纳米级均分散氧化钕胶体粒子的制备

运用“交替淬冷快热”法，成功地制备了氧化钕的纳米级均分散胶体粒子，颗粒分散性好，呈规则球形，最小粒径为３５ｎｍ，纯度９９９％，详细讨论了“交替淬冷快热”法提出的基本原理，运用ＤＴＡ／ＴＧ的分析结果，确定了产物的煅烧温度及热分解机理，并用ＸＲａｙ衍射对各种温度处理的粉末样品进行了观测和分析。     

均分散超微氧化铜粒子的研制

研究了制备氧化铜均分散的超微粒子的条件,发现pH、阴离子、温度等均与此有关。用不同方法研究了粒子形成过程及内在的化学机理。在实验室条件下,制备出各种形状、大小的氧化铜粒子,从中得到一些规律。     

Synthesis of transparent oil dispersion of monodispersed calcium carbonate nanoparticles with high concentration

The preparation of monodispersed inorganic nanoparticles is of great interest for many applications. In this article, transparent oil dispersion of monodispersed amorphous CaCO₃ nanoparticles with high concentration and long‐term stability were controllably prepared by a reverse microemulsion method. The effects of the addition amount of extra minute water and (NH₄)₂CO₃ as novel assistant promoter, reaction temperature, Ca(OH)₂/CaO mole ratio were explored. The optimum synthesis conditions were achieved. The as‐prepared transparent oil nanodispersion had a good monodispersity, a uniform particle size of 8–10 nm, a high stability of over 12 months, a high solid content of 38 wt% (Ca content of about 15.5 wt%) and a high total base number of 416 mgKOH/g. The preparation process was further investigated by polarized optical microscope and Fourier transform infrared. This nanodispersion will find a promising applicability as an excellent nanodetergent in the fields of automobile and marine lubricants. © 2017 American Institute of Chemical Engineers AIChE J, 63: 3663–3669, 2017     

一种尺寸均匀的金纳米粒子制备及表征

以氯金酸为原料,葡萄糖为还原剂,柠檬酸钠为保护剂,在一定温度条件下成功制备出金纳米粒子,并用透射电镜和紫外-可见分光光度计对实验样品进行了表征,结果表明,此类纳米金粒子尺寸均匀,呈球形单分散分布,发现葡萄糖和柠檬酸钠对粒子尺寸影响较小,性质稳定,具有较高的应用价值。     

单分散Co/SiO2催化剂的制备及其F-T合成性能

以Co(NO₃)₂·6H₂O和Co(NO₃)₂·7C₆H₁₃OH为前驱体,采用热分解法制得Co/SiO₂催化剂,通过BET、TEM、HRTEM、XPS和TPR等手段进行表征,并对F-T合成反应性能进行了评价。结果表明,浸渍法制备的Co₃O₄颗粒团聚严重,而热分解法制备的Co₃O₄颗粒呈球形,单分散状态。与浸渍法制备的催化剂相比,热分解法制备的催化剂孔容较小,表面钴硅原子比较高,钴硅相互作用较强。评价结果表明,热分解法制备的催化剂反应活性低于浸渍法制备的催化剂,但汽油（C₅～C₁₁）选择性高,且选择性在前驱体去结晶水后有所增大.     

单分散大粒径硅溶胶的制备

采用单质硅粉水解法,经过初级粒子制备和粒子多级生长,制备了单分散的大粒径硅溶胶,考察了反应温度、反应时间、硅粉添加量、氢氧化钠浓度等因素对粒径及PDI的影响.最优实验条件为:反应温度70℃、反应时间12h、硅粉添加量21 g、氢氧化钠浓度0.5wt％.最优条件下的硅溶胶粒径为20 nm,通过粒径的多次生长,制备出粒径为90 nm的硅溶胶,且呈单分散性.     

Effects of calcination atmosphere on monodispersed spherical particles for highly optical transparent yttria ceramics

Highly sinterable powders are required for the fabrication of transparent ceramics. Here, we studied the effects of calcination atmosphere on the characteristics of monodispersed spherical Y₂O₃ powders, such as crystallite size and particle density, for high optical transparent ceramics. It was found that vacuum calcination around the crystallization temperature is the crucial step to eliminate intragranular pores in the spherical particle. The fast decomposition rate in a vacuum creates smaller crystallites, and the following higher calcination temperature results in the enhancement of pore elimination. The in‐line transmittance of the transparent Y₂O₃ ceramics, vacuum sintered at 1750°C, was improved by increasing the particle density of the as‐calcined powders. This result indicates that the high‐density starting particles effectively enhance the pore elimination during the fabrication of transparent Y₂O₃ ceramics.     

聚合物/SiO2核壳结构单分散微球的制备

聚合物/SiO2核壳结构单分散微球比聚合物微球具有更好的稳定性,有望在较高的温度和有机溶剂中得到使用.为了制备出这种微球,作为模板的聚合物微球首先进行表面胺化处理,然后正硅酸乙酯被诱导在其表层水解缩合从而形成SiO2壳层;采用扫描电子显微镜(SEM)、傅里叶红外光谱仪(FTIR)、激光粒度仪,烧蚀质量损失等手段分析表征...     

Facile Preparation and Formation Mechanism of Uniform Silver Nanoparticles Using OP-10 as Emulsifier in Reverse Microemulsion

Using the polymerizable hydrophobic styrene monomer as the dispersion medium and the traditional nonionic surfactant OP-10 as emulsifier, stable silver nanoparticles of narrow size distribution were prepared by a reverse (w/o) microemulsion method. The powder X-ray diffraction (XRD) pattern indicated that the obtained silver nanoparticles were of face-centered cubic structure. The results of the transmission electron microscopy (TEM) show that the final silver nanoparticles are of spherical structure with a...