三门峡大坝温度观测资料分析

三门峡水利枢纽大坝为混凝土重力坝,原设计选择其溢流坝和安装场坝为重点观测坝段,因此,在施工中埋设了各种观测仪器1000多支。经对1958～1988年气温、坝体混凝土温度、基岩温度及水库水温观测资料分析表明:三门峡大坝温度变化规律虽与一般重力坝不同,但它却比较全面地反映了防洪与径流发电具体运用的特性。     

动态光散射法研究海藻酸钠凝胶松弛行为

在前文的基础上，用相关函数轮廓分析的方法剖析了运动模型模式的复杂性。通过海藻酸钠水溶液在０．１ｍｏｌ／ＬＣａＣｌ２水溶液透析凝胶化过程中交联网络的松弛时间谱表明它不是单一的峰，有两上特征运动模式，并随透析向更慢的运动模式发展，这很慢的运动模式估计与区域的结构的生成有关。     

Residue curve maps for reactive distillation systems with liquid-phase splitting

A model has been developed to study the effects of chemical kinetics on the residue curve maps (RCM) for reactive distillation systems with liquid phase splitting. In the model, chemical reaction can occur in both or only one of the two liquid phases. The heating policy V/V₀=H/H₀ is applied so that the kinetic effect can be described by a single parameter, the Damköhler number Da. The effects of reaction kinetics on pseudohomogeneous and heterogeneous mixtures have been compared. The properties of their RCMs are the same outside, but are fully different inside the liquid-liquid (L-L) region if they have different chemical equilibrium curves. Inside the L-L region, the chemical equilibrium curve coincides to a unique reactive liquid-liquid tie line in case that the pseudohomogeneous chemical equilibrium curve intersects with the L-L envelope. When the reaction occurs in only one of the two liquid phases, the residue curves inside the L-L region are strongly affected by the L-L envelope, especially at high Da. In the present paper, first an illustrative arbitrary reaction system, and then the reaction of cyclohexene with water to cyclohexanol are analysed with respect to their RCMs.     

In situ polyurethane/silica composite formation via a sol‐gel process

Polyurethane acrylate anionomer (PUAA)/silica composite gels were prepared by the sol‐gel reaction of tetraethoxysilane (TEOS) and methacryloxypropyl trimethoxysilane (MPTS) incorporated to PUAA gels by using a swelling method. The formation and structure of composites were confirmed by FTIR, X‐ray diffraction, and SEM. As a result, we found that silica components in composites are located within the ionic domains of their gels and interacted with PUAA via hydrogen bonding. This drastically enhanced the mechanical properties of the composites. Mechanical properties are also improved by MPTS, because MPTS improves the dispersibility and adhesion of silica components in PUAA/silica composite gels. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2327–2334, 2002     

成藏流体历史分析——以黄骅坳陷三马地区为例

应用储集层岩石烃类流体包裹体研究方法，对黄骅坳陷三马地区沙一段油藏进行了重建成藏流体历史的尝试。对包体流体状态的分析表明，成藏流体具有高密度，高矿化度的性质，被捕获时的温度约为110－140℃，成藏流体的主要充注时期在明化镇组沉积期，距今为10－4Ma之前，充注成藏后的小幅度构造抬升中可能使原称油水界面以下的地层水矿化度发生变化，导致现今储集层流体矿化矿比包裹体流体矿化度明显下降。图5表2参6（钟宁宁摘）。     

Formation and investigation of epoxy intumescent compositions modified by active additives

Results are reported of research on intumescent composites based on epoxy resin cross‐linked with polyethylene polyamine and containing ammonium polyphosphate and such modifying additives as calcium borate, manganese dioxide, nickel, and chromium, containing tubulenes as gas‐formers and carbonization stimulators. The changes in composition and physicochemical properties of modified compositions under conditions of heat and fire were investigated by X‐ray photo‐electron spectroscopy, atomic force microscopy, and local force spectroscopy. Ammonium polyphosphate mainly stimulates carbonization processes on the inner surface of a bubble being formed during foam coke formation. The introduction of metal‐containing tubulenes leads to the formation of fire‐retardant and low flammability‐compositions with high coke and carbon structures content. The use of calcium borate in the compositions considerably increases the strength of foam coke being formed. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1477–1483, 2002     

空间桁架结构拓扑优化设计的线性规划方法

本文以杆件内力为设计变量,构造了多工况作用下空间桁架结构拓扑优化的线性规划模型,考虑了应力和位移约束,能够避免奇异最优拓扑和不稳定结构的产生。     

广义准正则格形码距离谱的计算

本文讨论了格形码距离谱的计算问题，定义了度量空间意义下的广义准正则格形码，对具有Ｉｍａｉ与Ｈｉｒａｋａｗａ［２］和Ｕｎｇｅｒｂｏｅｃｋ［３］定义的典型的时不变网格结构的广义准正则格形码，证明了其距离谱可用全零信息序列对应的码字进行计算。在理论上推广了Ｍ．Ｒｏｕａｎｃｅ与Ｄ．Ｊ．Ｃｏｓｔｅｌｏ的结果，解决了非平方欧几里德度量意义下一类ＴＣＭ信号序列的距离谱计算问题     

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本文应用灰色关联分析方法,对70种不同类型和组成的钻井液,进行了两参数流变模式优选及评价。与现行方法比较的结果表明此方法与现行结果的吻合度高,并有新颖、数据要求量少、结论易于比较等优点。