多源信息融合的测井曲线分层算法研究

测井数据解释中,针对单一测井曲线无法真实反映地层属性问题,提出以多条测井曲线的滤波因子为权值,融合出一条综合特征曲线,对该特征曲线相继采用层内差异法细分层与模糊聚类校正分层,实现特征曲线的合理分层。实验结果表明:该方法避免了海量数据处理过程,剔除了噪点数据的影响,提高了分层的速度与精度,能够为应用测井资料进行岩性识别、测井相分析、储层划分等研究提供有利的技术支撑。     

一类内部点级联的PDE-ODE系统的边界控制

本文运用backstepping方法研究了一类偏微分方程与常微分方程(PDE-ODE)级联系统的能稳性.常见的级联系统在边界点x=0处级联,而本文所讨论的级联系统在内部点x0∈(0,1)处级联,级联点的改变使得新系统的控制问题更加复杂.针对新系统,首先,我们改进了backstepping方法中的常见变换,改进后的变换与常见变换相比,增加了变换中的核函数,且得到的是带有多个相容性条件的核方程组,给求解带来了困难.文中运用了一系列的技巧解出核函数,从而得到反馈控制器;其次,运用同样的方法找到改进变换的逆变换;最后,选择合适范数,利用变换的有界性证明得到闭环系统的稳定性.     

Effect of dopants on the performance of CuO–CeO2 catalysts in methanol steam reforming

Steam reforming of methanol was carried out over a series of doped CuO–CeO₂ catalysts prepared via the urea–nitrate combustion method. XRD analysis showed that at least part of the dopant cations enter the ceria lattice. The addition of various metal oxide dopants in the catalyst composition affected in a different way the catalytic performance towards H₂ production. Small amounts of oxides of Sm and Zn improved the performance of CuO–CeO₂, while further addition of these oxides caused a decrease in catalyst activity. XPS analysis of Zn- and Sm-doped catalysts showed that increase of dopant loading leads to surface segregation of the dopant and decrease of copper oxide dispersion. The addition of oxides of La, Zr, Mg, Gd, Y or Ca lowered or had no effect on catalytic activity, but led to less CO in the reaction products. Noble-metal modified catalysts had slightly higher activity, but the CO selectivity was also significantly higher.     

Simultaneous measurement of gas hold-up and mass transfer coefficient by tracer dynamic technique in “Emulsair” reactor with an emulsion-venturi distributor

Hydrodynamics and gas-liquid mass transfer have been investigated in an “Emulsair” reactor with cocurrent downflow of gas and liquid. This consists of a cylindrical tank with conical bottom topped by an emulsion-venturi as the gas-liquid distributor in which the gas is self-aspired by action of the kinetic energy of the liquid recirculation. An original tracer dynamic technique using the CO₂-N₂/water system that enables the simultaneous measurement of overall gas hold-up and overall volumetric mass transfer coefficient has been developed and validated using conventional techniques, such as volume expansion for gas hold-up and dynamic oxygenation for mass transfer. It has been shown that gas hold-up and K_La_L can be deduced from the moments of experimental response curves using a CO₂ pulse in the gas feed. Experimental results have proved that hydrodynamics and mass transfer in the Emulsair reactor are strongly influenced by the flow regime in the divergent. Two different regimes have been observed depending on the liquid recirculation flow rate: annular and homogeneous bubbling flows. In both regimes, self-aspired gas flow rate, gas hold-up and K_La_L have been reported to increase with the liquid flow rate. The operation effectiveness, estimated from the gas-to-liquid flow rate ratio, has been shown to pass through a maximum around 0.59 as a function of liquid recirculation. A comparison with the literature proved that this maximum is higher than those observed for other kinds of gas-liquid reactors equipped with a venturi. Correlations for mass transfer estimation have been derived and are in agreement with the literature.     

