全文获取类型
收费全文 | 22879篇 |
免费 | 3533篇 |
国内免费 | 1646篇 |
专业分类
电工技术 | 311篇 |
综合类 | 1483篇 |
化学工业 | 2796篇 |
金属工艺 | 11691篇 |
机械仪表 | 906篇 |
建筑科学 | 434篇 |
矿业工程 | 434篇 |
能源动力 | 126篇 |
轻工业 | 1024篇 |
水利工程 | 97篇 |
石油天然气 | 262篇 |
武器工业 | 272篇 |
无线电 | 903篇 |
一般工业技术 | 4434篇 |
冶金工业 | 2712篇 |
原子能技术 | 92篇 |
自动化技术 | 81篇 |
出版年
2024年 | 151篇 |
2023年 | 628篇 |
2022年 | 1137篇 |
2021年 | 1132篇 |
2020年 | 1178篇 |
2019年 | 937篇 |
2018年 | 945篇 |
2017年 | 1103篇 |
2016年 | 1012篇 |
2015年 | 1119篇 |
2014年 | 1187篇 |
2013年 | 1277篇 |
2012年 | 1596篇 |
2011年 | 1720篇 |
2010年 | 1285篇 |
2009年 | 1375篇 |
2008年 | 975篇 |
2007年 | 1394篇 |
2006年 | 1349篇 |
2005年 | 1071篇 |
2004年 | 961篇 |
2003年 | 804篇 |
2002年 | 640篇 |
2001年 | 573篇 |
2000年 | 432篇 |
1999年 | 370篇 |
1998年 | 278篇 |
1997年 | 260篇 |
1996年 | 227篇 |
1995年 | 169篇 |
1994年 | 163篇 |
1993年 | 115篇 |
1992年 | 123篇 |
1991年 | 84篇 |
1990年 | 107篇 |
1989年 | 85篇 |
1988年 | 24篇 |
1987年 | 15篇 |
1986年 | 7篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1982年 | 13篇 |
1981年 | 2篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1959年 | 2篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Slim Salhi Jihen Mahfoudh Souhir Abid Leonard‐Ionut Atanase Marcel Popa Christelle Delaite 《Polymer International》2020,69(11):1161-1168
A series of random polyesteramides (PEAs) with a range of molar composition from 90/10 to 50/50 were synthesized by direct melt polycondensation of ε‐caprolactone and l ‐alanine. Their structure was fully characterized by Fourier transform IR and NMR spectroscopy. The resulting copolymers are completely amorphous with the exception of PEA‐90/10 which possesses a semicrystalline structure. These PEAs present increasing glass transition temperatures at increasing l ‐alanine contents and exhibit fairly good thermal stability with 10% mass loss temperatures reaching 315 °C. © 2020 Society of Industrial Chemistry 相似文献
12.
Hechun Cao Hui Zheng Lining Fan Zifeng Cheng Jianwei Zhou Qiong Wu Peng Zheng Liang Zheng Yang Zhang 《International Journal of Applied Ceramic Technology》2020,17(2):813-822
In this study, yttrium iron garnet co-doped with Zn and Zr atoms with a chemical formula Y3ZnxZrxFe(5−2x)O12 (x = 0.0-0.3) has been successfully prepared by the solid-state reaction method. The effects of doping concentration on the microstructure, crystal structure, magnetic properties, and dielectric properties of Y3ZnxZrxFe(5−2x)O12 were investigated. The microstructure analysis indicates that co-doping of YIG with Zn and Zr can effectively reduce the grain size of the ceramic. The crystal structure results reveal that the doping concentration of Zn–Zr has substantial influence on the lattice parameters of YIG, such as, increases the lattice constant, crystal cell size, and interplanar spacing. However, the second phase of ZrO2 appears once x ≥ 0.15. Additionally, the dielectric properties of YIG ferrite can be regulated using this Zn–Zr co-doping method. Zn–Zr co-doping can improve the dielectric stability and reduce the dielectric loss at high temperature. The magnetization measurement shows that the saturation magnetization is stabilized at x < 0.15, and the magnetic loss is decreased with the increase in the doping concentration. Overall, the findings show that the ceramic with x = 0.1 exhibits better properties included high saturation magnetization (24.607 emu/g), low magnetic loss (0.0025 @ 1 MHz), and relatively low dielectric loss (496 @ 400°C). 相似文献
13.
Fatigue crack growth behaviour of Ti–6Al–2Zr–1.5Mo–1.5V (VT-20 a near-α Ti alloy) was studied in lamellar, bimodal and acicular microstructural conditions. Fatigue crack growth tests at both increasing and decreasing stress intensity factor range values were performed at ambient temperature and a loading ratio of 0.3 using compact tension samples. Lamellar and acicular microstructures showed lower fatigue crack growth rates as compared to the bimodal microstructure due to the tortuous nature of cracks in the former and the cleavage of primary α in the latter. The threshold stress intensity factor range was highest for acicular microstructure. 相似文献
14.
