EVM阻燃机理初探

通过运用氧指数、TG、DSC等试验手段对乙烯醋酸乙烯橡胶（EVM）进行研究,揭示了EVM橡胶的阻燃性能与结构之间的必然联系。结果表明,醋酸乙烯酯（VA）从EVM主链脱落,属于吸热反应;主链裂解,属于放热反应;VA含量提高,导致整个体系吸热增加,从而使阻燃性能得以提高。     

智能卡行业中影响卡体黏合强度的因素及化学分析在智能卡制作中的应用

智能卡的加工制作过程是多层塑料薄膜的热压复合过程,其各层之间的黏合强度与制卡用塑料薄膜的相容性、薄膜材料的表面状态和洁净度有关.总结了在热压加工过程中由于各种原因,各层薄膜之间出现的层压不牢现象,并给出了几种常用的相关测试方法.     

啮齿类动物28天重复剂量经口毒性改良试验简介与进展

经济合作与发展组织(Organization for Economic Co-operation and Development,OECD)推荐的啮齿类动物28天重复剂量经口毒性试验(OECD TG 407)是一种广泛用于评价化学物一般毒性的毒理学试验方案。OECD在1998年对其进行改良后,建立TG 407改良试验并经世界多国实验室验证,用于检测化学物的内分泌干扰作用。本文简要介绍了OECD TG 407改良试验指南,并对其进展情况以及优缺点进行综述,以期为我国的内分泌干扰物的评价体系提供参考。     

Application of a novel halogen‐free intumescent flame retardant for acrylonitrile‐butadiene‐styrene

A novel intumescent flame retardant (IFR), containing ammonium polyphosphate (APP) and poly(tetramethylene terephthalamide) (PA4T), was prepared to flame‐retard acrylonitrile‐butadiene‐styrene (ABS). The flame retardation of the IFR/ABS composite was characterized by limiting oxygen index (LOI) and UL‐94 test. Thermogravimetric analysis (TGA) and TGA coupled with Fourier transform infrared spectroscopy (TG‐FTIR) were carried out to study the thermal degradation behavior of the composite and look for the mechanism of the flame‐retarded action. The morphology of the char obtained after combustion of the composite was studied by scanning electron microscopy (SEM). It has been found the intumescent flame retardant showed good flame retardancy, with the LOI value of the PA4T/APP/ABS (7.5/22.5/70) system increasing from 18.5 to 30% and passing UL‐94 V‐1 rating. Meanwhile, the TGA and TG‐FTIR work indicated that PA4T could be effective as a carbonization agent and there was some reaction between PA4T and APP, leading to some crosslinked and high temperature stable material formed, which probably effectively promoted the flame retardancy of ABS. Moreover, it was revealed that uniform and compact intumescent char layer was formed after combustion of the intumescent flame‐retarded ABS composite. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Thermal Decomposition Performance of Unsymmetrical Dimethylhydrazine (UDMH) Oxalate

The thermal decomposition behavior of unsymmetrical dimethylhydrazine (UDMH) oxalate was studied using differential scanning calorimetry (DSC), thermogravimetric analysis (TG/DTG), and thermogravimetric analysis combined with infrared spectroscopy (TG‐IR). The endothermic decomposition of UDMH oxalate occurred at temperatures between 180.4 °C and 217.6 °C, the maximum decomposition temperature is 199.2 °C. The kinetic parameters of the decomposition reaction were calculated based on the Kissinger equation. The TG‐IR spectra indicated that the thermal main decomposition products of UDMH oxalate are CO₂,H₂O and NH₃.     

葛粉的非等温动力学研究

利用TG/DTA技术,考察不同升温速率下葛粉的热分解特性,研究葛粉热分解动力学,运用Kissinger法、Coats-Redfern法和Achar法对非等温动力学数据进行了分析。研究结果表明：在氮气气氛下,葛粉在280℃左右开始分解,至400℃以上基本分解完毕,反应机理函数的积分形式和微分形式分别为：G（α）=[（1-α）-1/3-1]2和f（α）=3/2（1-α）4/3[（1-α）-1/3-1]-1,对应的机理为三维扩散模型。     

增韧改性聚对苯二甲酸丁二酯/聚碳酸酯共混物非等温结晶动力学与力学性能

The polybutylene terephthalate (PBT）/ polycarbonate (PC）blends modified by toughening agent（S-2001）consisting of methyl methacrylate, styrene and silicone were prepared via melt blending.The non-isothermal crystallization kinetics of the blends were investigated by scanning calorimetry (DSC）at different cooling rate of 5℃·min^-1,10℃·min^-1,15℃·min^-1, and the data were analyzed by using modified Avrami theories of the Jeziorny method.The influence of toughening agent相似文献   

UHMWPE/HDPE-g-MAH/PC非等温结晶动力学

用DSC法研究UHMWPE/PC与UHMWPE/HDPE-g-MAH/PC合金材料非等温结晶动力学.DSC曲线分析表明:对于同一种合金材料,随着降温速率的增加,结晶起始温度T0、结晶峰温度Tp都向低温移动,结晶峰宽化.加入增容剂HDPE-g-MAH后,Ta、Tp均有所提高,△t和t1/2增大,结晶速率降低.同时采用莫志深法分析非等温结晶过程,在相同相对结晶度下,UHMWPE/HDPE-g-MAH/PC的F(T)值大于UHMWPE/PC的F(T)值,也表明增容剂的加入降低了材料的结晶能力.     

The Performance of a High Paraffin Reservoir Under Non-isothermal Waterflooding

This study analyzes the performance of a high paraffin reservoir under cold waterflooding for 17 years using a 3-D finite difference simulator and analytical solution of injection wellbore temperature profile to upgrade reservoir management strategies. The reservoir has been marked by injectivity issues, early injection rate decline by half initial values and low incremental recovery, hence subject to alternate developmental schemes. The influence of cold waterflooding is assessed from simulated temperature maps due to nonisothermal injection and solution of injection well temperature profile.     

改性聚乙烯醇的非等温结晶动力学研究

通过差示扫描量热法(DSC)测定了己内酰胺水溶液改性的聚乙烯醇(PVA)降温结晶过程,并用Ozawa方法,Jeziorny方法和莫志深方法分析了改性PVA的非等温结晶动力学。结果表明:随着冷却速率增加,改性体系内起增塑作用的小分子由于其蒸发升华的减缓,改性PVA体系的运动能力增强,结晶度提高;莫志深方法能够较好地解释改性PVA的非等温结晶过程,即在单位时间内达到较大结晶度需较大的降温速率,且随着体系相对结晶度的增加,结晶速率降低。