Enhanced Photocatalytic Hydrogen Evolution Over CaTi1−x Zr x O3 Composites Synthesized by Polymerized Complex Method

The solid solution of CaTi_1−x Zr _x O₃ (x = 0–0.15) was successfully synthesized by the polymerized complex (PC) method. This study has exhibited the advantage of the PC method to prepare a highly active CaTiO₃ compared with the conventional solid-state reaction (SSR) method. More importantly, further improvement in phase purity and large surface area was achieved by the doping of Zr⁴⁺, leading to remarkable enhancement of photocatalytic activities compared to pure CaTiO₃. The quantum yield for H₂ evolution over the most active photocatalyst, Pt (1.0 wt%)/CaTi_0.93Zr_0.07O₃, was 1.91% and 13.3% in photoreactions from pure water and aqueous ethanol solution, respectively for 0.1 g photocatalyst, which was about 3.3 and 2.5 times compared to that of PC-derived CaTiO₃.     

Synthesis and electrochemical characteristics of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials for lithium ion batteries

LiNi_1/3Co_1/3Mn_1/3O₂ cathode materials have been coated with Al₂O₃ nano-particles using sol-gel processing to improve its electrochemical properties. The X-ray diffraction (XRD) pattern of the as-prepared Al₂O₃ nano-particles was indexed to the cubic structure of the γ-Al₂O₃ phase and had an average size of ∼4 nm. The XRD showed that the structure of LiNi_1/3Co_1/3Mn_1/3O₂ was not affected by the Al₂O₃ coating. However, the Al₂O₃ coatings on LiNi_1/3Co_1/3Mn_1/3O₂ improved the cyclic life performance and rate capability without decreasing its initial discharge capacity. These electrochemical properties were also compared with those of LiAlO₂-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathode material. The electrochemical impedance spectroscopy (EIS) was studied to understand the enhanced electrochemical properties of the Al₂O₃-coated LiNi_1/3Co_1/3Mn_1/3O₂ compared to uncoated LiNi_1/3Co_1/3Mn_1/3O₂.     

解析三角截柱法储量计算

通过对勘探工程中相邻最近三工程控制的矿块即三角截柱体的空间解析计算，进而对整个矿区进行高精度的储量计算，可以得到比传统方法更高的计算精度，并使储量计算走上微机化的道路。     

基于改进遗传算法的星地任务优化调度研究

星地任务优化调度是利用特定的星地资源合理地安排星地任务。由于星地任务众多而资源有限,而且星地任务受星地可见性以及多方面约束,星地任务调度问题十分复杂。针对星地任务的特点,建立了星地任务调度问题模型,提出了基于改进遗传算法的星地任务优化调度算法。算法采用按适应度排名轮盘赌选择、顺序交叉、随机对换变异的算法要素。针对遗传算法局部搜索能力弱的特点,提出了利用爬山算法优化新一代个体的方法,以增强遗传算法的局部搜索能力,给出了基于改进遗传算法的星地任务调度算法。     

基于ANSYS有限元法的电导率传感器分析

提出了一种结构简单的新型非接触电导率传感器。从原理出发,采用ANSYS有限元方法,通过建立有限元模型、定义材料属性、网格划分、设置边界条件、加载和求解等,得到了溶液电导率分别与传感器电感和电容之间的关系。利用该传感器对几种已知电导率溶液进行了测试,结果显示其测量的最大相对误差为0.64%,从而证明所提出的传感器测量方法不仅测量精度可行,还提高了测量的冗余度和可靠性,具有很高的商业应用价值。     

基于无线疲劳监测系统的铝合金材料疲劳损伤研究

铝合金材料具有重量轻、强度高等特点,是国民经济发展的重要基础材料,在诸多领域(如飞行器设计与制造、建筑装饰等)中占有十分重要的地位。然而,其抗疲劳性能较差,在交变荷载作用下容易产生疲劳裂纹和发生疲劳破坏。提出了一种基于无线疲劳监测系统的铝合金材料疲劳损伤研究方法,实时监测了铝合金构件的疲劳应变,并实时分析了构件的疲劳损伤状况,为研究铝合金材料的疲劳性能提供了可借鉴性的方法。