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11.
12.
再谈高速走丝线切割机断丝原因的分析及对策 总被引:3,自引:0,他引:3
针对高速走丝电火花线切割加工的断丝问题,从各个方面补充分析了线切割加工中的断丝原因及解决方法,这些方法能切实有效地减少断丝的发生。 相似文献
13.
A set of Co promoted 10% Mo/Al2O3 samples have been characterized by means of Raman spectroscopy under ambient as well as in situ dehydrated conditions. Under ambient conditions, the degree of the polymerization of surface molybdenum oxide species decreases with increasing Co loading. Under dehydrated conditions, the polymeric molybdenum oxide species is absent with the addition of only 0.2% Co. At low Co loadings (2%), before the formation of CoMoO4 compound, the spectral features are very similar under ambient conditions. Dehydration causes the upward shift of the Mo=O symmetric stretching mode. A broad band around 920–930 cm–1 was thus observed. This band has been suggested to be associated with the Co-Mo interaction species. In contrast to crystalline CoMoO4, this species shows a reversibility on H2 reduction-O2 reoxidation treatments. From the results obtained, it is proposed that cobalt oxide interacts with the most polymerized molybdenum oxide species to form Co-Mo interaction species and/or crystalline CoMoO4; therefore, the amount of the surface molybdenum oxide species decreases with a change in the molecular structure as a function of the Co concentration. 相似文献
14.
The effect of Mo loading, calcination temperature, reaction temperature and space velocity on the catalytic performance of methane dehydrogenation and aromatization without using oxidants over Mo/HZSM-5 has been studied. The XRD and BET measurements show that Mo species are highly dispersed in the channels of the HZSM-5 zeolite, resulting from the interaction between the Mo species and the zeolite, which also leads to a decrease in its crystallinity. The Brønsted acidity, the channel structure and the state and location of Mo species in the zeolite seem to be crucial factors for its catalytic performance. It was found that 2% Mo/HZSM-5 calcined at 773 K showed the best aromatization activity among the tested catalysts, the methane conversion being 9% at 1013 K with the selectivity to aromatics higher than 90%. The experimental results obtained from the variation of space velocity gave evidence that ethylene is an initial product. On the basis of these results a possible mechanism for methane dehydrogenation and aromatization has been proposed in which both the heterolytic splitting of methane in a solid acid environment and a molybdenum carbene-like complex as an intermediate are of significance. 相似文献
15.
Arun K. Bhattacharya John J. Petrovic 《Journal of the American Ceramic Society》1991,74(10):2700-2703
The indentation technique has been used to evaluate the hardness and fracture toughness of SiC-reinforced MoSi2 composites made by hot-pressing. It is seen that the toughness increases with increasing indentation crack length (under increasing load) and a probable mechanism responsible for this behavior is described. It is also observed that there is an optimum volume fraction of SiC particles for which the maximum fracture toughness of the composite can be achieved. 相似文献
16.
17.
Jose E. Herrera Ja Hun Kwak Jian Zhi Hu Yong Wang Charles H. F. Peden 《Topics in Catalysis》2006,39(3-4):245-255
The advantages of the atomic layer deposition (ALD) method for preparation of tungsten, vanadium, titanium, and molybdenum
oxide catalyst supported on mesoporous silica are discussed, with emphasis on the importance of synthesis conditions on dispersion,
structure and activity of the resulting materials. A suite of complementary techniques such as DRS-UV/Vis, BET, 1H-NMR, XRD, and TEM were used to study the structural properties of the supported metal oxides, and probe reactions such as
2-butanol dehydration and ethanol partial oxidation were used to demonstrate the potential advantages of the ALD-prepared
catalysts. Specifically, highly dispersed oxides of titanium, molybdenum, and tungsten oxide on mesoporous silica were synthesized
using the ALD method. It is also demonstrated that attainment of high dispersions of vanadium oxide on mesoporous silica requires
the presence of at least a single layer of titanium oxide due to the well-known poor interaction between vanadia and silica.
The highly dispersed catalysts prepared here by ALD methods exhibited superior catalytic performance relative to those prepared
using conventional incipient wetness impregnation. 相似文献
18.
A composite catalyst Nafion-Pt-HxMoO3 was prepared on a glassy carbon by cyclic voltammetry methods in sulfuric acid solution containing Na2MoO4, H2PtCl6 and Naton, and its activity for the methanol oxidation was studied with Pt-HxMoO3 as comparison. It is found that the electrocatalytic activity and the stability of Pt-HxMoO3 are improved by the Nation. The activity of Pt-HxMoO3 reaches its maximum when the content of Nation in the preparation solution is 0.012%(mass fraction). In this case the oxidation peak current of methanol on Nation-Pt-HxMoO3 is 1.76 times larger than that on Pt-HxMoO3 and keeps unchanged when the potential is set at 0.3 V (vs Hg-Hg2SO4) for 5 000 s in 1 mol/LCH3OH+0.5 mol/L U2SO4 solution. The results from energy dispersive spectroscopy show that the content of Nation in the composite is 0.57%. The results from scanning electron spectroscopy show that the composite of Nafion-Pt-HxMoO has a gain size of about 90 nm and distributes more uniformly than Pt-HxMoO3. 相似文献
19.
介绍了2006年上半年国际、国内钼市场的产量、供需平衡及进出口情况。西方世界钼产量平稳,钼价格呈现出上涨趋势。西方世界钼铁平均价格1月份为53.5~55.8美元/kg,6月份为58.71~60.07美元/kg,上涨9.72%;中国产钼铁在鹿特丹仓库现货价格1月份为50.99~53.70美元/kg,6月份为58.51~60.03美元/kg,上涨14.74%。分析了上半年国际、国内钼市场的形势,预测下半年国际钼市场钼精矿供应仍将紧张,副产钼供应平缓,因此下半年的钼市场将得到支撑。 相似文献
20.
利用双层辉光放电形成Mo-N硬质镀层 总被引:4,自引:0,他引:4
用双层辉光放电在钛合金Ti6Al4V表面形成了Mo-N硬质镀层。用X射线衍射仪和纳米压入仪分别对镀层的相结构、硬度和弹性模量进行了研究,并用涂层压入仪对镀层与基体间的结合强度进行了测定。结果表明:Ti6Al4V表面形成了均匀的Mo—N硬质镀层,镀层厚约10μm,由面心立方结构Mo2N化合物构成;Mo2N硬质镀层的硬度和弹性模量分别为13.80GPa和261.65GPa;镀层与基体间具有较好的结合强度。 相似文献