用情况。     

Schottky barrier heights of contact metals to p-type ZnSe

Schottky barrier heights (SBHs) of a variety of metals (In, Cd, Nb, Ti, W, Cu, Ag, Au, Ni, Pt, and Se) contacting to p-ZnSe grown by a molecular beam epitaxy method were determined by analyzing capacitance-voltage (C-V) and/or current density-voltage (J-V) curves. The SBH values of the Au and Ni contacts were determined from intersections of straight lines of the C⁻²-V curves to be 1.23 and 1.13 eV, respectively. The J-V calculations provided a large SBH value of 1.2 ± 0.1 eV for a variety of metals, indicating that the Fermi-level could be pinned at the contact interface. Reduction of the SBH values to a level lower than 0.4 eV and/or increase of doping concentrations to a level higher than 10²⁰ cm⁻³ are essential to obtain an ohmic contact with contact resistivity of around 10⁻³ Ω·cm².     

Effects of crack size and weld metal mismatch on the has cleavage toughness of wide plates

The heat affect zone (HAZ) is in many cases considered to be the most critical part of a weldment. In this paper, the effect of crack size and weld metal mismatch on the HAZ cleavage toughness of wide plate specimens with X-groove has been investigated by the J-Q-M theories and a simple micromechanism for cleavage fracture. Two crack sizes have been studied (a/w = 0.1 and 0.3). In the analyses, the HAZ yield strength is assumed to be higher than the base metal. For each crack size, weld metal local overmatch and local evenmatch with respect to the HAZ are considered. For a given global strain, the results indicate that weld metal overmatch and evenmatch yield the same crack tip loading in terms of J-integral for a/w = 0.3. For a/w = 0.1, overmatch gives lower crack tip loading than evenmatch. For a given crack tip loading, weld metal local evenmatch in general results in less effective crack tip loading than the overmatch. Overmatch is detrimental to HAZ toughness, but this detrimental effect becomes less significant when the crack size decreases.     

圆锥形零件冲压变形与成形载荷的分析

由于悬空侧壁部分的变形状态是圆锥形零件成形的关键，而径向拉应力是实现悬空部分成形的必要条件，同时也是该部分冲压成形成败的关键为此，经力学分析得出了侧壁部分径向拉应力的解析式和造成圆锥形零件破裂的最大径向拉应力的计算式。同时分析了圆锥形零件的成形载荷。     

Production and properties of micro‐porous glas bubble zinc and aluminium composites

Micro‐porous syntactic foams were produced by means of integration of glass bubbles into aluminium and zinc matrices. Preforms of glass bubbles were pressure infiltrated with the alloys AlSi9Cu9 ans ZnAl4Cu using squeeze casting. The preforms were sintered thermically without the use of bonding agents. Using the combination of different sintering steps syntactic foams with locally different densities could be produced. The mechanical properties of the foams were tested indicating a high compression strength of the foams and a very good compression energy absorption. Furthermore, corrosion behaviour and behaviour at higher temperatures were investigated.     

New Technology for Producing Molybdenum Wire Billets

On the basis of systematic studies of intense methods for metal forming, a production scheme has been developed, substantiated by experiment and realized for manufacturing molybdenum wire. The main stages are helical rolling of small rounded bars, vibratory drawing with induction heating of wire billets, and cold wire drawing with hydrodynamic introduction of lubricant and application to the tool of vibration in the transitional stages of the process (start-up, speed-up, slow-down, and stopping the pulling tool drive).     

光度法测定金属表面处理溶液中的磷

采用光度法直接测定金属磷酸盐处理溶液中的磷，磷量在0～50ug／50mL内符合比耳定律。此法特点快速、简便、显色稳定性好、选择性强，回收率为98．00％～102．00％。     

过渡金属对Au-Pd/TiO_2-Al_2O_3催化剂加氢脱硫性能的影响

研究了掺杂过渡金属Ru,Ni,Co对Au-Pd/TiO2-Al2O3催化剂催化噻吩加氢脱硫活性的影响,并采用X射线衍射、电感耦合等离子发射光谱、程序升温还原和程序升温脱附等方法对TiO2-Al2O3复合载体、Au-Pd/TiO2-Al2O3和Au-Pd-TM/TiO2-Al2O3(TM表示过渡金属)催化剂进行了表征。实验结果表明,掺杂过渡金属未改变Au-Pd/TiO2-Al2O3催化剂的结构;掺杂Ru或Ni增强了Au-Pd/TiO2-Al2O3催化剂的活性组分与TiO2-Al2O3复合载体的相互作用,降低了反应活化能,提高了催化剂活性组分的分散度和活性比表面积,改善了Au-Pd/TiO2-Al2O催化剂的吸附性能,从而提高了Au-Pd/TiO2-Al2O3催化剂催化噻吩加氢脱硫的活性;而掺杂Co的效果则与之相反。     

Ni|MH二次电池负极用贮氢合金的研究发展

本文详细综述了近年Ni MH二次电池负极用贮氢合金的研究发展概况。依次阐述了AB5、AB2与Ni Ni基、V Ti基固溶体合金以及Mg Ni合金的电化学性能。讨论了改善电化学性能的一些方法 ,同时给出目前一些研究成果     

云2-平1多台阶变方位水平井钻井液技术

云2-平1井是位于复杂断块油气田上的一口中曲率半径水平井,水平段长820.86 m,水平段多台阶、方位角变化幅度大(29.6°),井下摩阻大,钻井液的携砂、润滑及防卡能力是该井钻井成功的关键。该井选用有机正电胶-聚合物钻井液体系,用高分子量聚合物胶液进行维护,以提高体系的悬浮携岩及防塌能力,通过加入液体磺化沥青、原油及与之相配伍的固体乳化剂来提高润滑性,配合良好的四级固控设备及时清除有害固相,使钻井液性能稳定且易于调整,增强了泥饼的韧度和强度,完全达到了充分悬浮携带岩屑、润滑防卡、稳定井壁的要求。在钻进过程中仔细观察钻井液的动切力、动塑比、静切力初终值、固相含量、含油量、膨润土含量等性能参数的变化,“细化、超前、配套”是该井钻井液性能稳定、效果良好的主要维护处理经验。下套管、钻杆输送测井顺利,井下摩阻始终小于10 kN,全井安全无事故,仅用45d8 h钻完3200 m的进尺。