Thermodynamic state of reinforced interpenetrating polymer networks

The free energies of mixing of two networks in the interpenetrating polymer network based on crosslinked polyurethane and poly(ester acrylate) have been determined by the vapour sorption method. It was established that the constituent networks in the IPN are not miscible. The introduction of fillers of different chemical nature increases the compatibility. The thermodynamic affinity of the fillers to the individual networks and IPN was estimated. It was established that when the free energy of interaction of one or both components of the IPN with the filler is negative, reinforcement leads to the formation of a compatible and equilibrium system. For fillers having no affinity to the polymers, compatibilization is observed, which is connected with slowing down of phase separation in the system in the presence of filler.     

Liquid phase epitaxial growth of pure and doped GaSb layers: morphological evolution and native defects

Undoped and Te-doped gallium antimonide (GaSb) layers have been grown on GaSb bulk substrates by the liquid phase epitaxial technique from Ga-rich and Sb-rich melts. The nucleation morphology of the grown layers has been studied as a function of growth temperature and substrate orientation. MOS structures have been fabricated on the epilayers to evaluate the native defect content in the grown layers from theC-V characteristics. Layers grown from antimony rich melts always exhibitp-type conductivity. In contrast, a type conversion fromp- ton- was observed in layers grown from gallium rich melts below 400 C. The electron mobility of undopedn-type layers grown from Ga-rich melts and tellurium doped layers grown from Sb- and Ga-rich solutions has been evaluated. Paper presented at the poster session of MRSI AGM VI. Kharagpur. 1995     

Effect of Annealing on the Surface Microstructure of Y-Ba-Cu-O Superconducting Ceramics

Precusors to the YBa₂Cu₃O_7-δ material were prepared by both the oxalate precipitation method and conventional ceramic processing. Second-phase grains were observed to develop on the exposed fracture surface during annealing at 500° to 600°C in an ambient atmosphere. The second-phase grains were identified to be BaCO₃ using EDX and XRD. The liquid phase, which was formed because of local chemical inhomogeneity in the Y-Ba-Cu-O system, contributed to the formation of second-phase grains as a source of Ba.     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

The application of microencapsulated phase‐change materials to nylon fabric using direct dual coating method

The fabrication of functional textiles able to provide thermal regulation and comfort for the body has attracted increasing interest in recent years. This research investigated fabric coatings containing energy absorbing, temperature stabilizing, phase‐change material microcapsules (PCMMcs), and their methods of application. Specifically, a coated fabric was directly prepared by a dual‐type coating method, in which the PCMMcs were dispersed in a polyurethane coating solution with no binder. The thermal performances of the dual‐coated samples were evaluated by differential scanning calorimetry, and their physical characteristics were examined by scanning electron microscopy, thermal vision camera, porosity, water vapor transmission rate (WVTR), and water entry pressure (WEP) analyses. Furthermore, the microclimate characteristics of the thermally enhanced fabrics were investigated under experimental conditions using a human‐clothing‐environment (HCE) simulator system. The study results confirmed the superior performance of the dual‐coated fabrics in terms of thermal regulation and body comfort, compared with those coated by the dry or wet coating method, because of the improved WEP, WVTR, and thermal performance. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

On the microhardness testing of electrically stressed poly(phenylene oxide): Polystyrene blends

Microhardness measurements have been performed on untreated (virgin) and electrically stressed, solvent‐cast laboratory‐prepared samples of pure poly(phenylene oxide) (PPO), pure polystyrene (PS), and PPO : PS polyblends with different weight proportions. Results of such measurement on untreated polyblend sample show that microhardness (H_v) increases with increase in the content of PS up to 10 wt %, which attributed to the existence of homogeneous phase morphology. However, this feature is not observable in samples containing higher content of PS. Electrical stress is found to modify considerably the mechanical property of polymer. The effect of electric field on the microhardness of such samples (PPO : PS :: 90 : 10) has been characterized by the existence of a peak. Trapping of charge carriers in electrically stressed samples imparts hardening to the polyblend up to an applied step field of 190 kV/cm. However, the excessive charging beyond this step field value destroys this characteristic. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Influence of third monomer on the crystal phase transition behavior of ethylene-tetrafluoroethylene copolymer

