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51.
52.
海洋钻井液有机物添加剂生物降解性评价 总被引:1,自引:0,他引:1
随着海洋石油的勘探开发,钻井液有机添加剂不可避免地进入海洋.因此在海洋勘探开发过程中应选择环保性能好,即生物降解性能好的有机物添加剂。用累计耗氧量法测定了海洋钻井液有机添加剂的生物降解性,研究评价了有机添加剂的生物降解规律和机理,探讨了有机物生物降解性同其化学结构的内在联系,为海洋勘探开发过程中选择环保性能好的有机物添加剂提供理论依据。总结实验结果发现:淀粉类(如DFD-140和FI-E1等)最容易生物降解;其次是纤维素类(如MV-CMC等)和烯类单体聚合物(如PAM和PHP);而沥青类、两性离子类则难以生物降解,有的甚至对生物降解起抑制作用。 相似文献
53.
简要介绍了全板电镀镍金加工过程中镀金面发白现象及改善措施。特别是针对高位发白(或粗糙)的产生原因和处理过程进行较为详细的描述,并对工艺在此处理过程中存在问题进行了简要剖析。 相似文献
54.
S.K. Lee D.‐H. Hwang B.‐J. Jung N.S. Cho J. Lee J.‐D. Lee H.‐K. Shim 《Advanced functional materials》2005,15(10):1647-1655
By using Ni0‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33). 相似文献
55.
S.‐C. Lo G.J. Richards J.P.J. Markham E.B. Namdas S. Sharma P.L. Burn I.D.W. Samuel 《Advanced functional materials》2005,15(9):1451-1458
We describe the preparation of a dendrimer that is solution‐processible and contains 2‐ethylhexyloxy surface groups, biphenyl‐based dendrons, and a fac‐tris[2‐(2,4‐difluorophenyl)pyridyl]iridium(III ) core. The homoleptic complex is highly luminescent and the color of emission is similar to the heteroleptic iridium(III ) complex, bis[2‐(2,4‐difluorophenyl)pyridyl]picolinate iridium(III ) (FIrpic). To avoid the change in emission color that would arise from attaching a conjugated dendron to the ligand, the conjugation between the dendron and the ligand is decoupled by separating them with an ethane linkage. Bilayer devices containing a light‐emitting layer comprised of a 30 wt.‐% blend of the dendrimer in 1,3‐bis(N‐carbazolyl)benzene (mCP) and a 1,3,5‐tris(2‐N‐phenylbenzimidazolyl)benzene electron‐transport layer have external quantum and power efficiencies, respectively, of 10.4 % and 11 lm W–1 at 100 cd m–2 and 6.4 V. These efficiencies are higher than those reported for more complex device structures prepared via evaporation that contain FIrpic blended with mCP as the emitting layer, showing the advantage of using a dendritic structure to control processing and intermolecular interactions. The external quantum efficiency of 10.4 % corresponds to the maximum achievable efficiency based on the photoluminescence quantum yield of the emissive film and the standard out‐coupling of light from the device. 相似文献
56.
We report here a non-enzymatic detecting electrode strip for fast monitoring of uric acid in human whole blood. A single-use amperometric uric acid sensor strip, incorporating a three-electrode configuration, has been fabricated on a polypropylene substrate using low cost screen-printing (thick-film) technology. Both the working and counter electrodes were prepared by screen-printing commercial carbon ink. The integration on the same support of pseudo-reference electrode was obtained by screen-printing a commercial silver ink and subsequent electrochemical pretreatment. Simply by placing a 20 μl human whole blood drop on the strip is enough for uric acid analysis by square-wave voltammetry. Real human whole blood samples were analyzed by this method and compared to the phosphotungstic acid clinical test procedure with satisfactory results. 相似文献
57.
溶液温度对电化学沉积氧化亚铜薄膜相成分和显微结构的影响 总被引:6,自引:0,他引:6
用电化学方法在不锈钢基体上沉积多晶Cu2O薄膜并用X射线衍射和扫描电进行了分析研究了溶液温度对薄膜相组成、晶粒尺寸和择优取向的影响,当溶液的PH=9,温度低于50℃时得到的是Cu2O/Cu复相薄膜,纯Cu2O薄膜可在溶液温度高于50℃时获得,纯Cu2O薄膜具有(100)择优取向,实验发现薄膜的晶粒尺寸随溶液温度的增加从0.12μm增加到0.65μm。 相似文献
58.
Per Axel Clausen 《Indoor air》1993,3(4):269-275
A waterborne paint was applied to tin plated steel sheets with three different film thicknesses. The emission of volatile and semivolaile organic compounds ((S) VOCs) from the samples was measured in small climatic chambers under standard conditions over a two-week period. The purpose of the study was to evaluate the effect of the film thickness on the emission rate decay. First order decay models, including sink effects for the high boiling (S) VOCs, were fitted to the concentration versus time data. The results showed that the first order rate constants decrease with increasing film thickness. In uddition, the results indicated that the emissions of the (S)VOCs in the waterborne paint film seemed to be controlled by evaporation. The thicknesses of paint films used in climatic chamber tests to estimate emission rates for product compurison or emission prediction must be known in order to prevent erroneous conclusions 相似文献
59.
M. Nicolaidis 《Journal of Electronic Testing》1991,1(4):257-273
It has been noted by several authors that the classical stuck-at logical fault model might not be an appropriate representation of certain real failures occurring in integrated circuits. Shorts are an important class of such faults. This article gives a detailed analysis of the effects of shorts in self-checking circuits and proposes techniques for dealing with them. More precisely, we show that, unlike other faults such as stuck-at, stuck-on, and stuck-open—which produce only single errors in the place they occur—shorts can produce double errors on the two shorted lines. In particular, feedback shorts can produce double errors on the two shorted lines. The double error is unidirectional for some feedback shorts and non-unidirectional for some others. Furthermore, in some technologies (e.g., CMOS), non-feedback shorts can also produce double non-unidirectional errors. We also show that unlike stuck-at, stuck-on, and stuck-open faults, redundant shorts can destroy the SFS property. Then we propose several techniques for coping with these problems and we illustrate the results by circuit implementation examples.The present study is given for NMOS and CMOS circuits but we show that it is valid for any other technology. 相似文献
60.