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921.
922.
采用等离子喷涂方法在LY12铝上制备了Ta/W/Sn复合涂层。研究了各种工艺参数对涂层材料熔化程度和沉积效率的影响。采用扫描电子显微镜观察了复合涂层的表面及界面,精密机械天平称量涂层的增重,力学拉伸机测量涂层的抗拉结合强度,能谱和化学方法分析涂层的化学成分。结果表明,等离子喷涂工艺可以制作组织致密,厚度均匀的Ta/W/Sn复合涂层;喷涂功率和送粉速率对材料的熔化状态影响较大,在特定喷距范围内喷距的影响则较小。 相似文献
923.
钛合金表面激光熔覆原位生成TiC增强复合涂层 总被引:31,自引:2,他引:31
利用Cr3C2和TiC生成自由能和稳定性的差异,通过激光熔化法在Ti6Al4V表面制备TiC颗粒增强钛基复合材料涂层,结果表明:选择合适的激光处理工艺,可使Cr3C2和Ti合金粉末通过原位结晶置换反应生成TiC/Ti复合材料熔覆层。亚微米级的TiC颗粒均匀地分布于复合材料的基体中,复合材料的基体组织随合金粉末的成分不同而改变。 相似文献
924.
Novel thermal barrier coatings that are resistant to high-temperature attack by glassy deposits 总被引:2,自引:0,他引:2
Aysegul Aygun Alexander L. Vasiliev Nitin P. Padture Xinqing Ma 《Acta Materialia》2007,55(20):6734-6745
Airborne sand particles that deposit on thermal barrier coatings (TBCs) in gas-turbine engines melt and form calcium–magnesium–aluminosilicate (CMAS) glass, which attacks the TBCs. A new approach for mitigating CMAS attack on TBCs is presented, where up to 20 mol.% Al2O3 and 5 mol.% TiO2 in the form of a solid solution is incorporated into Y2O3-stabilized ZrO2 (YSZ) TBCs. The fabrication of such TBCs with engineered chemistries is made possible by the solution-precursor plasma spray (SPPS) process, which is uniquely suited for depositing coatings of metastable ceramics with extended solid-solubilities. Here, the TBC serves as a reservoir of Al and Ti solutes, which are incorporated into the molten CMAS glass that is in contact with the TBC. This results in the crystallization of the CMAS glass and the attendant arrest of the penetrating CMAS front. This approach could also be used to mitigate attack by other types of foreign deposits (salt, ash, and contaminants) on TBCs. 相似文献
925.
926.
A vacuum impregnation procedure for examining the microstructure of thermal spray coatings has been evaluated using a low-viscosity
fluorescent resin. The use of confocal laser scanning microscopy for examining the microstructure allows three-dimensional
image reconstruction of the sample. Relationships between defects (i.e., porosity or micro/macrocracking) and coating properties
can be established more accurately with the proposed methodology because it enables quantitative analysis. 相似文献
927.
M. Tamura M. Takahashi J. Ishii K. Suzuki M. Sato K. Shimomura 《Journal of Thermal Spray Technology》1999,8(1):68-72
Multilayered thermal barrier coatings (TBC) with different functions were proposed for the hot section components of land-based
gas turbines. This article describes a multilayered TBC with an oxidation resistant layer. A conventional duplex TBC and a
triplex TBC, in which an aluminized layer was added to the conventional duplex TBC to increase oxidation resistance, were
prepared. It was confirmed by a burner rig test that the triplex TBC with the aluminized layer is resistant to oxidation and
shows high durability in a thermal cycle test, compared with the conventional duplex TBC. The spalling in the thermal cycle
test of each TBC specimen occurred at the same position, when the thickness of the oxidation layer was 11 to 13 μm. The mechanism
of spalling of the coating in the thermal cycle test was discussed in terms of stress in the coating. Stress in the direction
of spalling occurred by an uneven interface between the bond and top coat and increased with growth of the oxidation layer.
It is thought that the high durability of the triplex TBC in the thermal cycle test is derived from suppressing the growth
of the oxidation layer and decreasing the stress due to the addition of the aluminized layer. 相似文献
928.
紫外光对涂层的老化作用 总被引:19,自引:0,他引:19
用人工加速的方法研究了紫外光对涂层的影响.用石英晶体微天平(QCM)测试发现老化后涂层对H2O和SO2的吸附率明显增大.电化学阻抗(EIS)测定发现孔隙率随光照射时间增加而增大,涂层电阻随光照时间增加而减小.傅利叶变换红外光谱(FTIR)分析表明,光照使涂层分子碳链断裂,醇酸涂层发生在芳香酯的C—O键,聚氨酯涂层发生在芳香酯的C—O键和氨酯键C—N,同时有一些亲水基团生成.用扫描电子显微镜(SEM)观察涂层表面产生了许多孔穴.涂层吸水率增加是由亲水基团增加和孔隙增加共同引起的,但孔隙增加的贡献更大.而涂层对SO2吸附率的增加是由双键α—H过氧化物的增加和孔隙的增加共同引起的,α—H过氧化物的增加的贡献更大。 相似文献
929.
930.
The ultimate methods for solving the contamination of Cr6+ is to replace the Cr electroplating with other techniques, thermal spray provides one of the best choices among those alternative techniques. The influence of coatings upon the fatigue performance of substrate, however,should be labeled as an important factor at some high level applications. The effects of both coatings manufactured by HVOF and Cr electroplating respectively on the fatigue performance of substrate are investigated in this article. These results show that the fatigue limit strength at P= 50 ,of thermal spray coating is 750 MPa in comparing with fatigue limit 726 MPa for substrate, and the fatigue life increase 25,- 150, when comparing with fatigue life of substrate at different stress levels. The fatigue life increases in the stress scope of 750-850 MPa even the area of thermal spray coating is subtracted. Cr eleetroplating coating reduces the fatigue life by 70,- 95, and the fatigue limit is only 600 MPa. Fracture analysis reveals that the main fracture is initiated at the subsurface, which is 0.2-0.5 mm away from substrate surface. The analysis also observes that the crack in the Cr electroplating propagates through the interface and finally into the substrate which hastens the formation of crack origin and the extension of crack in the substrate, however, the crack in the thermal spray coating deflects at the interface, spreads along the interface, as a result,the crack forming in the coatings has no negative influence on the main crack initiator and crack extension in the substrate. 相似文献