以方竹笋中提取的膳食纤维为研究对象,采用动态高压微射流(dynamic high-pressure micro-fluidization, DHPM)在不同压力条件(0,50,100,150,200 MPa)下进行处理,探究其对竹笋膳食纤维(bamboo shoots dietary fiber, BSDF)理化和结构特性的影响。结果表明,随着处理压力的增大,BSDF粒径先增大后减小,当处理压力为150 MPa时,粒径最小,为(370±11) nm,此条件下BSDF的持水力、持油力和膨胀力达到最大,较对照组分别提高了47.74%,50.54%,61.27%,且差异显著(P<0.05)。红外光谱分析表明DHPM处理不会改变BSDF的官能团,但会使BSDF内部的部分氢键断裂和半纤维素、木质素等发生降解;X射线衍射和热重分析表明DHPM处理不会引起BSDF的晶体结构改变,但晶体有序度会下降,进而导致其热稳定性降低;微观结构分析显示DHPM处理会使BSDF颗粒尺寸减小、表面粗糙、组织松散,且当处理压力为200 MPa时,颗粒发生团聚。综上,DHPM可以有效改善BSDF的理化性质,在膳食纤维改性方面具有一定的应用价值。 相似文献
15.
16.
Feng Juanni Guo Xuefeng Xu Chunjie Zhang Zhongming 《中国稀土学报(英文版)》2006,24(1):120-120
As-east mierostruetures and their distribution of Mg-Zn-Y ternary alloy with high magnesium, low zinc and yttrium were examined using Nikon Epiphot optical microscopy (OM), RigakuD/max-3C X- ray diffraetion (XRD), and JEOL JSM-6700F scanning electron microscopy (SEM) equipped with an energydispersive X-ray spectroscopy (EDS). In the as-east mierostructures, Yttrium and zinc tend to segregate at grain boundaries, 相似文献
17.
催化裂化装置沉降器内结焦物的基本特性分析及其形成过程的探讨 总被引:5,自引:0,他引:5
采用扫描电镜(SEM)和X射线能谱分析仪对催化裂化装置(FCCU)沉降器内结焦物的微观组织结构和成分进行了分析,将结焦物划分为软焦和硬焦。焦的硬度与油气液滴和催化剂颗粒的沉积过程有关,尤其是结焦部位的油气流动方式和催化剂颗粒的运动状态,决定着未汽化的重质油组分液滴和催化剂颗粒的沉积形式和沉积物的构成,从而影响着焦的软硬程度。软焦是催化剂颗粒或油气在油气静止空间以自由沉降和扩散方式堆积在器壁表面而产生的结焦,形成的焦块松散,易粉碎,含催化剂比较多,颗粒粒径比较大,是一种堆积型结焦;而硬焦是油气液滴和细小催化剂颗粒在油气流动状态下,在器壁表面的附面层内以沉积方式粘附在器壁表面形成的结焦,焦块质地坚硬,含催化剂比较少。颗粒粒径细小,足沉积型结焦。还有相当一部分结焦物介于软焦和硬焦之间。 相似文献
18.
纳米ZrO2等离子涂层的结构,性能和工艺特点 总被引:6,自引:0,他引:6
采用大气等离子喷涂技术(APS),制备了常规氧化锆和纳米结构氧化锆两种涂层.利用扫描电镜(SEM)对涂层的显微结构进行了观察.对两种涂层的沉积效率、表面粗糙度和显微硬度作了对比研究.结果表明,粉末原料的显微结构、粒度、形态、喷涂工艺参数(喷涂功率和距离)对涂层的显微结构有较大的影响.等离子喷涂造粒纳米氧化锆粉制备的涂层沉积效率高而稳定,其显微结构与喷涂功率和距离密切相关.与常规氧化锆涂层相比,纳米结构氧化锆涂层具有较高的显微硬度和较低的表面粗糙度. 相似文献
19.
J. Gegner 《Materialwissenschaft und Werkstofftechnik》2003,34(3):290-297
Chemical Composition and Microstructure of Polymer‐Derived Glasses and Ceramics in the Si–C–O System. Part 2: Characterization of microstructure formation by means of high‐resolution transmission electron microscopy and selected area diffraction Liquid or solid silicone resins represent the economically most interesting class of organic precursors for the pyrolytic production of glass and ceramics materials on silicon basis. As dense, dimensionally stable components can be cost‐effectively achieved by admixing reactive filler powders, chemical composition and microstructure development of the polymer‐derived residues must be exactly known during thermal decomposition. Thus, in the present work, glasses and ceramics produced by pyrolysis of the model precursor polymethylsiloxane at temperatures from 525 to 1550 °C are investigated. In part 1, by means of analytical electron microscopy, the bonding state of silicon was determined on a nanometre scale and the phase separation of the metastable Si–C–O matrix into SiO2, C and SiC was proved. The in‐situ crystallization could be considerably accelerated by adding fine‐grained powder of inert fillers, such as Al2O3 or SiC, which permits effective process control. In part 2, the microstructure is characterized by high‐resolution transmission electron microscopy and selected area diffraction. Turbostratic carbon and cubic β‐SiC precipitate as crystallization products. Theses phases are embedded in an amorphous matrix. Inert fillers reduce the crystallization temperature by several hundred °C. In this case, the polymer‐derived Si–C–O material acts as a binding agent between the powder particles. Reaction layer formation does not occur. On the investigated pyrolysis conditions, no crystallization of SiO2 was observed. 相似文献
20.