Crystal phase transition between the low- and high-temperature phases has been investigated for ethylene (E)-tetrafluoroethylene (TFE) alternating copolymer (ETFE) containing the third monomeric species by the temperature dependent measurements of wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) and differential scanning calorimetry. Nonafluoro-1-hexene (NFH) and hexafluoropropylene (HFP) were chosen as the third monomers, where they are different in the side-branch length, -(CF₂)₃CF₃ and -CF₃, respectively. In the case of E/TFE/NFH copolymer (ET-C4F9), the crystal phase transition temperature of the original ETFE two-components copolymer was not very much affected by the existence of NFH in the range of NFH content from 0.7 to 3 mol%. Contrarily, the crystal phase transition temperature of E/TFE/HFP copolymer (ET-CF3) was found to decrease drastically with increasing HFP content. The melting temperature and the higher-order structure were also affected sensitively depending on the HFP content. This difference in phase transition behavior between ET-C4F9 and ET-CF3 copolymers is reasonably interpreted as follows: the short side groups (-CF₃) of HFP monomeric unit are included in the crystal lattice of E/TFE chains and the unit cell is expanded gradually with an increment of the HFP content, resulting in the decrease in phase transition point because of easier thermal motion of the chains. On the other hand, the long side groups [-(CF₂)₃CF₃] of NFH monomeric units are excluded out of the crystal lattice and located on the lamellar surfaces or in the amorphous region and do not affect very much the phase transition temperature even when the NFH content is increased. In association with such a change in crystal structure, the long period of stacked lamellar structure was found to decrease remarkably in the case of NFH, whereas it does not change very much for HFP, consistent with the interpretation of the above-mentioned WAXD data.     

用穿透法测量声速时初始点的选择问题

用穿透方法测量岩心或固体的声速时，从测量波形中确定纵波（或横波）的到达时刻（或称初始点）比较困难，当声波的频率比较低时，其误差对测量结果影响比较大。本文用相位分析的方法研究了初始点的选择问题。首先，用各向同性较强、均匀的汉白玉制作标准件，测量其不同传播距离的波形，再用相位补偿的方法得到其传播速度；其次，利用传播速度，可从不同距离的测量波形中确定初始点及其对应的测量系统的时间延迟常数；最后，确定波形的其他位置为初始点时对应的时间延迟常数，因此，我们可以根据实际测量波形的特点选择最佳的初始点，利用其对应的时间延迟常数得到比较精确的声速。模型测量结果表明，初始点位置不同，其对应的测量系统的时间延迟常数也不同，也即测量系统的时间延迟常数是与初始点的选择相对应的。     

Study of Liquid Phase Shifter for ICRF on EAST

A method of current drive with Ion Cyclotron Range of Frequency （ICRF） on Experimental Advanced Superconducting Tokomak （EAST） is described. A variety of liquid silicon oil heights in the phase shifter will bring the phase difference to the current drive. It is found that the current drive can be achieved by using the phase shifter. The liquid phase shifter is one of the impedance matching systems too.     

两相管流工艺计算软件的研制

利用流体力学理论 ,结合目前国内外最新的两相流理论和实验研究成果 ,在描述气液两相流水力计算、热力计算和流型判断的数学物理模型基础上 ,研制出适用于海洋、沙漠、丘陵地区原油与伴生气、凝析天然气与凝液输送工艺的一套新的计算模拟软件TFTCS。介绍TFTCS软件的结构、功能、适用范围。用该软件对锦州 2 0 - 2海底湿天然气管道进行模拟计算 ,并与管线生产数据进行对比 ,用国外同类软件PIPEPHASE进行验算。实例计算分析表明 ,该软件功能完善 ,操作方便 ,计算结果可靠 ,能满足油气混输管道的设计计算和生产管理的需要