In Situ Chelating Synthesis of Hierarchical LiNi1/3Co1/3Mn1/3O2 Polyhedron Assemblies with Ultralong Cycle Life for Li‐Ion Batteries

Layered lithium transition‐metal oxides, with large capacity and high discharge platform, are promising cathode materials for Li‐ion batteries. However, their high‐rate cycling stability still remains a large challenge. Herein, hierarchical LiNi_1/3Co_1/3Mn_1/3O₂ polyhedron assemblies are obtained through in situ chelation of transition metal ions (Ni²⁺, Co²⁺, and Mn²⁺) with amide groups uniformly distributed along the backbone of modified polyacrylonitrile chains to achieve intimate mixing at the atomic level. The assemblies exhibit outstanding electrochemical performances: superior rate capability, high volumetric energy density, and especially ultralong high‐rate cyclability, due to the superiority of unique hierarchical structures. The polyhedrons with exposed active crystal facets provide more channels for Li⁺ diffusion, and meso/macropores serve as access shortcuts for fast migration of electrolytes, Li⁺ and electrons. The strategy proposed in this work can be extended to fabricate other mixed transition metal‐based materials for advanced batteries.     

乙基纤维素微胶囊红磷的制备及改性

目前微胶囊红磷大多采用原位聚合法制备,工艺较为复杂,且囊壳原料可能对环境造成危害.为解决这一问题,以可降解材料乙基纤维素(EC)为囊壳,采用相分离法在常温、中性条件下制备微胶囊红磷(MRP);为进一步增强MRP使用性能,添加正硅酸乙酯(TEOS)作为改性材料,在碱性条件下制备SiO_2凝胶/EC复合囊壳微胶囊红磷(SiMRP).对所得样品进行FTIR、形态及XPS分析,观察样品形态并计算包覆率;对样品进行热稳定性分析、吸湿率测定及安定性测试.实验结果表明:采用相分离法可对红磷实现有效包覆,囊壳包覆率为88.2%;EC囊壳提高了红磷的热稳定性,着火点温度较RP提升50℃; MRP 10日后吸湿率降至6.8%,摩擦感度降至34%;添加1 mL TEOS改性后的SiMPR样品包覆率达94.1%,热稳定性较MRP进一步增强,着火点温度较MRP提升90℃;SiMRP 10日后吸湿率降至4.5%,摩擦感度降至20%.     

基于改进双曲正切函数的变步长最小平均p范数算法

在信号处理领域,传统的自适应滤波算法采用的固定步长会导致稳态误差和收敛速度无法同时兼顾。针对这个问题,对最小平均p范数(Least Mean p-norm,LMP)算法进行改进,提出了一种基于改进双曲正切(tanh)函数的变步长最小平均p范数算法。该算法利用改进的tanh函数来调节步长,采用移动加权平均法构造变步长函数;同时引入了一个调节函数以进一步提升算法的性能。通过在海洋脉冲噪声干扰下进行仿真,实验表明,与已有的固定步长和变步长算法相比,改进的变步长LMP算法较好地兼顾系统的收敛速度和稳态误差;引入调节函数后的新算法在保证原有算法收敛速度的同时进一步降低了算法的稳态误差,从而兼顾了算法的收敛性和稳定性,具有较好的可行性。     

随机脉冲控制下超混沌复Lü系统的渐近稳定性

基于脉冲微分方程的稳定性理论,研究了具有随机信号的脉冲作用下,超混沌复Lü系统的渐近稳定性.给出了确定性和随机脉冲作用下系统达到渐近稳定的判据.并且提出了在等距脉冲间隔下,系统达到稳定的区域估计值.通过数值算例,讨论了确定性脉冲和随机脉冲的异同点,并证实,此方法对于外界噪声是比较稳健的.     

中立型时滞反馈扭转控制系统的稳定性分析

研究了中立型时滞动力吸振器抑制扭转系统的振动问题.针对一类强迫扭转振动系统,采用动力系统的稳定性理论分析了动力吸振器与扭转振动系统的稳定性问题,以时滞为参数,分别得到了动力吸振器与扭转振动系统的稳定区域,并研究时滞变化时动力吸振器对于主振动系统振动的吸收效果,通过与时滞动力吸振器对比,得到了更大的吸振器和减振系统时滞稳定工作区域,通过数值模拟验证了结论的正确性.     

Measurement and analysis of low-acceleration and long-duration longitudinal events using delivery van

This study investigates longitudinal acceleration events during freight transportation characterized as low-acceleration and long-duration using delivery van type vehicles. In the past several decades, there has been an increase in shipments requiring only single or small pallet load quantities and mixed palletized unit loads comprised of different goods. These loads are often transported in delivery vans without load securing devices, increasing the risk of product loss and damage due to load failures resulting from unit loads shifting. A field data acquisition system was used to observe and record the random acceleration events from five vehicles for 5 days, explicitly targeting the vehicles' braking and acceleration manoeuvres. The study aimed to understand the physical phenomenon and provide new information that can be used during preshipment tests to prevent damage to goods and ensure unit load integrity is maintained throughout the supply chain. The events were statistically analysed to understand their probability of occurrence, severity level, and quantify critical parameters such as event rise and hold times. For the braking manoeuvre, the statistical mean of average deceleration was 0.25 g with a corresponding rise and hold duration of 0.83 and 1.27 s, respectively. During the vehicle's acceleration manoeuvre, the statistical mean of average acceleration was 0.29 g with a rise and hold time of 1.29 and 1.39 s, respectively. Utilizing the field data, composite profiles were developed, and these profiles were compared to the currently available test procedures and previous results of other studies.     

Contact Stability Analysis of a One Degree-of-Freedom Robot

The aim of this note is to examine the conditions of stability of a simple robotic task: we consider a one degree-of-freedom (dof) robot that collides with a spring-like environment with stiffness k, the goal being to stabilize the system in contact with the environment. We study conditions on the feedback gains that guarantee quadratic Lyapunov stability of the task with a well-conditioned solution to the Lyapunov equation. It is shown that when the environment's stiffness k grows unbounded, those conditions yield unbounded values of the gains. Motivated by the stability analysis of the impact Poincaré map in the perfectly rigid case ( ), we propose an analysis that is independent of k. It enables us to conclude on global asymptotic convergence of the system's state towards the equilibrium point. This work can also be seen as the study of stability of a contact (force control) phase, taking into account the unilateral feature of the constraint.     

Stability and boundedness in difference systems with finite delay

In this paper, stability and boundedness theorems for delay difference systems with the condition

δV(n,x(n))≤-W₂(|x(n)|)+σ

are given, where Δ is the backward difference operator. Some known results are generalized.