RI/VI联用测定聚乙烯相对分子质量及其分布

150℃测试温度下，以1，2，4-三氯苯为溶剂，采用示差折光指数器，毛细管黏度计双检测器联用凝胶渗透色谱技术测定了聚乙烯的相对分子质量及其分布。与常规凝胶渗透色谱法对比，该方法不仅能直接得到聚乙烯较精确的相对分子质量和分布形态，同时可以得到聚乙烯的特性黏数分布。     

无油分子泵机组的组装

介绍了将ALCATEL公司生产的一台ATPl00涡轮分子泵、一台MDP50ll牵引分子泵及一台VRC公司生产的lBy6型干泵组装成无油分子泵机组的过程。文中给出了泵间配合的计算、机组方案的设计、连接管路、仪器支架的设计及选择。本机组所采取的设计方案使三个泵都最大限度地发挥了优点避免了缺陷，较好地满足了使用要求，为今后选购单泵和组装无油分子泵机组提供了可靠的理论和实验依据。     

Inhibition of radical polymerization in solvent‐based systems (security of solvent‐based radical polymerization of PSA‐acrylic in a plant reactor)

This article shows the influence of some chain‐transfer agents as inhibitors for acrylic solvent‐based polymerization. These chain‐transfer agents can offer significant advantages, as outlined below. The following chain‐transfer agents were studied to stop or slow down the polymerization process in the case of a runaway: n‐dodecyl mercaptan, trimethylolpropane‐trimercaptoacetate, phenothiazine, diphenylphenylen diamine, cuprum oxide, isopropanol, toluene, and carbon tetrachloride. Synthesized pressure‐sensitive adhesive based on acrylic polymers and containing 2‐ethylhexyl acrylate, methyl acrylate, and acrylic acid were used for the production of self‐adhesives with high cohesion. The polymerization was accomplished in ethyl acetate. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1354–1357, 2003     

卟啉类光电功能材料的研究进展

卟啉及其衍生物是一类具有优良的光电性能的有机半导体材料．引起人们广泛的关注。本文对卟啉类光电材料在模拟生物光合作用中心的光致电荷转移和能量转移，有机太阳能电池．分子光电器件。有机电致发光和光存储等领域的研究进展做一简要介绍。     

Evaluation of Atmospheric and Vacuum Residues Using Molecular Distillation and Optimization

The term atmospheric residue describes the material at the bottom of the atmospheric distillation tower having a lower boiling point limit of about 340°C; the term vacuum residue (heavy petroleum fractions) refers to the bottom of the vacuum distillation, which has an atmospheric equivalent boiling point (AEBP) above 540°C. In this work, the objective is to evaluate the behavior of different kinds of Brazilian atmospheric and vacuum residues using molecular distillation. The Falling Film Molecular Distillator was used. For the results obtained through this process, a significant range of temperature can be explored avoiding the thermal decomposition of the material. So these results are very important to the refinery decisions and improvements. The Experimental Factorial Design results showed that the temperature has more influence on the process than the feed flow rate, when a higher percentage of distillate is required.     

KOAc/NaY催化合成邻甲基苯甲醚

以KOA c/NaY为催化剂,在连续流动固定床反应器内,邻甲基苯酚(OC)与碳酸二甲酯(DMC)经过气固相催化反应合成了邻甲基苯甲醚(OM)。考察了内、外扩散对KOA c/NaY催化剂活性的影响。实验结果表明,当气流线速度大于30cm/m in时可消除外扩散对合成反应的影响;当KOA c/NaY催化剂的平均粒径在0.30~0.75mm(20~80目的颗粒)时能消除内扩散对合成反应的影响。在消除内、外扩散效应后,还考察了反应温度、原料配比、空速对合成反应的影响,得到较佳的反应条件:催化剂5mL,反应温度548K,反应压力0.6M Pa,空速0.6h-1,n(DMC)∶n(OC)=1,在线评价时间7h。在此条件下,OC的转化率高达85.7%,OM的选择性大于99%。     

微波干燥在气相超稳Y型分子筛制备中的应用研究

研究了微波干燥在气相超稳Y型分子筛制备中的应用。结果表明，分子筛经微波干燥后，其理化性质有所改善，结晶度提高，经气相超稳化反应后其产品结构及物化性质与传统电加热干燥后的气相超稳产品基本一致，说明微波干燥可替代传统干燥方式。与传统电加热干燥方式相比，微波干燥能缩短干燥时间，有效降低能耗。     

Retrograde Amnesia Induced by Drugs Acting on Different Molecular Systems.

The gamma aminobutyric acid-A (GABAA) agonist, muscimol, the glutamate N-methyl-D-aspartate (NMDA) receptor antagonist, D-2-amino-5-phosphonopentanoic acid (AP5), and the inhibitor of the extracellularly regulated kinases (ERKs), UO 126, cause retrograde amnesia when administered to the hippocampus. In the present study, the authors found that they all cause retrograde amnesia for 1-trial inhibitory avoidance, not only when infused into the dorsal CA1 region of the hippocampus, but also when infused into the basolateral amygdala or the entorhinal, parietal, and posterior cingulate cortices. The posttraining time course of the effect of each drug was, however, quite different across brain structures. Thus, in all of them, NMDA receptors and the ERK pathway are indispensable for memory consolidation, and GABAA receptor activation inhibits memory consolidation: but in each case, their influence is interwoven differently. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

超高分子量聚乙烯的辐照效应

通过密度测定和ＤＳＣ热分析，观测了超高分子量聚乙烯的辐射效应。实验结果表明：在吸收剂量０—１．１３ＭＧｙ范围内，密度随吸收剂量的增加而增大，熔化热和熔点也有所增加，特别是在低剂量范围内增加十分明显。以上结果都说明，超高分子量聚乙烯在辐照过程中，结晶在完善或有新的结晶形成     

MPID─TOF质谱的快速时间分辨微弱信号测试系统

把瞬态记录仪Ｂｉｏｍａｔｉｏｎ８ｌ００与微型计算机ＩＢＭ─ｐＣ／ＸＴ联接建成了一个高速数据采集系统，本文介绍了系统的硬件接口设计及软件设计。在超声分子束条件下，把它应用于环氧乙烷（Ｃ＿２Ｈ＿４Ｏ）的多光子电离与离解飞行时间（ＭＰＩＤ─ＴＯＦ）质谱的实验研究中，并给出了实验结果；本系统在微观基元化学反应动力学实验研究中广泛适用于对时间分辨微弱信号的探测。